7-Methylenebicyclo[2.2.1]-heptane
- Formula: C8H12
- Molecular weight: 108.1809
- IUPAC Standard InChIKey: JSASFGPUXQDHEC-UHFFFAOYSA-N
- CAS Registry Number: 31463-35-1
- Chemical structure:
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔcH°liquid | -1667.0 ± 0.5 | kcal/mol | Ccb | Belikova, Gazuko, et al., 1975 | Corresponding ΔfHºliquid = 504.7 kcal/mol (simple calculation by NIST; no Washburn corrections) |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | 4.7 ± 0.5 | kcal/mol | Ccb | Kozina, Bychikhina, et al., 1977 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -1167.0 ± 0.5 | kcal/mol | Ccb | Kozina, Bychikhina, et al., 1977 | Corresponding ΔfHºsolid = 4.7 kcal/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 9.7 ± 0.5 | kcal/mol | V | Kozina, Bychikhina, et al., 1977 | ALS |
ΔsubH° | 9.56 | kcal/mol | N/A | Kozina, Bychikhina, et al., 1977 | DRB |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Belikova, Gazuko, et al., 1975
Belikova, N.A.; Gazuko, I.V.; Ranneva, Yu.I.; Bychikhina, L.V.; Kozina, M.P.; Plate, A.F.,
The relative thermodynamic stabilities of unsaturated hydrocarbons of the bicyclo-[2.2.1]heptane and bicyclo[2.2.2]octane series,
J. Org. Chem. USSR (Engl. Transl.), 1975, 10, 1689-1696. [all data]
Kozina, Bychikhina, et al., 1977
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.,
The enthalpies of combustion and formation of 2,2-dimethyl-3-methylene bicyclo[2,2,1]heptane and 7-methylenebicyclo[2,2,1]heptane,
Russ. J. Phys. Chem. (Engl. Transl.), 1977, 51, 1258-1259. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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