Norbornane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-95.0 ± 1.1kJ/molCcbAn, Zhu, et al., 1987ALS
Δfsolid-102.0 ± 3.3kJ/molCcbSteele, 1978ALS
Δfsolid-92.1 ± 2.2kJ/molCcbBoyd, Sanwal, et al., 1971ALS
Δfsolid-92.1 ± 2.7kJ/molCcbBedford, Beezer, et al., 1963see also Boyd, Sanwal, et al., 1971; ALS
Quantity Value Units Method Reference Comment
Δcsolid-4374.59 ± 0.97kJ/molCcbAn, Zhu, et al., 1987Corresponding Δfsolid = -94.96 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-4367.5 ± 3.3kJ/molCcbSteele, 1978Corresponding Δfsolid = -102.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-4377.5 ± 2.2kJ/molCcbBedford, Beezer, et al., 1963see also Boyd, Sanwal, et al., 1971; Corresponding Δfsolid = -92.09 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
151.0298.15Steele, 1978DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil381.KN/ADesty and Whyman, 1957Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus360.KN/ABurwell, Shim, et al., 1957Uncertainty assigned by TRC = 2. K; TRC
Tfus360.9KN/ABirch and Dean, 1954Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Δsub41. ± 5.kJ/molAVGN/AAverage of 8 values; Individual data points

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
40.3 ± 0.4293.GSVerevkin and Emel'yanenko, 2004Based on data from 278. to 308. K.; AC
40.0 ± 0.8305.TSGCClark, Knox, et al., 1975Based on data from 284. to 326. K.; AC
40.1 ± 0.84284.VBoyd, Sanwal, et al., 1971ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
4.45360.8DSCVerevkin and Emel'yanenko, 2004AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

An, Zhu, et al., 1987
An, X-W.; Zhu, H-P.; Hu, R-H., Heats of combustion and formation of norbornane, Thermochim. Acta, 1987, 121, 473-477. [all data]

Steele, 1978
Steele, W.V., The standard enthalpies of formation of a series of C7, bridged-ring hydrocarbons: norbornane, norbornene, nortricyclene, norbornadiene, and quadricyclane, J. Chem. Thermodyn., 1978, 10, 919-927. [all data]

Boyd, Sanwal, et al., 1971
Boyd, R.H.; Sanwal, S.N.; Shary-Tehrany, S.; McNally, D., The thermochemistry, thermodynamic functions, and molecular structures of some cyclic hydrocarbons, J. Phys. Chem., 1971, 75, 1264-1271. [all data]

Bedford, Beezer, et al., 1963
Bedford, A.F.; Beezer, A.E.; Mortimer, C.T.; Springall, H.D., Heats of combustion and molecular structure. Part IX. Bicylo[2,2,1]heptane, 7-oxabicyclo[2,2,1]heptane, and exo- and endo-2-methyl-7-oxabicyclo[2,2,1]heptane, J. Chem. Soc., 1963, 3823-3828. [all data]

Desty and Whyman, 1957
Desty, D.H.; Whyman, B.H.F., Anal. Chem., 1957, 29, 320. [all data]

Burwell, Shim, et al., 1957
Burwell, R.L.; Shim, B.K.C.; Rowlinson, H.C., The Exchange between Hydrocarbons and Deuterium on Plladium Catalysts, J. Am. Chem. Soc., 1957, 79, 5142. [all data]

Birch and Dean, 1954
Birch, S.F.; Dean, R.A., A Ring Clousre Reaction by Desulfurization with Raney Nickel, Justus Liebigs Ann. Chem., 1954, 585, 234. [all data]

Verevkin and Emel'yanenko, 2004
Verevkin, Sergey P.; Emel'yanenko, Vladimir N., Enthalpy of Formation and Strain of Norbornane from Thermochemical Measurements and from ab Initio Calculations, J. Phys. Chem. A, 2004, 108, 31, 6575-6580, https://doi.org/10.1021/jp0490554 . [all data]

Clark, Knox, et al., 1975
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J., Heats of sublimation of some cage hydrocarbons by a temperature scanning technique, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107 . [all data]


Notes

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