Urea, tetraethyl-
- Formula: C9H20N2O
- Molecular weight: 172.2679
- IUPAC Standard InChIKey: UWHSPZZUAYSGTB-UHFFFAOYSA-N
- CAS Registry Number: 1187-03-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraethylurea; 1,1,3,3-Tetraethylurea; Urea, 1,1,3,3-tetraethyl-; N,N,N',N'-Tetraethylurea
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Condensed phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -90.8 ± 1.2 | kcal/mol | Ccb | Kozyro, Simirskii, et al., 1990 | ALS |
ΔfH°liquid | -132.4 ± 1.4 | kcal/mol | Ccb | Tavernier and Lamouroux, 1956 | Reanalyzed by Cox and Pilcher, 1970, Original value = -129.51 kcal/mol; Author's hf298_condensed=-134.219 kcal/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -1438.8 ± 1.2 | kcal/mol | Ccb | Kozyro, Simirskii, et al., 1990 | ALS |
ΔcH°liquid | -1397.2 ± 1.4 | kcal/mol | Ccb | Tavernier and Lamouroux, 1956 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1400.11 kcal/mol; Author's hf298_condensed=-134.219 kcal/mol; ALS |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
84.99 | 298.15 | Kozyro, Simirskii, et al., 1990, 2 | T = 160 to 370 K. Cp(c) = 77.10 + 0.7804 T (160 to 230 K); Cp(liq) = 235.75 + 0.4019 T (290 to 370 K) J/mol*K.; DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 482. | K | N/A | Tavernier and Lamouroux, 1956, 2 | Uncertainty assigned by TRC = 0.00001 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 239.7 | K | N/A | Kabo, Kozyro, et al., 1995 | Uncertainty assigned by TRC = 0.1 K; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
15.20 ± 0.13 | 323.3 | C | Kozyro, Simirskii, et al., 1990 | ALS |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
4.9116 | 253. | Kozyro, Simirskii, et al., 1990, 2 | DH |
4.912 | 253. | Kozyro, Simirskii, et al., 1990, 3 | See also Domalski and Hearing, 1996 and Kabo, Kozyro, et al., 1995, 2.; AC |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kozyro, Simirskii, et al., 1990
Kozyro, A.A.; Simirskii, V.V.; Kabo, G.Ya.; Frenkel, M.L.; Krasulin, A.P.; Sevruk, V.M.; Sokolov, N.A.,
The additivity of the thermodynamic properties of tetra-alkyl derivatives of carbamide,
Russ. J. Phys. Chem. (Engl. Transl.), 1990, 64, 1274-1275. [all data]
Tavernier and Lamouroux, 1956
Tavernier, P.; Lamouroux, M.,
Determinations calorimetriques relatives a vingt-six substances organiques,
Mem. Poudres, 1956, 38, 65-88. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Kozyro, Simirskii, et al., 1990, 2
Kozyro, A.A.; Simirskii, V.V.; Kabo, G.Ya.; Frenkel, M.L.; Krasulin, A.P.; Sevruk, V.M.; Sokolov, N.A.,
The additivity of the thermodynamic properties of tetra-alkyl derivatives of carbamide,
Zhur. Fiz. Khim., 1990, 64(9), 2360-2365. [all data]
Tavernier and Lamouroux, 1956, 2
Tavernier, P.; Lamouroux, M.,
Meml. Poudres, 1956, 38, 65. [all data]
Kabo, Kozyro, et al., 1995
Kabo, G.Ya.; Kozyro, A.A.; Diky, V.V.; Simirsky, V.V.,
Additivity of Thermodynamic Properties of Organic Compounds in Crystalline State. 2. Heat Capacities and Enthalpies of Phase Transition of Alkyl Derivatives of Urea in Crystalline State,
J. Chem. Eng. Data, 1995, 40, 371-93. [all data]
Kozyro, Simirskii, et al., 1990, 3
Kozyro, A.A.; Simirskii, V.V.; Kabo, G.Y.; Frenkel, M.L.; Krasulin, A.P.; Sevruk, V.M.; Sokolov, N.A.,
Additivity of the thermochemical characteristics of tetraalklyl-substituted carbamides,
Zh. Fiz. Khim., 1990, 64, 2360. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Kabo, Kozyro, et al., 1995, 2
Kabo, Gennady J.; Kozyro, Alexander A.; Diky, Vladimir V.; Simirsky, Vladimir V.,
Additivity of Thermodynamic Properties of Organic Compounds in Crystalline State. 2. Heat Capacities and Enthalpies of Phase Transition of Alkyl Derivatives of Urea in Crystalline State,
J. Chem. Eng. Data, 1995, 40, 2, 371-393, https://doi.org/10.1021/je00018a005
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Tboil Boiling point Ttriple Triple point temperature ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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