Bismuthine, triethyl-

• Formula: C₆H₁₅Bi
• Molecular weight: 296.1637
• IUPAC Standard InChI: InChI=1S/3C2H5.Bi/c3*1-2;/h3*1H2,2H3; Copy

  
• IUPAC Standard InChIKey: FPYOWXFLVWSKPS-UHFFFAOYSA-N Copy
• CAS Registry Number: 617-77-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Triethylbismuth; triethylbismuthine
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

Enthalpy of fusion

Entropy of fusion

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Nistratov, Rabinovich, et al., 1989
Nistratov, V.P.; Rabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A., Specific heat and thermodyanamic characteristics of triethylbismuth, Zhur. Fiz. Khim., 1989, 63, 1779-1783. [all data]

Nistratov, Rabinovich, et al., 1989, 2
Nistratov, V.P.; Rabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A., Zh. Fiz. Khim., 1989, 1779. [all data]

Lautsch, Tröber, et al., 1964
Lautsch, W.F.; Tröber, A.; Korner, H.; Wagner, K.; Kaden, R.; Blase, S., Z. Chem., 1964, 4, 441. [all data]

Maier, Seyferth, et al., 1957
Maier, Ludwig; Seyferth, Dietmar; Stone, F.G.A.; Rochow, Eugene G., Vinyl Derivatives of the Metals. VI. Preparation, Properties and Some Reactions of Trivinyl Compounds of Group V Elements ^1,2, J. Am. Chem. Soc., 1957, 79, 22, 5884-5889, https://doi.org/10.1021/ja01579a012 . [all data]

Nistratov, Kabinovich, et al., 1989
Nistratov, V.P.; Kabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A., Heat capacity and thermodynamic characteristics of triethylbismuth, Zh. Fiz. Khim., 1989, 63, 7, 1779. [all data]

Notes

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• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°liquid	Entropy of liquid at standard conditions
  Ttriple	Triple point temperature
  ΔcH°liquid	Enthalpy of combustion of liquid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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