Nitrogen

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Reaction thermochemistry data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Nitric oxide anion + Nitrogen = (Nitric oxide anion • Nitrogen)

By formula: NO- + N2 = (NO- • N2)

Quantity Value Units Method Reference Comment
ΔrH°4.6 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrH°4.7kcal/molDTGheno and Fitaire, 1987gas phase; ΔrS+-2.9 cal/mol*K; M
ΔrH°4.4kcal/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
ΔrH°5.2kcal/molHPMSTurner and Conway, 1976gas phase; M
ΔrH°4.5kcal/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°17.0cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrS°13.8cal/mol*KDTGheno and Fitaire, 1987gas phase; ΔrS+-2.9 cal/mol*K; M
ΔrS°13.3cal/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
ΔrS°18.9cal/mol*KHPMSTurner and Conway, 1976gas phase; M
ΔrS°15.7cal/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.5200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

Nitrogen cation + Nitrogen = (Nitrogen cation • Nitrogen)

By formula: N2+ + N2 = (N2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°24.4 to 24.4kcal/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°21.0cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°16.2cal/mol*KPHPMSTeng and Conway, 1973gas phase; M
ΔrS°19.5cal/mol*KPHPMSPayzant and Kebarle, 1970gas phase; M
ΔrS°11.cal/mol*KDTVarney, 1968gas phase; Entropy change is questionable; M
ΔrS°-1.cal/mol*KDTVarney, 1959gas phase; Entropy change is questionable; M

Oxygen cation + Nitrogen = (Oxygen cation • Nitrogen)

By formula: O2+ + N2 = (O2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°5.0 ± 0.3kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°5.2kcal/molHPMSSpeller and Fitaire, 1983gas phase; M
ΔrH°5.7kcal/molPHPMSJanik and Conway, 1967gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°17.4cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°15.8cal/mol*KHPMSSpeller and Fitaire, 1983gas phase; M
ΔrS°18.9cal/mol*KPHPMSJanik and Conway, 1967gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0296.FAHoward, Bierbaum, et al., 1972gas phase; M

(HN2+ • 4Nitrogen) + Nitrogen = (HN2+ • 5Nitrogen)

By formula: (HN2+ • 4N2) + N2 = (HN2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°3.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°3.2kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°20.cal/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
1.492.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

(Oxygen anion • 7Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 8Nitrogen • Oxygen)

By formula: (O2- • 7N2 • O2) + N2 = (O2- • 8N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°1.6 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
ΔrH°1.53kcal/molPHPMSHiraoka, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°17.9cal/mol*KPHPMSHiraoka, 1988gas phase; M
ΔrS°18.0cal/mol*KN/AHiraoka, 1988gas phase; Entropy change calculated or estimated; M

(Oxygen cation • 2Nitrogen) + Nitrogen = (Oxygen cation • 3Nitrogen)

By formula: (O2+ • 2N2) + N2 = (O2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°4.2 ± 0.3kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°3.5kcal/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°19.6cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°12.1cal/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • Nitrogen) + Nitrogen = (Oxygen cation • 2Nitrogen)

By formula: (O2+ • N2) + N2 = (O2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°4.5 ± 0.3kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°4.3kcal/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°19.1cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°13.8cal/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion • Nitrogen) + Nitrogen = (Nitric oxide anion • 2Nitrogen)

By formula: (NO- • N2) + N2 = (NO- • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°4.2 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrH°3.9kcal/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°17.4cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrS°12.6cal/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

C3N2NiO3 (solution) = C3NiO3 (solution) + Nitrogen (solution)

By formula: C3N2NiO3 (solution) = C3NiO3 (solution) + N2 (solution)

Quantity Value Units Method Reference Comment
ΔrH°10. ± 1.kcal/molKinSTurner, Simpson, et al., 1983solvent: Liquid krypton; The reaction enthalpy relies on the experimental value for the activation enthalpy, 10. ± 1. kcal/mol, and on the assumption that the activation enthalpy for product recombination is negligible Turner, Simpson, et al., 1983.; MS

N+ + Nitrogen = (N+ • Nitrogen)

