Biphenyl
- Formula: C12H10
- Molecular weight: 154.2078
- IUPAC Standard InChIKey: ZUOUZKKEUPVFJK-UHFFFAOYSA-N
- CAS Registry Number: 92-52-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: 1,1'-Biphenyl; Bibenzene; Diphenyl; Phenylbenzene; 1,1'-Diphenyl; Lemonene; Phenador-X; PhPh; Xenene; Carolid AL; Tetrosin LY; NSC 14916; 1,1-Biphenyl
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 43.1 ± 0.7 | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Constant pressure heat capacity of gas
Cp,gas (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
12.03 | 50. | Dorofeeva O.V., 1997 | None of the statistically calculated values of S(T) known from literature [ Trevissoi C., 1955, Katon J.E., 1959, Aleman H., 1973, Thermodynamics Research Center, 1997] is in full accord with experimental data (see also discussion in [ Chirico R.D., 1989]). Recommended values agree with experimental values within their uncertainties except for temperature range 340-460 K where discrepancies amount to 0.4-0.6 J/mol*K.; GT |
15.49 | 100. | ||
20.14 | 150. | ||
26.030 | 200. | ||
36.202 | 273.15 | ||
39.84 ± 0.24 | 298.15 | ||
40.105 | 300. | ||
53.903 | 400. | ||
65.397 | 500. | ||
74.517 | 600. | ||
81.773 | 700. | ||
87.655 | 800. | ||
92.512 | 900. | ||
96.573 | 1000. | ||
100.00 | 1100. | ||
102.93 | 1200. | ||
105.43 | 1300. | ||
107.57 | 1400. | ||
109.43 | 1500. |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 23.5 ± 0.60 | kcal/mol | Review | Roux, Temprado, et al., 2008 | There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB |
ΔfH°solid | 23.12 ± 0.62 | kcal/mol | Ccb | Montgomery, Rossini, et al., 1978 | ALS |
ΔfH°solid | 24.02 ± 0.36 | kcal/mol | Ccb | Coleman and Pilcher, 1966 | ALS |
ΔfH°solid | 23.14 ± 0.96 | kcal/mol | Ccb | Mackle and O'Hare, 1963 | ALS |
ΔfH°solid | 23.24 ± 0.39 | kcal/mol | Ccb | Parks and Vaughan, 1951 | Reanalyzed by Cox and Pilcher, 1970, Original value = 23.10 kcal/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -1494. ± 5. | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 50.043 | cal/mol*K | N/A | Chirico, Knipmeyer, et al., 1989 | DH |
S°solid,1 bar | 49.952 | cal/mol*K | N/A | Saito, Atake, et al., 1988 | DH |
S°solid,1 bar | 49.21 | cal/mol*K | N/A | Huffman, Parks, et al., 1930 | Extrapolation below 90 K, 65.4 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
68.19 | 370. | Walker, Brooks, et al., 1958 | T = 200 to 600°F.; DH |
71.99 | 422. | McEwen, March 31 1956 | T = 300 to 600°C.; DH |
71.70 | 370. | Kurbatov, 1950 | T = 98 to 255°C. Mp 70.8°C.; DH |
62.91 | 350.8 | Forrest, Brugmann, et al., 1931 | T = 350 to 620 K. Value is unsmoothed experimental datum.; DH |
62.032 | 298. | Newton, Kaura, et al., 1931 | T = 100 to 300°C, equation only, in t°C. Cp(liq) = 0.388 + 0.00057t cal/g*K.; DH |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
47.416 | 298.15 | Chirico, Knipmeyer, et al., 1989 | T = 5 to 700 K.; DH |
47.364 | 298.15 | Saito, Atake, et al., 1988 | T = 3 to 300 K.; DH |
47.25 | 298.15 | O'Rourke and Mraw, 1983 | T = 220 to 475 K. Cp = 0.7143 (T/K) - 15.3 (220 to 342.2 K) J/mol*K.; DH |
45.4 | 300. | Wasicki, Radomska, et al., 1982 | T = 180 to 350 K. Data given graphically. Value estimated from graph.; DH |
45.60 | 298.15 | Ueberreiter and Orthmann, 1950 | T = 293 to 368 K. Equation only.; DH |
47.30 | 298.1 | Schmidt, 1941 | T = 20 to 200°C, equations only, in t°C. Cp(c) = 0.2745 + 0.001235t cal/g*K (20 to 69°C); Cp(liq) = 0.3917 + 0.0005206t cal/g*K (69 to 200°C).; DH |
