Hydrazine, (2,4-dinitrophenyl)-
- Formula: C6H6N4O4
- Molecular weight: 198.1362
- IUPAC Standard InChIKey: HORQAOAYAYGIBM-UHFFFAOYSA-N
- CAS Registry Number: 119-26-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: (2,4-Dinitrophenyl)hydrazine; 1-Hydrazino-2,4-dinitrobenzene; DNP-hydrazine; 2,4-Dinitrofenylhydrazin; 2,4-DNPH; 1-(2,4-Dinitrophenyl)hydrazine; NSC 5709
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Condensed phase thermochemistry data
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 49.9 ± 3.3 | kJ/mol | Ccb | Medard and Thomas, 1954 | Heat of combustion corrected for pressure |
ΔfH°solid | 54.02 | kJ/mol | Ccb | Medard, 1954 | Heat of combustion corrected for pressure |
ΔfH°solid | 116. | kJ/mol | Cm | Fromageot and Emami, 1931 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -3268.5 ± 3.3 | kJ/mol | Ccb | Medard and Thomas, 1954 | Heat of combustion corrected for pressure |
ΔcH°solid | -3272.6 | kJ/mol | Ccb | Medard, 1954 | Heat of combustion corrected for pressure |
ΔcH°solid | -3330. | kJ/mol | Cm | Fromageot and Emami, 1931 |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference |
---|---|---|
18.89 | 474.1 | Musuc, Razus, et al., 2002 |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compiled by: Coblentz Society, Inc.
- SOLID (MINERAL OIL MULL); Not specified, most likely a prism, grating, or hybrid spectrometer.; DIGITIZED BY NIST FROM HARD COPY; 4 cm-1 resolution
- SOLID (OIL MULL); PERKIN-ELMER 521 (GRATING); DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 4 cm-1 resolution
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-1944 |
NIST MS number | 233665 |
UV/Visible spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | Pickett and Sheffield, 1946 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 12454 |
Instrument | Beckman quartz spectrometer |
Melting point | 194 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Medard and Thomas, 1954
Medard, L.; Thomas, M.,
Chaleurs de combustion de vingt-quatre substances explosives ou apparentees a des explosifs,
Mem. Poudres, 1954, 36, 97-127. [all data]
Medard, 1954
Medard, L.,
Tables thermochimiques a l'usage des techniciens des substances explosives,
Mem. Artillerie Fr. Sci. Tech. Armement, 1954, 28, 415-492. [all data]
Fromageot and Emami, 1931
Fromageot, M.Cl.; Emami, M.E.,
Sur la chaleur de combustion du methylglyoxal,
Bull. Soc. Chim. Belg., 1931, 49, 929-936. [all data]
Musuc, Razus, et al., 2002
Musuc, A.M.; Razus, D.; Oancea, D.,
Analele Universitatii Bucuresti Chimie, 2002, 11, 2, 147. [all data]
Pickett and Sheffield, 1946
Pickett, L.W.; Sheffield, E.,
J. Am. Chem. Soc., 1946, 68, 214. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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