Nitrogen

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Reaction thermochemistry data

Go To: Top, Henry's Law data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Nitric oxide anion + Nitrogen = (Nitric oxide anion • Nitrogen)

By formula: NO- + N2 = (NO- • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr20.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
Δr18.kJ/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Δr22.kJ/molHPMSTurner and Conway, 1976gas phase; M
Δr19.kJ/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr57.7J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
Δr55.6J/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Δr79.1J/mol*KHPMSTurner and Conway, 1976gas phase; M
Δr65.7J/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

Nitrogen cation + Nitrogen = (Nitrogen cation • Nitrogen)

By formula: N2+ + N2 = (N2+ • N2)

Quantity Value Units Method Reference Comment
Δr102. to 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr67.8J/mol*KPHPMSTeng and Conway, 1973gas phase; M
Δr81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase; M
Δr46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable; M
Δr-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable; M

Oxygen cation + Nitrogen = (Oxygen cation • Nitrogen)

By formula: O2+ + N2 = (O2+ • N2)

Quantity Value Units Method Reference Comment
Δr21. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr22.kJ/molHPMSSpeller and Fitaire, 1983gas phase; M
Δr24.kJ/molPHPMSJanik and Conway, 1967gas phase; M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr66.1J/mol*KHPMSSpeller and Fitaire, 1983gas phase; M
Δr79.1J/mol*KPHPMSJanik and Conway, 1967gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0296.FAHoward, Bierbaum, et al., 1972gas phase; M

(HN2+ • 4Nitrogen) + Nitrogen = (HN2+ • 5Nitrogen)

By formula: (HN2+ • 4N2) + N2 = (HN2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr12. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr13.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr84.J/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.992.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

(Oxygen anion • 7Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 8Nitrogen • Oxygen)

By formula: (O2- • 7N2 • O2) + N2 = (O2- • 8N2 • O2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Δr6.40kJ/molPHPMSHiraoka, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, 1988gas phase; M
Δr75.3J/mol*KN/AHiraoka, 1988gas phase; Entropy change calculated or estimated; M

(Oxygen cation • 2Nitrogen) + Nitrogen = (Oxygen cation • 3Nitrogen)

By formula: (O2+ • 2N2) + N2 = (O2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr18. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr15.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr50.6J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • Nitrogen) + Nitrogen = (Oxygen cation • 2Nitrogen)

By formula: (O2+ • N2) + N2 = (O2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr18.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr57.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion • Nitrogen) + Nitrogen = (Nitric oxide anion • 2Nitrogen)

By formula: (NO- • N2) + N2 = (NO- • 2N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr16.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr52.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

C3N2NiO3 (solution) = C3NiO3 (solution) + Nitrogen (solution)

By formula: C3N2NiO3 (solution) = C3NiO3 (solution) + N2 (solution)

Quantity Value Units Method Reference Comment
Δr42. ± 4.kJ/molKinSTurner, Simpson, et al., 1983solvent: Liquid krypton; The reaction enthalpy relies on the experimental value for the activation enthalpy, 42. ± 4. kJ/mol, and on the assumption that the activation enthalpy for product recombination is negligible Turner, Simpson, et al., 1983.; MS

N+ + Nitrogen = (N+ • Nitrogen)

By formula: N+ + N2 = (N+ • N2)

Quantity Value Units Method Reference Comment
Δr249.kJ/molN/ANational Bureau of Standards, 1968gas phase; from ΔrH(f); M
Δr250.kJ/molEISaporoschenko, 1965gas phase; M
Δr250.kJ/molEIFranklin, Dibeler, et al., 1958gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
361. (+7.5,-0.) CIDHaynes, Freysinger, et al., 1995gas phase; guided ion beam CID; M

Copper ion (1+) + Nitrogen = (Copper ion (1+) • Nitrogen)

By formula: Cu+ + N2 = (Cu+ • N2)

Quantity Value Units Method Reference Comment
Δr26.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
Δr67.J/mol*KHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
Δr5.9kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M

(HN2+ • 2Nitrogen) + Nitrogen = (HN2+ • 3Nitrogen)

By formula: (HN2+ • 2N2) + N2 = (HN2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr16.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr84.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 3Nitrogen) + Nitrogen = (HN2+ • 4Nitrogen)