47.30 | 303. | Spaght, Thomas, et al., 1932 | T = 30 to 100°C.; DH |
46.39 | 294.4 | Huffman, Parks, et al., 1930 | T = 93 to 295 K. Value is unsmoothed experimental datum.; DH |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 527. ± 2. | K | AVG | N/A | Average of 40 out of 42 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 343. ± 1. | K | AVG | N/A | Average of 285 out of 294 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 342.090 | K | N/A | Chirico, Knipmeyer, et al., 1989, 2 | Uncertainty assigned by TRC = 0.01 K; TRC |
Ttriple | 341.8 | K | N/A | Parks and Huffman, 1931 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 780. ± 20. | K | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 34. ± 6. | atm | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.497 | l/mol | N/A | Tsonopoulos and Ambrose, 1995 | |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 2.0 ± 0.1 | mol/l | N/A | Tsonopoulos and Ambrose, 1995 | |
ρc | 2.01 | mol/l | N/A | Ellard and Yanko, 1963 | Uncertainty assigned by TRC = 0.065 mol/l; TRC |
ρc | 2.09 | mol/l | N/A | Reiter, 1963 | Uncertainty assigned by TRC = 0.065 mol/l; TRC |
ρc | 1.99 | mol/l | N/A | Mandel and Ewbank, 1960 | Uncertainty assigned by TRC = 0.097 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 15. ± 3. | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 19.5 ± 0.7 | kcal/mol | AVG | N/A | Average of 10 values; Individual data points |
Reduced pressure boiling point
Tboil (K) | Pressure (atm) | Reference | Comment |
---|---|---|---|
418.2 | 0.029 | Weast and Grasselli, 1989 | BS |
418. | 0.029 | Buckingham and Donaghy, 1982 | BS |
343. to 351. | 0.0003 | Buckingham and Donaghy, 1982 | BS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
12.2 | 510. | DSC | Back, Grzyll, et al., 1996 | Based on data from 495. to 688. K.; AC |
13.7 | 400. | EB | Chirico, Knipmeyer, et al., 1989 | Based on data from 350. to 578. K.; AC |
14.4 | 360. | EB | Chirico, Knipmeyer, et al., 1989 | Based on data from 350. to 578. K.; AC |
12.0 | 500. | EB | Chirico, Knipmeyer, et al., 1989 | Based on data from 350. to 578. K.; AC |
14.2 | 363. | GS | Sakoguchi, Iwai, et al., 1989 | Based on data from 348. to 453. K.; AC |
14.4 | 363. | N/A | Sasse, N'guimbi, et al., 1989 | Based on data from 333. to 393. K.; AC |
13.7 | 405. | A | Stephenson and Malanowski, 1987 | Based on data from 390. to 563. K.; AC |
13.1 | 417. | GS | Nasir, Hwang, et al., 1980 | Based on data from 396. to 437. K.; AC |
11.5 | 647. | N/A | Glaser and Rüland, 1957 | Based on data from 528. to 766. K.; AC |
14.2 | 357. | N/A | Cunningham, 1930 | Based on data from 342. to 544. K. See also Boublik, Fried, et al., 1984.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
342.3 to 544.3 | 4.35114 | 1987.623 | -71.556 | Cunningham, 1930, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
19.484 | 298.15 | N/A | Chirico, Knipmeyer, et al., 1989 | DH |
19.6 | 383. | GS | Nass, Lenoir, et al., 1995 | Based on data from 313. to 453. K.; AC |
19.9 | 311. | EM | Sasse, N'guimbi, et al., 1989 | Based on data from 283. to 338. K.; AC |
18.2 ± 0.96 | 273. to 313. | HSA | Chickos, 1975 | AC |
19.2 ± 0.38 | 319. | TSGC | Clark, Knox, et al., 1975 | Based on data from 306. to 332. K.; AC |
18.0 | 298. to 318. | ME | Pribilová and Pouchlý, 1974 | AC |
19.98 ± 0.59 | 283. | V | Radchenko and Kitaigorodskii, 1974 | ALS |
18.12 ± 0.14 | 342.5 | V | Aihara, 1959 | ALS |
18.1 ± 0.1 | 289. | N/A | Aihara, 1955 | Based on data from 279. to 299. K.; AC |