By formula: N+ + N2 = (N+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°59.4kcal/molN/ANational Bureau of Standards, 1968gas phase; from ΔrH(f); M
ΔrH°60.kcal/molEISaporoschenko, 1965gas phase; M
ΔrH°59.kcal/molEIFranklin, Dibeler, et al., 1958gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
86.2 (+1.8,-0.) CIDHaynes, Freysinger, et al., 1995gas phase; guided ion beam CID; M

Copper ion (1+) + Nitrogen = (Copper ion (1+) • Nitrogen)

By formula: Cu+ + N2 = (Cu+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°6.2kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
ΔrS°16.cal/mol*KHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
ΔrG°1.4kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M

(HN2+ • 2Nitrogen) + Nitrogen = (HN2+ • 3Nitrogen)

By formula: (HN2+ • 2N2) + N2 = (HN2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°3.4 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°3.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°20.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 3Nitrogen) + Nitrogen = (HN2+ • 4Nitrogen)

By formula: (HN2+ • 3N2) + N2 = (HN2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°3.3 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°3.5kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°20.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • Nitrogen) + Nitrogen = (HN2+ • 2Nitrogen)

By formula: (HN2+ • N2) + N2 = (HN2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°3.6 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°4.0kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°19.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°18.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°8.0kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.6cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.2310.FAPerry, Rowe, et al., 1980gas phase; M
2.0310.DTBeyer and Keller, 1971gas phase; low E/N; M

HN2+ + Nitrogen = (HN2+ • Nitrogen)

By formula: HN2+ + N2 = (HN2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°16.0kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrH°14.5kcal/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrS°20.4cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

C39H66N2O3P2W (solution) + Hydrogen (g) = C39H68O3P2W (solution) + Nitrogen (g)

By formula: C39H66N2O3P2W (solution) + H2 (g) = C39H68O3P2W (solution) + N2 (g)

Quantity Value Units Method Reference Comment
ΔrH°4.40 ± 0.41kcal/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 288-308 K; MS

C39H66MoO3P3 (solution) + Nitrogen (g) = C39H66MoN2O3P2 (solution)

By formula: C39H66MoO3P3 (solution) + N2 (g) = C39H66MoN2O3P2 (solution)

Quantity Value Units Method Reference Comment
ΔrH°-9.01 ± 0.60kcal/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 294-308 K; MS

(Hydronium cation • 2Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 3Water)

By formula: (H3O+ • 2N2 • 3H2O) + N2 = (H3O+ • 3N2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°1.2kcal/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
ΔrS°6.4cal/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Oxygen cation • 4Nitrogen) + Nitrogen = (Oxygen cation • 5Nitrogen)

By formula: (O2+ • 4N2) + N2 = (O2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°2.7 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°16.2cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.7184.HPMSSpeller and Fitaire, 1983gas phase; M

(Nitric oxide anion • 2Nitrogen) + Nitrogen = (Nitric oxide anion • 3Nitrogen)

By formula: (NO- • 2N2) + N2 = (NO- • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°3.8 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°16.8cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.9204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 3Nitrogen) + Nitrogen = (Nitric oxide anion • 4Nitrogen)

By formula: (NO- • 3N2) + N2 = (NO- • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°3.4 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°17.9cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.4204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Oxygen cation • 3Nitrogen) + Nitrogen = (Oxygen cation • 4Nitrogen)

By formula: (O2+ • 3N2) + N2 = (O2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°4.0 ± 0.3kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.5cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.7204.HPMSSpeller and Fitaire, 1983gas phase; M

(Hydronium cation • 3Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 4Nitrogen • 2Water)

By formula: (H3O+ • 3N2 • 2H2O) + N2 = (H3O+ • 4N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°3.kcal/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
ΔrS°12.cal/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Nitric oxide anion • 9Nitrogen) + Nitrogen = (Nitric oxide anion • 10Nitrogen)

By formula: (NO- • 9N2) + N2 = (NO- • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°1.68kcal/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°19.cal/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

(HN2+ • 10Nitrogen) + Nitrogen = (HN2+ • 11Nitrogen)

By formula: (HN2+ • 10N2) + N2 = (HN2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°1.72kcal/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°22.cal/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
ΔrH°2.70 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°18.4cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-2.80 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(C2H5+ • Nitrogen) + Nitrogen = (C2H5+ • 2Nitrogen)