By formula: (HN2+ • 3N2) + N2 = (HN2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr15.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • Nitrogen) + Nitrogen = (HN2+ • 2Nitrogen)

By formula: (HN2+ • N2) + N2 = (HN2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr15. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr17.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr75.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
Δr33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

HN2+ + Nitrogen = (HN2+ • Nitrogen)

By formula: HN2+ + N2 = (HN2+ • N2)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Δr60.7kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Δr85.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

C39H66N2O3P2W (solution) + Hydrogen (g) = C39H68O3P2W (solution) + Nitrogen (g)

By formula: C39H66N2O3P2W (solution) + H2 (g) = C39H68O3P2W (solution) + N2 (g)

Quantity Value Units Method Reference Comment
Δr18.4 ± 1.7kJ/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 288-308 K; MS

C39H66MoO3P3 (solution) + Nitrogen (g) = C39H66MoN2O3P2 (solution)

By formula: C39H66MoO3P3 (solution) + N2 (g) = C39H66MoN2O3P2 (solution)

Quantity Value Units Method Reference Comment
Δr-37.7 ± 2.5kJ/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 294-308 K; MS

(Hydronium cation • 2Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 3Water)

By formula: (H3O+ • 2N2 • 3H2O) + N2 = (H3O+ • 3N2 • 3H2O)

Quantity Value Units Method Reference Comment
Δr5.0kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr27.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Oxygen cation • 4Nitrogen) + Nitrogen = (Oxygen cation • 5Nitrogen)

By formula: (O2+ • 4N2) + N2 = (O2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr67.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.184.HPMSSpeller and Fitaire, 1983gas phase; M

(Nitric oxide anion • 2Nitrogen) + Nitrogen = (Nitric oxide anion • 3Nitrogen)

By formula: (NO- • 2N2) + N2 = (NO- • 3N2)

Quantity Value Units Method Reference Comment
Δr16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr70.3J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 3Nitrogen) + Nitrogen = (Nitric oxide anion • 4Nitrogen)

By formula: (NO- • 3N2) + N2 = (NO- • 4N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Oxygen cation • 3Nitrogen) + Nitrogen = (Oxygen cation • 4Nitrogen)

By formula: (O2+ • 3N2) + N2 = (O2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.204.HPMSSpeller and Fitaire, 1983gas phase; M

(Hydronium cation • 3Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 4Nitrogen • 2Water)

By formula: (H3O+ • 3N2 • 2H2O) + N2 = (H3O+ • 4N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr10.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr50.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Nitric oxide anion • 9Nitrogen) + Nitrogen = (Nitric oxide anion • 10Nitrogen)

By formula: (NO- • 9N2) + N2 = (NO- • 10N2)

Quantity Value Units Method Reference Comment
Δr7.03kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr79.J/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

(HN2+ • 10Nitrogen) + Nitrogen = (HN2+ • 11Nitrogen)

By formula: (HN2+ • 10N2) + N2 = (HN2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr7.20kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(C2H5+ • Nitrogen) + Nitrogen = (C2H5+ • 2Nitrogen)

By formula: (C2H5+ • N2) + N2 = (C2H5+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19.kJ/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr45.6J/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M

(Nitrogen cation • Nitrogen) + Nitrogen = (Nitrogen cation • 2Nitrogen)

By formula: (N2+ • N2) + N2 = (N2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr5.9kJ/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • Oxygen) + Nitrogen = (Oxygen cation • Nitrogen • Oxygen)

By formula: (O2+ • O2) + N2 = (O2+ • N2 • O2)

Quantity Value Units Method Reference Comment
Δr12.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr42.3J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
Δr22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

(CH2N+ • 2Nitrogen) + Nitrogen = (CH2N+ • 3Nitrogen)

By formula: (CH2N+ • 2N2) + N2 = (CH2N+ • 3N2)

Quantity Value Units Method Reference Comment
Δr13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr54.8J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 3Nitrogen) + Nitrogen = (CH2N+ • 4Nitrogen)

By formula: (CH2N+ • 3N2) + N2 = (CH2N+ • 4N2)

Quantity Value Units Method Reference Comment
Δr13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr57.7J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 4Nitrogen) + Nitrogen = (CH2N+ • 5Nitrogen)

By formula: (CH2N+ • 4N2) + N2 = (CH2N+ • 5N2)

