m-Terphenyl

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfsolid38.62 ± 0.74kcal/molReviewRoux, Temprado, et al., 2008There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
99.69370.Walker, Brooks, et al., 1958T = 200 to 600°F.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil652.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus359. ± 3.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tc883. ± 10.KN/ATsonopoulos and Ambrose, 1995 
Tc883.KN/AReiter, 1963Uncertainty assigned by TRC = 10. K; TRC
Tc924.8KN/AMandel and Ewbank, 1960Uncertainty assigned by TRC = 16.7 K; TRC
Quantity Value Units Method Reference Comment
Pc24. ± 5.atmN/ATsonopoulos and Ambrose, 1995 
Pc24.48atmN/AReiter, 1963Uncertainty assigned by TRC = 5.0000 atm; TRC
Pc34.54atmN/AMandel and Ewbank, 1960Uncertainty assigned by TRC = 6.805 atm; TRC
Quantity Value Units Method Reference Comment
Vc0.724l/molN/ATsonopoulos and Ambrose, 1995 
Quantity Value Units Method Reference Comment
ρc1.4 ± 0.5mol/lN/ATsonopoulos and Ambrose, 1995 
ρc1.38mol/lN/AReiter, 1963Uncertainty assigned by TRC = 0.087 mol/l; TRC
ρc1.30mol/lN/AMandel and Ewbank, 1960Uncertainty assigned by TRC = 0.13 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap23.2 ± 0.07kcal/molCGCPuri, Chickos, et al., 2001AC
Quantity Value Units Method Reference Comment
Δsub28.3 ± 0.2kcal/molMERibeiro da Silva, Santos, et al., 2008Based on data from 337. to 359. K.; AC
Δsub28.30 ± 0.57kcal/molReviewRoux, Temprado, et al., 2008There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB
Δsub28.23 ± 0.38kcal/molN/AVerevkin, 1997AC
Δsub28.7 ± 0.2kcal/molN/AKimura and Takagi, 1979AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
18.2477.AStephenson and Malanowski, 1987Based on data from 462. to 691. K.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
27.61 ± 0.38341.TVerevkin, 1997Based on data from 329. to 353. K.; AC
28.4338.N/AHoyer and Peperle, 1958Based on data from 313. to 363. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
7.41361.2DSCVerevkin, 1997AC
5.399360.N/AKambe, Mita, et al., 1971AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y., Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons, J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]

Walker, Brooks, et al., 1958
Walker, B.E., Jr.; Brooks, M.S.; Ewing, C.T.; Miller, R.R., Specific heat of biphenyl and other polyphenyls. Correlation of specific heat data for phenyl type compounds, J. Chem. Eng. Data, 1958, 3, 280-282. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Tsonopoulos and Ambrose, 1995
Tsonopoulos, C.; Ambrose, D., Vapor-Liquid Critical Properties of Elements and Compounds. 3. Aromatic Hydrocarbons, J. Chem. Eng. Data, 1995, 40, 547-558. [all data]

Reiter, 1963
Reiter, R.W., , NASA Doc. N63-19495 1963 1963, 1963. [all data]

Mandel and Ewbank, 1960
Mandel, H.; Ewbank, N., , Atomics International NAA-S-R-5129 1960, 1960. [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Ribeiro da Silva, Santos, et al., 2008
Ribeiro da Silva, Manuel A.V.; Santos, Luís M.N.B.F.; Lima, Luís M. Spencer S., Standard molar enthalpies of formation and of sublimation of the terphenyl isomers, The Journal of Chemical Thermodynamics, 2008, 40, 3, 375-385, https://doi.org/10.1016/j.jct.2007.08.008 . [all data]

Verevkin, 1997
Verevkin, S.P., Thermochemistry of substituted benzenes. Experimental standard molar enthalpies of formation of o-, m-, and p-terphenyls and 1,3,5-triphenylbenzene, J. Chem. Thermodyn., 1997, 29, 1495-1501. [all data]

Kimura and Takagi, 1979
Kimura, Takayoshi; Takagi, Sadao, Enthalpies of solution of o-, m-, and p-terphenyls in benzene at 298.15 K, The Journal of Chemical Thermodynamics, 1979, 11, 1, 47-55, https://doi.org/10.1016/0021-9614(79)90082-X . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hoyer and Peperle, 1958
Hoyer, H.; Peperle, W., Z. Elektrochem., 1958, 62, 61. [all data]

Kambe, Mita, et al., 1971
Kambe, H.; Mita, I.; Yokata, R., , Proceedings of the Third ICTAC, Davos Swizz, 1971, 387. [all data]


Notes

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