19.5 ± 0.41 | 301. | N/A | Bradley and Cleasby, 1953 | Based on data from 288. to 314. K.; AC |
19.500 | 288.05 | V | Bradley and Cleasby, 1953, 2 | ALS |
17.9 ± 0.41 | 297. | N/A | Seki and Suzuki, 1953 | Based on data from 287. to 307. K.; AC |
16.4 ± 0.2 | 292. | QF | Wolf and Weghofer, 1938 | AC |
16.4 ± 0.2 | 295. | V | Wolf and Weghofer, 1938, 2 | ALS |
Entropy of sublimation
ΔsubS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
65.349 | 298.15 | Chirico, Knipmeyer, et al., 1989 | DH |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
4.43977 | 342.098 | N/A | Chirico, Knipmeyer, et al., 1989 | DH |
4.4407 | 342.2 | N/A | O'Rourke and Mraw, 1983 | DH |
4.4933 | 344.1 | N/A | Smith, 1979 | DH |
4.4570 | 341.5 | N/A | Spaght, Thomas, et al., 1932 | DH |
4.71 | 342.3 | DSC | Khimeche and Dahmani, 2006 | AC |
4.606 | 344.34 | DSC | Benkhennouf, Kamel, et al., 2004 | AC |
4.460 | 341.5 | N/A | Domalski and Hearing, 1996 | AC |
4.4395 | 343. | N/A | Ueberreiter and Orthmann, 1950 | DH |
4.4441 | 342. | N/A | Schmidt, 1941 | DH |
4.5280 | 314.3 | N/A | Eykman, 1889 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
12.978 | 342.098 | Chirico, Knipmeyer, et al., 1989 | DH |
13.0 | 342.2 | O'Rourke and Mraw, 1983 | DH |
13.0 | 344.1 | Smith, 1979 | DH |
13.0 | 341.5 | Spaght, Thomas, et al., 1932 | DH |
13.10 | 341.5 | Domalski and Hearing, 1996 | CAL |
13.0 | 343. | Ueberreiter and Orthmann, 1950 | DH |
13.0 | 342. | Schmidt, 1941 | DH |
14.4 | 314.3 | Eykman, 1889 | DH |
Enthalpy of phase transition
ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.000036 | 16.8 | crystaline, III | crystaline, II | Saito, Atake, et al., 1988 | DH |
0.00120 | 40.4 | crystaline, II | crystaline, I | Saito, Atake, et al., 1988 | Twist transition.; DH |
0.000036 | 16.8 | crystaline, III | crystaline, II | Atake, Saito, et al., 1983 | Anomalous region: 15.3 to 18.3 K.; DH |
0.00120 | 40.4 | crystaline, II | crystaline, I | Atake, Saito, et al., 1983 | Anomalous region: 30 to 47 K.; DH |
0.000070 | 11.0 | crystaline, III | crystaline, II | Ataki and Chihara, 1980 | DH |
0.00120 | 40.4 | crystaline, II | crystaline, I | Ataki and Chihara, 1980 | DH |
4.7562 | 343.3 | crystaline, I | liquid | Wasicki, Radomska, et al., 1982 | DH |
Entropy of phase transition
ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.002 | 16.8 | crystaline, III, Lock | crystaline, II, in transition | Saito, Atake, et al., 1988 | DH |
0.0308 | 40.4 | crystaline, II | crystaline, I | Saito, Atake, et al., 1988 | Twist; DH |
0.002 | 16.8 | crystaline, III | crystaline, II | Atake, Saito, et al., 1983 | Anomalous; DH |
0.0308 | 40.4 | crystaline, II | crystaline, I | Atake, Saito, et al., 1983 | Anomalous; DH |
0.0060 | 11.0 | crystaline, III | crystaline, II | Ataki and Chihara, 1980 | DH |
0.0308 | 40.4 | crystaline, II | crystaline, I | Ataki and Chihara, 1980 | DH |
13.9 | 343.3 | crystaline, I | liquid | Wasicki, Radomska, et al., 1982 | DH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dorofeeva O.V., 1997
Dorofeeva O.V.,
Unpublished results. Thermocenter of Russian Academy of Science, Moscow, 1997. [all data]
Trevissoi C., 1955
Trevissoi C.,
Specific heat and entropy of biphenyl,
Ann. Chim. (Rome), 1955, 45, 943-959. [all data]
Katon J.E., 1959
Katon J.E.,
The vibrational spectra and geometrical configuration of biphenyl,
Spectrochim. Acta, 1959, 15, 627-650. [all data]
Aleman H., 1973
Aleman H.,
Thermodynamic functions for biphenyl and the 4,4'-dihalogenobiphenyls,
Thermochim. Acta, 1973, 7, 69-73. [all data]