By formula: (C2H5+ • N2) + N2 = (C2H5+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°4.6kcal/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°10.9cal/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M

(Nitrogen cation • Nitrogen) + Nitrogen = (Nitrogen cation • 2Nitrogen)

By formula: (N2+ • N2) + N2 = (N2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°2.8 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°1.4kcal/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.0cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • Oxygen) + Nitrogen = (Oxygen cation • Nitrogen • Oxygen)

By formula: (O2+ • O2) + N2 = (O2+ • N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°2.9kcal/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°10.1cal/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°5.3kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°16.8cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
-0.3310.FAPerry, Rowe, et al., 1980gas phase; M

(CH2N+ • 2Nitrogen) + Nitrogen = (CH2N+ • 3Nitrogen)

By formula: (CH2N+ • 2N2) + N2 = (CH2N+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°3.2kcal/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°13.1cal/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 3Nitrogen) + Nitrogen = (CH2N+ • 4Nitrogen)

By formula: (CH2N+ • 3N2) + N2 = (CH2N+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°3.1kcal/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°13.8cal/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 4Nitrogen) + Nitrogen = (CH2N+ • 5Nitrogen)

By formula: (CH2N+ • 4N2) + N2 = (CH2N+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°3.2kcal/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°15.2cal/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

2,5-Pyrrolidinedione, 1-bromo- + 0.5Hydrazine = Hydrogen bromide + Succinimide + 0.5Nitrogen

By formula: C4H4BrNO2 + 0.5H4N2 = HBr + C4H5NO2 + 0.5N2

Quantity Value Units Method Reference Comment
ΔrH°-62.22 ± 0.11kcal/molCmHoward and Skinner, 1966solid phase; solvent: Aqueous solution; Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -62.55 ± 0.11 kcal/mol; ALS

Oxygen anion + Nitrogen = (Oxygen anion • Nitrogen)

By formula: O2- + N2 = (O2- • N2)

Quantity Value Units Method Reference Comment
ΔrH°6.0 ± 1.0kcal/molN/APosey and Johnson, 1988gas phase; B
ΔrH°<13.60kcal/molIMRBAdams and Bohme, 1970gas phase; N2..O2- + O2 -> O4-; B

C12H34P4Ru (solution) + Nitrogen (solution) = C12H32N2P4Ru (solution) + Hydrogen (solution)

By formula: C12H34P4Ru (solution) + N2 (solution) = C12H32N2P4Ru (solution) + H2 (solution)

Quantity Value Units Method Reference Comment
ΔrH°3.90kcal/molPACBelt, Scaiano, et al., 1993solvent: Cyclohexane; The reaction enthalpy relies on 0.85 for the quantum yield of H2 dissociation.; MS

(Hydronium cation • 2Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 2Water)

By formula: (H3O+ • 2N2 • 2H2O) + N2 = (H3O+ • 3N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°9.0 ± 2.7kcal/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.4cal/mol*KDTGheno and Fitaire, 1987gas phase; M

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Nitrogen (solution) = C8H5N2O3V (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + N2 (solution) = C8H5N2O3V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
ΔrH°6.5 ± 1.kcal/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.; MS

(Oxygen anion • 2Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 3Nitrogen • Oxygen)

By formula: (O2- • 2N2 • O2) + N2 = (O2- • 3N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°2.5 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.3cal/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 3Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 4Nitrogen • Oxygen)

By formula: (O2- • 3N2 • O2) + N2 = (O2- • 4N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°2.2 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 4Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 5Nitrogen • Oxygen)

By formula: (O2- • 4N2 • O2) + N2 = (O2- • 5N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°1.9 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°19.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 5Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 6Nitrogen • Oxygen)

By formula: (O2- • 5N2 • O2) + N2 = (O2- • 6N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°1.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°19.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 6Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 7Nitrogen • Oxygen)

By formula: (O2- • 6N2 • O2) + N2 = (O2- • 7N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°1.7 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.8cal/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 2Nitrogen • Oxygen)

By formula: (O2- • N2 • O2) + N2 = (O2- • 2N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°2.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°17.9cal/mol*KPHPMSHiraoka, 1988gas phase; M