Quantity Value Units Method Reference Comment
Δr13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr63.6J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

2,5-Pyrrolidinedione, 1-bromo- + 0.5Hydrazine = Hydrogen bromide + Succinimide + 0.5Nitrogen

By formula: C4H4BrNO2 + 0.5H4N2 = HBr + C4H5NO2 + 0.5N2

Quantity Value Units Method Reference Comment
Δr-260.3 ± 0.46kJ/molCmHoward and Skinner, 1966solid phase; solvent: Aqueous solution; Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -261.7 ± 0.46 kJ/mol; ALS

Oxygen anion + Nitrogen = (Oxygen anion • Nitrogen)

By formula: O2- + N2 = (O2- • N2)

Quantity Value Units Method Reference Comment
Δr25. ± 4.2kJ/molN/APosey and Johnson, 1988gas phase; B
Δr<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2..O2- + O2 -> O4-; B

C12H34P4Ru (solution) + Nitrogen (solution) = C12H32N2P4Ru (solution) + Hydrogen (solution)

By formula: C12H34P4Ru (solution) + N2 (solution) = C12H32N2P4Ru (solution) + H2 (solution)

Quantity Value Units Method Reference Comment
Δr16.3kJ/molPACBelt, Scaiano, et al., 1993solvent: Cyclohexane; The reaction enthalpy relies on 0.85 for the quantum yield of H2 dissociation.; MS

(Hydronium cation • 2Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 2Water)

By formula: (H3O+ • 2N2 • 2H2O) + N2 = (H3O+ • 3N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr38. ± 11.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr119.J/mol*KDTGheno and Fitaire, 1987gas phase; M

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Nitrogen (solution) = C8H5N2O3V (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + N2 (solution) = C8H5N2O3V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Δr27. ± 4.kJ/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.; MS

(Oxygen anion • 2Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 3Nitrogen • Oxygen)

By formula: (O2- • 2N2 • O2) + N2 = (O2- • 3N2 • O2)

Quantity Value Units Method Reference Comment
Δr10.3 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr76.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 3Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 4Nitrogen • Oxygen)

By formula: (O2- • 3N2 • O2) + N2 = (O2- • 4N2 • O2)

Quantity Value Units Method Reference Comment
Δr9.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 4Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 5Nitrogen • Oxygen)

By formula: (O2- • 4N2 • O2) + N2 = (O2- • 5N2 • O2)

Quantity Value Units Method Reference Comment
Δr8.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 5Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 6Nitrogen • Oxygen)

By formula: (O2- • 5N2 • O2) + N2 = (O2- • 6N2 • O2)

Quantity Value Units Method Reference Comment
Δr7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 6Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 7Nitrogen • Oxygen)

By formula: (O2- • 6N2 • O2) + N2 = (O2- • 7N2 • O2)

Quantity Value Units Method Reference Comment
Δr7.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 2Nitrogen • Oxygen)

By formula: (O2- • N2 • O2) + N2 = (O2- • 2N2 • O2)

Quantity Value Units Method Reference Comment
Δr11.7 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, 1988gas phase; M

(Hydronium cation • 2Nitrogen • Water) + Nitrogen = (Hydronium cation • 3Nitrogen • Water)

By formula: (H3O+ • 2N2 • H2O) + N2 = (H3O+ • 3N2 • H2O)

Quantity Value Units Method Reference Comment
Δr33. ± 8.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 2Water)

By formula: (H3O+ • N2 • 2H2O) + N2 = (H3O+ • 2N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr69.5J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 3Water)

By formula: (H3O+ • N2 • 3H2O) + N2 = (H3O+ • 2N2 • 3H2O)

Quantity Value Units Method Reference Comment
Δr18.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr65.7J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Oxygen cation • 10Nitrogen) + Nitrogen = (Oxygen cation • 11Nitrogen)

By formula: (O2+ • 10N2) + N2 = (O2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 10Nitrogen) + Nitrogen = (Nitrogen cation • 11Nitrogen)

By formula: (N2+ • 10N2) + N2 = (N2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Henry's Law data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
0.000601300.XN/A
0.000651300.LN/A

Ion clustering data

Go To: Top, Reaction thermochemistry data, Henry's Law data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Ar+ + Nitrogen = (Ar+ • Nitrogen)

