Dibutoxymethane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-501. ± 3.kJ/molCcbSkuratov, Strepikheev, et al., 1957Heat of formation derived by Cox and Pilcher, 1970

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-549. ± 2.kJ/molCcbSkuratov, Strepikheev, et al., 1957Heat of formation derived by Cox and Pilcher, 1970
Quantity Value Units Method Reference Comment
Δcliquid-5850.5 ± 1.7kJ/molCcbSkuratov, Strepikheev, et al., 1957Reanalyzed by Cox and Pilcher, 1970, Original value = -5852.2 kJ/mol; Combustion for liq at 293 K; Corresponding Δfliquid = -549.40 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil455.0KN/ATimmermans, 1927Uncertainty assigned by TRC = 0.6 K; source of data not clear; TRC
Tboil452.6KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Tfus214.KN/ATimmermans, 1927Uncertainty assigned by TRC = 0.3 K; TRC
Tfus215.05KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Δvap48.1kJ/molEBPalczewska-Tulinska and Szafranski, 2000Based on data from 363. to 452. K.; AC
Δvap48. ± 3.kJ/molESkuratov, Strepikheev, et al., 1957Heat of formation derived by Cox and Pilcher, 1970; ALS
Δvap48.0kJ/molN/ASkuratov, Strepikheev, et al., 1957DRB

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
47.9381.EBPalczewska-Tulinska and Szafranski, 2000Based on data from 366. to 452. K.; AC
57.3293.VSkuratov, Strepikheev, et al., 1957Combustion for liq at 293 K; ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Skuratov, Strepikheev, et al., 1957
Skuratov, S.M.; Strepikheev, A.A.; Shtekhter, S.M.; Volokhina, A.V., About the enthalpies of polymerization of cyclic formales, Dokl. Akad. Nauk SSSR, 1957, 117, 263-265. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Timmermans, 1927
Timmermans, J., The Melting Point of Organic Substances, Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]

Timmermans, 1922
Timmermans, J., Investigation of the Freezing Point of Organic Substances VII, Bull. Soc. Chim. Belg., 1922, 31, 389. [all data]

Palczewska-Tulinska and Szafranski, 2000
Palczewska-Tulinska, Marcela; Szafranski, Andrzej M., Selected Physicochemical Properties of Dibutoxymethane, J. Chem. Eng. Data, 2000, 45, 6, 988-990, https://doi.org/10.1021/je000070l . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References