(Hydronium cation • 2Nitrogen • Water) + Nitrogen = (Hydronium cation • 3Nitrogen • Water)

By formula: (H3O+ • 2N2 • H2O) + N2 = (H3O+ • 3N2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 2.kcal/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.cal/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 2Water)

By formula: (H3O+ • N2 • 2H2O) + N2 = (H3O+ • 2N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°5.2kcal/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°16.6cal/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 3Water)

By formula: (H3O+ • N2 • 3H2O) + N2 = (H3O+ • 2N2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°4.4kcal/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.7cal/mol*KDTGheno and Fitaire, 1987gas phase; M

(Oxygen cation • 10Nitrogen) + Nitrogen = (Oxygen cation • 11Nitrogen)

By formula: (O2+ • 10N2) + N2 = (O2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°1.4 ± 0.3kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.2cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 10Nitrogen) + Nitrogen = (Nitrogen cation • 11Nitrogen)

By formula: (N2+ • 10N2) + N2 = (N2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°1.7 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.2cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Mass spectrum (electron ionization)

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

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Origin D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY
NIST MS number 61309

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References

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., How are Nitrogen Molecules Bound to NO2+ and NO+?, J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880 . [all data]

Gheno and Fitaire, 1987
Gheno, F.; Fitaire, M., Association of N2 with NH4+ and H3O+(H2O)n, n = 1,2,3, J. Chem. Phys., 1987, 87, 2, 953, https://doi.org/10.1063/1.453250 . [all data]

Speller, Fitaire, et al., 1983
Speller, C.V.; Fitaire, M.; Pointu, A.M., Three - Body Association Reactions of NO+ and O2+ with N2, J. Chem. Phys., 1983, 79, 5, 2190, https://doi.org/10.1063/1.446067 . [all data]

Turner and Conway, 1976
Turner, D.L.; Conway, D.C., Stability of the NO+.N2 Ion Cluster, J. Chem. Phys., 1976, 65, 10, 3944, https://doi.org/10.1063/1.432887 . [all data]

Johnsen, Huang, et al., 1975
Johnsen, R.; Huang, C.M.; Biondi, M.A., The Formation and Breakup of NO2+.N2 Clusters in N2 at Low Temperatures, J. Chem. Phys., 1975, 63, 8, 3374, https://doi.org/10.1063/1.431751 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Dunkin, Fehsenfeld, et al., 1971
Dunkin, D.B.; Fehsenfeld, F.C.; Schelmetekopf, A.L.; Ferguson, E.E., Three-Body Association Reactions of NO+ with O2, N2, and CO2, J. Chem. Phys., 1971, 54, 9, 3817, https://doi.org/10.1063/1.1675432 . [all data]

Hiraoka and Nakajima, 1988
Hiraoka, K.; Nakajima, G., A Determination of the Stabilities of N2+(N2)n and O2+(N2)n with n = 1 - 11 from Measurements of the Gas - Phase Ion Equilibria, J. Chem. Phys., 1988, 88, 12, 7709, https://doi.org/10.1063/1.454285 . [all data]

Teng and Conway, 1973
Teng, H.H.; Conway, D.C., Ion - Molecule Equilibria in Mixtures of N2 and Ar, J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338 . [all data]

Payzant and Kebarle, 1970
Payzant, J.D.; Kebarle, P., Clustering Equilibrium N2+ + 2N2 = N4+ + N2 and the Bond Dissociation Energy of N4+, J. Chem. Phys., 1970, 53, 12, 4723, https://doi.org/10.1063/1.1674010 . [all data]

Varney, 1968
Varney, R.N., Equilibrium Constant and Rates for the Reversible Reaction N4+ -> N2+ + N2, Phys. Rev., 1968, 174, 1, 165, https://doi.org/10.1103/PhysRev.174.165 . [all data]

Varney, 1959
Varney, R.N., Molecular Ions, J. Chem. Phys., 1959, 31, 5, 1314, https://doi.org/10.1063/1.1730590 . [all data]

Speller and Fitaire, 1983
Speller, C.V.; Fitaire, M., Proceedings of the 16th International Conference on Phenomena of Ionized Gases, H. Boetticher, H. Wenk and E. Shulz - Gulde, ed(s)., ICPIG, Dusseldorf, 1983, 568. [all data]

