4,4'-Bipyridine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas293.1 ± 3.6kJ/molCcbRibeiro da Silva, Morais, et al., 1995 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid186.8 ± 2.2kJ/molCcbRibeiro da Silva, Morais, et al., 1995 
Quantity Value Units Method Reference Comment
Δcsolid-5265.2 ± 1.8kJ/molCcbRibeiro da Silva, Morais, et al., 1995 

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil578.2KN/AWeast and Grasselli, 1989BS
Tboil578.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Δvap71.1 ± 2.6kJ/molCGCLipkind and Chickos, 2009See also Lipkind, Hanshaw, et al., 2009.; AC
Quantity Value Units Method Reference Comment
Δsub106.3 ± 2.8kJ/molCRibeiro da Silva, Morais, et al., 1995ALS
Δsub106.3kJ/molN/ARibeiro da Silva, Morais, et al., 1995DRB
Δsub106.3 ± 2.8kJ/molCRibeiro da Silva, Morais, et al., 1995AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
16.1377.5DSCLipkind, Hanshaw, et al., 2009AC

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Morais, et al., 1995
Ribeiro da Silva, M.A.V.; Morais, V.M.F.; Matos, M.A.R.; Rio, C.M.A., Thermochemical and theoretical studies of some bipyridines, J. Org. Chem., 1995, 60, 5291-5294. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Lipkind and Chickos, 2009
Lipkind, D.; Chickos, J.S., , Abstract from 38th Great Lakes Regional Meeting of the American Chemical Society, May 13-16, Chicago, IL, 2009, GLRM-275. [all data]

Lipkind, Hanshaw, et al., 2009
Lipkind, Dmitri; Hanshaw, William; Chickos, James S., Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Heterocycles and Related Compounds, J. Chem. Eng. Data, 2009, 54, 10, 2930-2943, https://doi.org/10.1021/je900034d . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References