Diethynyl-diphenyl-silane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar82.50cal/mol*KN/AMilov, Lebedev, et al., 1977 
solid,1 bar85.49cal/mol*KN/AMilov, Lebedev, et al., 1974 

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
72.94298.15Milov, Lebedev, et al., 1977T = 10 to 326 K.
74.69298.15Milov, Lebedev, et al., 1974T = 50 to 330 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
4.7020316.24Milov, Lebedev, et al., 1974DH
4.701316.2Domalski and Hearing, 1996AC

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
209.crystaline, II, Crystalcrystaline, I, glass transitionMilov, Lebedev, et al., 1977DH

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
5.3442316.72crystaline, IliquidMilov, Lebedev, et al., 1977DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
16.87316.72crystaline, IliquidMilov, Lebedev, et al., 1977DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Milov, Lebedev, et al., 1977
Milov, V.I.; Lebedev, B.V.; Kiparisova, Y.G.; Bykova, T.A.; Sladkov, A.M., Thermodynamics of diphenyldiethynylsilane in the 10-326 K range, Termodin. Org. Soedin., 1977, (6), 13-25. [all data]

Milov, Lebedev, et al., 1974
Milov, V.I.; Lebedev, B.V.; Tsvetkova, L.Ya.; Sladkov, A.M.; Luneva, L.K.; Lebedev, N.K.; Evstropov, A.A., Heat capacity and thermodynamic functions of diphenyldiethynylsilane and poly(diphenyldiethynylsilane), Tr. Khim. Khim. Tekhnol, Gor'kii, 1974, 1(36), 140-145. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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