Janik and Conway, 1967
Janik, G.S.; Conway, D.C., Bonding in Heteromolecular Ion Clusters. N2O2+, J. Phys. Chem., 1967, 71, 4, 823, https://doi.org/10.1021/j100863a007 . [all data]

Howard, Bierbaum, et al., 1972
Howard, C.J.; Bierbaum, V.M.; Rundle, H.W.; Kaufman, F., Kinetics and Mechanism of Formation of Water Cluster Ions from O2+ and H2O+, J. Chem. Phys., 1972, 57, 8, 3491, https://doi.org/10.1063/1.1678783 . [all data]

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Turner, Simpson, et al., 1983
Turner, J.J.; Simpson, M.B.; Poliakoff, M.; Maier II, W.B., J. Am. Chem. Soc., 1983, 105, 3898. [all data]

National Bureau of Standards, 1968
National Bureau of Standards, US, Technical Note 270 - 3 in The NBS Tables of Chemical Thermodynamic Properties, 1968. [all data]

Saporoschenko, 1965
Saporoschenko, M., Mobility of Mass Analyzed N+, N2+, N3+, and N4+ Ions in Nitrogen Gas, Phys. Rev. A, 1965, 139, 352. [all data]

Franklin, Dibeler, et al., 1958
Franklin, J.L.; Dibeler, V.H.; Reese, R.M.; Krauss, M., Ionization and dissociation of hydrazoic acid and methyl azide by electron impact, J. Am. Chem. Soc., 1958, 80, 298. [all data]

Haynes, Freysinger, et al., 1995
Haynes, C.L.; Freysinger, W.; Armentrout, P.B., Collision-induced dissociation of N3+(X3-) with Ne, Ar, Kr, and Xe, Int. J. Mass Spectrom. Ion Processes, 1995, 149/150, 267. [all data]

El-Shall, Schriver, et al., 1989
El-Shall, M.S.; Schriver, K.E.; Whetten, R.L.; Meot-Ner (Mautner), M., Ion/Molecule Clustering Thermochemistry by Laser Ionization High - Pressure Mass Spectrometry, J. Phys. Chem., 1989, 93, 24, 7969, https://doi.org/10.1021/j100361a002 . [all data]

Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., Laboratory Measurements of Stratospheric Sodium Ion Measurements, Geophys. Res. Lett., 1980, 7, 9, 693, https://doi.org/10.1029/GL007i009p00693 . [all data]

Beyer and Keller, 1971
Beyer, R.A.; Keller, G.E., The Clustering of Atmospheric Gases to Alkali Ions, Trans. Am. Geophys. Union, 1971, 52, 303. [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Gonzalez and Hoff, 1989
Gonzalez, A.A.; Hoff, C.D., Inorg. Chem., 1989, 28, 4295. [all data]

Speller, 1983
Speller, C.V., Ph. D. Thesis, Universite de Paris Sud, 1983. [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]

Speller, Fitaire, et al., 1982
Speller, C.V.; Fitaire, M.; Pointu, A.M., H2CN+.nN2 Clustering Formation and the Atmosphere of Titan, Nature, 1982, 300, 5892, 507, https://doi.org/10.1038/300507a0 . [all data]

Howard and Skinner, 1966
Howard, P.B.; Skinner, H.A., Thermochemistry of some reactions of aqueous hydrazine with halogens, hydrogen halides and N-halogenosuccinimides, J. Chem. Soc. A, 1966, 1536-1540. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Posey and Johnson, 1988
Posey, L.A.; Johnson, M.A., Pulsed Photoelectron Spectroscopy of Negative Cluster Ions: Isolation of Three Distinguishable Forms of N2O2-, J. Chem. Phys., 1988, 88, 9, 5385, https://doi.org/10.1063/1.454576 . [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Belt, Scaiano, et al., 1993
Belt, S.T.; Scaiano, J.C.; Whittlesey, M.K., J. Am. Chem. Soc., 1993, 115, 1921. [all data]

Johnson, Popov, et al., 1991
Johnson, F.P.A.; Popov, V.K.; George, M.W.; Bagratashvili, V.N.; Poliakoff, M.; Turner, J.J., Mendeleev Commun., 1991, 145.. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References