Thermodynamics Research Center, 1997
Thermodynamics Research Center,
Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]
Chirico R.D., 1989
Chirico R.D.,
The thermodynamic properties of biphenyl,
J. Chem. Thermodyn., 1989, 21, 1307-1331. [all data]
Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y.,
Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons,
J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]
Montgomery, Rossini, et al., 1978
Montgomery, R.L.; Rossini, F.D.; Mansson, M.,
Enthalpies of combustion, vaporization, and formation of phenylbenzene, cyclohexylbenzene, and cyclohexylcyclohexane; enthalpy of hydrogenation of certain aromatic systems,
J. Chem. Eng. Data, 1978, 23, 125-129. [all data]
Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G.,
Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene,
Trans. Faraday Soc., 1966, 62, 821-827. [all data]
Mackle and O'Hare, 1963
Mackle, H.; O'Hare, P.A.G.,
A high-precision aneroid semi-micro combustion calorimeter,
Trans. Faraday Soc., 1963, 59, 2693-2701. [all data]
Parks and Vaughan, 1951
Parks, G.S.; Vaughan, L.M.,
The heat of combustion of biphenyl,
J. Am. Chem. Soc., 1951, 73, 2380-2381. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Chirico, Knipmeyer, et al., 1989
Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Steele, W.V.,
The thermodynamic properties of biphenyl,
J. Chem. Thermodyn., 1989, 21, 1307-1331. [all data]
Saito, Atake, et al., 1988
Saito, K.; Atake, T.; Chihara, H.,
Incommensurate phase transitions and anomalous lattice heat capacities of biphenyl,
Bull. Chem. Soc. Japan, 1988, 61, 679-688. [all data]
Huffman, Parks, et al., 1930
Huffman, H.M.; Parks, G.S.; Daniels, A.C.,
Thermal data on organic compounds. VII. The heat capacities, entropies and free energies of twelve aromatic hydrocarbons,
J. Am. Chem. Soc., 1930, 52, 1547-1558. [all data]
Walker, Brooks, et al., 1958
Walker, B.E., Jr.; Brooks, M.S.; Ewing, C.T.; Miller, R.R.,
Specific heat of biphenyl and other polyphenyls. Correlation of specific heat data for phenyl type compounds,
J. Chem. Eng. Data, 1958, 3, 280-282. [all data]
McEwen, March 31 1956
McEwen, M.,
Preliminary engineering study of organic nuclear reactor coolant-moderators Monsanto Chemical Co, March 31 1956. [all data]
Kurbatov, 1950
Kurbatov, V.Ya.,
Specific heats of liquids. III. Specific heat of hydrocarbons with several noncondensed rings,
Zhur. Obshch. Khim., 1950, 20, 1139-1144. [all data]
Forrest, Brugmann, et al., 1931
Forrest, H.O.; Brugmann, E.W.; Cummings, L.W.T.,
The specific heat of diphenyl,
Ind. Eng. Chem., 1931, 23, 37-39. [all data]
Newton, Kaura, et al., 1931
Newton, R.F.; Kaura, B.D.; DeVries, T.,
The specific heat of liquid diphenyl,
Ind. Eng. Chem., 1931, 23, 35-37. [all data]
O'Rourke and Mraw, 1983
O'Rourke, D.F.; Mraw, S.C.,
Heat capacities and enthalpies of fusion of dibenzothiophene (220 to 560 K) and of biphenyl, cyclohexylbenzene, and cyclohexylcyclohexane (220 to 475 K). Enthalpies and temperatures of three transitions in solid cyclohexylcyclohexane,
J. Chem. Thermodynam., 1983, 15, 489-502. [all data]
Wasicki, Radomska, et al., 1982
Wasicki, J.; Radomska, M.; Radomski, R.,
Heat capacities of diphenyl, p-terphenyl and p-quaterphenyl from 180 K to their melting points,
J. Therm. Anal., 1982, 25, 509-514. [all data]
Ueberreiter and Orthmann, 1950
Ueberreiter, K.; Orthmann, H.-J.,
Specifische Wärme, spezifisches Volumen, Temperatur- und Wärme-leittähigkeit einiger disubstituierter Benzole und polycyclischer Systeme,