By formula: Ar+ + N2 = (Ar+ • N2)

Quantity Value Units Method Reference Comment
Δr164.kJ/molFAShul, Passarella, et al., 1987gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982; M

Trifluoromethyl cation + Nitrogen = (Trifluoromethyl cation • Nitrogen)

By formula: CF3+ + N2 = (CF3+ • N2)

Quantity Value Units Method Reference Comment
Δr29.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • Nitrogen) + Nitrogen = (Trifluoromethyl cation • 2Nitrogen)

By formula: (CF3+ • N2) + N2 = (CF3+ • 2N2)

Quantity Value Units Method Reference Comment
Δr21.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 2Nitrogen) + Nitrogen = (Trifluoromethyl cation • 3Nitrogen)

By formula: (CF3+ • 2N2) + N2 = (CF3+ • 3N2)

Quantity Value Units Method Reference Comment
Δr8.4kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr54.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 3Nitrogen) + Nitrogen = (Trifluoromethyl cation • 4Nitrogen)

By formula: (CF3+ • 3N2) + N2 = (CF3+ • 4N2)

Quantity Value Units Method Reference Comment
Δr7.5kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr59.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 4Nitrogen) + Nitrogen = (Trifluoromethyl cation • 5Nitrogen)

By formula: (CF3+ • 4N2) + N2 = (CF3+ • 5N2)

Quantity Value Units Method Reference Comment
Δr6.3kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr50.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

CH2N+ + Nitrogen = (CH2N+ • Nitrogen)

By formula: CH2N+ + N2 = (CH2N+ • N2)

Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; M

(CH2N+ • Nitrogen) + Nitrogen = (CH2N+ • 2Nitrogen)

By formula: (CH2N+ • N2) + N2 = (CH2N+ • 2N2)

Quantity Value Units Method Reference Comment
Δr21.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr83.3J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; M

(CH2N+ • 2Nitrogen) + Nitrogen = (CH2N+ • 3Nitrogen)

By formula: (CH2N+ • 2N2) + N2 = (CH2N+ • 3N2)

Quantity Value Units Method Reference Comment
Δr13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr54.8J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 3Nitrogen) + Nitrogen = (CH2N+ • 4Nitrogen)

By formula: (CH2N+ • 3N2) + N2 = (CH2N+ • 4N2)

Quantity Value Units Method Reference Comment
Δr13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr57.7J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 4Nitrogen) + Nitrogen = (CH2N+ • 5Nitrogen)

By formula: (CH2N+ • 4N2) + N2 = (CH2N+ • 5N2)

Quantity Value Units Method Reference Comment
Δr13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr63.6J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

Methyl cation + Nitrogen = (Methyl cation • Nitrogen)

By formula: CH3+ + N2 = (CH3+ • N2)

Quantity Value Units Method Reference Comment
Δr203.kJ/molPDissFoster, Williamson, et al., 1974gas phase; M

CH5+ + Nitrogen = (CH5+ • Nitrogen)

By formula: CH5+ + N2 = (CH5+ • N2)

Quantity Value Units Method Reference Comment
Δr28.kJ/molHPMSSpeller, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KHPMSSpeller, 1983gas phase; M

C2H5+ + Nitrogen = (C2H5+ • Nitrogen)

By formula: C2H5+ + N2 = (C2H5+ • N2)

Quantity Value Units Method Reference Comment
Δr29.kJ/molHPMSSpeller, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KHPMSSpeller, 1983gas phase; M

(C2H5+ • Nitrogen) + Nitrogen = (C2H5+ • 2Nitrogen)

By formula: (C2H5+ • N2) + N2 = (C2H5+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19.kJ/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr45.6J/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M

Calcium ion (1+) + Nitrogen = (Calcium ion (1+) • Nitrogen)

By formula: Ca+ + N2 = (Ca+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FASpears and Fehsenfeld, 1972gas phase; M

Copper ion (1+) + Nitrogen = (Copper ion (1+) • Nitrogen)

By formula: Cu+ + N2 = (Cu+ • N2)

Quantity Value Units Method Reference Comment
Δr26.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
Δr67.J/mol*KHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
Δr5.9kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M

(Copper ion (1+) • Nitrogen) + Nitrogen = (Copper ion (1+) • 2Nitrogen)

By formula: (Cu+ • N2) + N2 = (Cu+ • 2N2)

