Spiro[4.5]decane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-145.1 ± 2.2kJ/molCcbSubach and Zwolinski, 1975 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-200. ± 1.kJ/molCcbKozin, Mirzaeva, et al., 1964 
Quantity Value Units Method Reference Comment
Δcliquid-6307.5 ± 2.0kJ/molCcbSubach and Zwolinski, 1975Corresponding Δfliquid = -200.0 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-6307. ± 1.kJ/molCcbKozin, Mirzaeva, et al., 1964Corresponding Δfliquid = -200. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil458.KN/ATurova-Pollyak, Sosnina, et al., 1957Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δvap54.923 ± 0.088kJ/molVSubach and Zwolinski, 1975ALS
Δvap54.8kJ/molCSubach and Zwolinski, 1975AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
44.0363.Naro, 1965Based on data from 348. to 389. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
348.0 to 389.35.04872313.6611.343Naro, 1965, 2Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Subach and Zwolinski, 1975
Subach, D.J.; Zwolinski, B.J., Enthalpies of combustion, formation, and vaporization of spiro[4,5]decane, spiro[5,5]undecane, and 7-n-Hexadecylspiro[4,5]decane, J. Chem. Eng. Data, 1975, 20, 232-235. [all data]

Kozin, Mirzaeva, et al., 1964
Kozin, M.P.; Mirzaeva, A.K.; Sosina, I.E.; Elagina, N.V.; Skuratov, S.M., The heats of formation of spiro hydrocarbons, Dokl. Phys. Chem. (Engl. Transl.), 1964, 155, 375-377. [all data]

Turova-Pollyak, Sosnina, et al., 1957
Turova-Pollyak, M.B.; Sosnina, I.E.; Yudkina, T.P., Isomerization of Polymethylene Hydrocarbons und the Influence of Aluminum Chloride XX. Isomrization of Spiro[4.5]decane, Zh. Obshch. Khim., 1957, 27, 586-9. [all data]

Naro, 1965
Naro, P.A., Physical Properties of Four Spiro Hydrocarbons., J. Chem. Eng. Data, 1965, 10, 1, 86-87, https://doi.org/10.1021/je60024a032 . [all data]

Naro, 1965, 2
Naro, P.A., Physical Properties of Four Spiro Hydrocarbons, J. Chem. Eng. Data, 1965, 10, 1, 86, https://doi.org/10.1021/je60024a032 . [all data]


Notes

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