Z. Natursforsch. 5a, 1950, 101-108. [all data]
Schmidt, 1941
Schmidt, W.R.,
Thesis Washington University (St. Louis), 1941. [all data]
Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S.,
Some heat capacity data on organic compounds obtained with a radiation calorimeter,
J. Phys. Chem., 1932, 36, 882-888. [all data]
Chirico, Knipmeyer, et al., 1989, 2
Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Steele, W.V.,
The thermodynamic properties of biphenyl,
J. Chem. Thermodyn., 1989, 21, 1307-31. [all data]
Parks and Huffman, 1931
Parks, G.S.; Huffman, H.M.,
Some fusion and transition data for hydrocarbons,
Ind. Eng. Chem., 1931, 23, 1138-9. [all data]
Tsonopoulos and Ambrose, 1995
Tsonopoulos, C.; Ambrose, D.,
Vapor-Liquid Critical Properties of Elements and Compounds. 3. Aromatic Hydrocarbons,
J. Chem. Eng. Data, 1995, 40, 547-558. [all data]
Ellard and Yanko, 1963
Ellard, J.A.; Yanko, W.H.,
, U. S. A. E. C. Rep. IDO-11008, 1963. [all data]
Reiter, 1963
Reiter, R.W.,
, NASA Doc. N63-19495 1963 1963, 1963. [all data]
Mandel and Ewbank, 1960
Mandel, H.; Ewbank, N.,
, Atomics International NAA-S-R-5129 1960, 1960. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M.,
Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]
Back, Grzyll, et al., 1996
Back, Dwight D.; Grzyll, Lawrence R.; Corrigan, Mary,
DSC enthalpy of vaporization measurements of high temperature two-phase working fluids,
Thermochimica Acta, 1996, 272, 53-63, https://doi.org/10.1016/0040-6031(95)02615-0
. [all data]
Sakoguchi, Iwai, et al., 1989
Sakoguchi, Akihiro; Iwai, Yoshio; Takenaka, Jun; Arai, Yasuhiko,
Measurement of vapor pressures of tetralin, 1-naphthol and biphenyl using flow-type apparatus.,
KAGAKU KOGAKU RONBUNSHU, 1989, 15, 1, 166-169, https://doi.org/10.1252/kakoronbunshu.15.166
. [all data]
Sasse, N'guimbi, et al., 1989
Sasse, K.; N'guimbi, J.; Jose, J.; Merlin, J.C.,
Tension de vapeur d'hydrocarbures polyaromatiques dans le domaine 10-3--10 Torr,
Thermochimica Acta, 1989, 146, 53-61, https://doi.org/10.1016/0040-6031(89)87075-3
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Nasir, Hwang, et al., 1980
Nasir, P.; Hwang, S.C.; Kobayashi, R.,
Development of an apparatus to measurement vapor pressures at high temperatures and its application to three higher-boiling compounds,
J. Chem. Eng. Data, 1980, 25, 4, 298-301, https://doi.org/10.1021/je60087a009
. [all data]
Glaser and Rüland, 1957
Glaser, Fritz; Rüland, Heinz,
Untersuchungen über Dampfdruckkurven und kritische Daten einiger technisch wichtiger organischer Substanzen,
Chemie Ing. Techn., 1957, 29, 12, 772-775, https://doi.org/10.1002/cite.330291204
. [all data]
Cunningham, 1930
Cunningham, G.V.,
Power, 1930, 72, 374. [all data]
Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E.,
The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]
Cunningham, 1930, 2
Cunningham, G.B.,
Diphenyl (C6H5-C6H5). May Solve Reheating Problem,
Power, 1930, 72, 374-377. [all data]
Nass, Lenoir, et al., 1995
Nass, Karen; Lenoir, Dieter; Kettrup, Antonius,
Calculation of the Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons by an Incremental Procedure,
Angew. Chem. Int. Ed. Engl., 1995, 34, 16, 1735-1736, https://doi.org/10.1002/anie.199517351
. [all data]
Chickos, 1975
Chickos, James Speros,
A simple equilibrium method for determining heats of sublimation,
J. Chem. Educ., 1975, 52, 2, 134-39, https://doi.org/10.1021/ed052p134
. [all data]
Clark, Knox, et al., 1975
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J.,
Heats of sublimation of some cage hydrocarbons by a temperature scanning technique,
J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107
. [all data]
Pribilová and Pouchlý, 1974
Pribilová, J.; Pouchlý, J.,
Vapour pressure of some low-volatile hydrocarbons determined by the effusion method,
Collect. Czech. Chem. Commun., 1974, 39, 5, 1118-1124, https://doi.org/10.1135/cccc19741118
. [all data]
Radchenko and Kitaigorodskii, 1974
Radchenko, L.G.; Kitaigorodskii, A.I.,
The vapour pressures and heats of sublimation of naphthalene, biphenyl, octafluoronaphthalene, decafluorobiphenyl, acenaphthene and α-nitronaphthalene,
Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 1595. [all data]
Aihara, 1959
Aihara, A.,
Estimation of the energy of hydrogen bonds formed in crystals. I. Sublimation pressures of some organic molecular crystals and the additivity of lattice energy,
Bull. Chem. Soc. Jpn., 1959, 32, 1242. [all data]
Aihara, 1955
Aihara, A.,
J. Chem. Soc. Jpn. Pure Chem. Sect., 1955, 76, 492. [all data]
Bradley and Cleasby, 1953
Bradley, R.S.; Cleasby, T.G.,
349. The vapour pressure and lattice energy of some aromatic ring compounds,
J. Chem. Soc., 1953, 1690, https://doi.org/10.1039/jr9530001690
. [all data]
Bradley and Cleasby, 1953, 2
Bradley, R.S.; Cleasby, T.G.,
The vapour pressure and lattice energy of some aromatic ring compounds,
J. Am. Chem. Soc., 1953, 1690-16. [all data]
Seki and Suzuki, 1953
Seki, Syûzô; Suzuki, Keisuke,
Physico-Chemical Studies on Molecular Compounds. III. Vapor Pressures of Diphenyl, 4, 4'-Dinitrodiphenyl, and Molecular Compound between Them,
Bull. Chem. Soc. Jpn., 1953, 26, 5, 209-213, https://doi.org/10.1246/bcsj.26.209
. [all data]
Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H.Z.,
Z. Phys. Chem. Abt. B, 1938, 39, 194. [all data]
Wolf and Weghofer, 1938, 2
Wolf, K.L.; Weghofer, H.,
Uber sublimationswarmen,
Z. Phys. Chem., 1938, 39, 194-208. [all data]
Smith, 1979
Smith, G.W.,
Phase behavior of some linear polyphenyls,
Mol. Cryst. Liq. Cryst., 1979, 49, 207-209. [all data]
Khimeche and Dahmani, 2006
Khimeche, K.; Dahmani, A.,
Determination by DSC of solid--liquid diagrams for polyaromatic -- 4,4'diaminodiphenylmethane binary systems,
J Therm Anal Calorim, 2006, 84, 1, 47-52, https://doi.org/10.1007/s10973-005-7167-9
. [all data]
Benkhennouf, Kamel, et al., 2004
Benkhennouf, M.; Kamel, K.; Dahmani, A.,
Solid-liquid phase equilibria for aromatic compounds,
J. Phys. IV France, 2004, 113, 7-9, https://doi.org/10.1051/jp4:20040002
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Eykman, 1889
Eykman, J.F.,
Zur kryoskopischen Molekulargewichtsbestimmung,
Z. Physik. Chem., 1889, 4, 497-519. [all data]
Atake, Saito, et al., 1983
Atake, T.; Saito, K.; Chihara, H.,
Low temperature heat capacities of 1,1'-biphenyl and 1,1'-biphenyl-d10,
Chem. Lett., 1983, (4), 493-496. [all data]
Ataki and Chihara, 1980
Ataki, T.; Chihara, H.,
Heat capacity anomalies due to successive phase transitions in 1,1'-biphenyl,
Solid State Commun., 1980, 35, 131-134. [all data]
Notes
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- Symbols used in this document:
Cp,gas Constant pressure heat capacity of gas Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid Pc Critical pressure S°solid,1 bar Entropy of solid at standard conditions (1 bar) Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔsubS Entropy of sublimation ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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