Quantity Value Units Method Reference Comment
Δr12.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desorption, equilibrium?; M

(Copper ion (1+) • 2Nitrogen) + Nitrogen = (Copper ion (1+) • 3Nitrogen)

By formula: (Cu+ • 2N2) + N2 = (Cu+ • 3N2)

Quantity Value Units Method Reference Comment
Δr10.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desorption; M

Iron ion (1+) + Nitrogen = (Iron ion (1+) • Nitrogen)

By formula: Fe+ + N2 = (Fe+ • N2)

Quantity Value Units Method Reference Comment
Δr54.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • Nitrogen) + Nitrogen = (Iron ion (1+) • 2Nitrogen)

By formula: (Fe+ • N2) + N2 = (Fe+ • 2N2)

Quantity Value Units Method Reference Comment
Δr82.8 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 2Nitrogen) + Nitrogen = (Iron ion (1+) • 3Nitrogen)

By formula: (Fe+ • 2N2) + N2 = (Fe+ • 3N2)

Quantity Value Units Method Reference Comment
Δr45. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 3Nitrogen) + Nitrogen = (Iron ion (1+) • 4Nitrogen)

By formula: (Fe+ • 3N2) + N2 = (Fe+ • 4N2)

Quantity Value Units Method Reference Comment
Δr54.0 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 4Nitrogen) + Nitrogen = (Iron ion (1+) • 5Nitrogen)

By formula: (Fe+ • 4N2) + N2 = (Fe+ • 5N2)

Quantity Value Units Method Reference Comment
Δr61.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

HN2+ + Nitrogen = (HN2+ • Nitrogen)

By formula: HN2+ + N2 = (HN2+ • N2)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Δr60.7kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Δr85.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

(HN2+ • Nitrogen) + Nitrogen = (HN2+ • 2Nitrogen)

By formula: (HN2+ • N2) + N2 = (HN2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr15. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr17.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr75.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 2Nitrogen) + Nitrogen = (HN2+ • 3Nitrogen)

By formula: (HN2+ • 2N2) + N2 = (HN2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr16.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr84.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 3Nitrogen) + Nitrogen = (HN2+ • 4Nitrogen)

By formula: (HN2+ • 3N2) + N2 = (HN2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr15.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 4Nitrogen) + Nitrogen = (HN2+ • 5Nitrogen)

By formula: (HN2+ • 4N2) + N2 = (HN2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr12. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Δr13.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Δr84.J/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.992.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

(HN2+ • 5Nitrogen) + Nitrogen = (HN2+ • 6Nitrogen)

By formula: (HN2+ • 5N2) + N2 = (HN2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 6Nitrogen) + Nitrogen = (HN2+ • 7Nitrogen)

By formula: (HN2+ • 6N2) + N2 = (HN2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 7Nitrogen) + Nitrogen = (HN2+ • 8Nitrogen)

By formula: (HN2+ • 7N2) + N2 = (HN2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 8Nitrogen) + Nitrogen = (HN2+ • 9Nitrogen)

By formula: (HN2+ • 8N2) + N2 = (HN2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 9Nitrogen) + Nitrogen = (HN2+ • 10Nitrogen)

By formula: (HN2+ • 9N2) + N2 = (HN2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 10Nitrogen) + Nitrogen = (HN2+ • 11Nitrogen)

By formula: (HN2+ • 10N2) + N2 = (HN2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr7.20kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

(Hydronium cation • Water) + Nitrogen = (Hydronium cation • Nitrogen • Water)

By formula: (H3O+ • H2O) + N2 = (H3O+ • N2 • H2O)

Quantity Value Units Method Reference Comment
Δr22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr58.2J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Water) + Nitrogen = (Hydronium cation • Nitrogen • 2Water)

By formula: (H3O+ • 2H2O) + N2 = (H3O+ • N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr21.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr59.8J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • Water) + Nitrogen = (Hydronium cation • 2Nitrogen • Water)

By formula: (H3O+ • N2 • H2O) + N2 = (H3O+ • 2N2 • H2O)

Quantity Value Units Method Reference Comment
Δr21.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr54.8J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 2Water)

By formula: (H3O+ • N2 • 2H2O) + N2 = (H3O+ • 2N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr69.5J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 3Water)

By formula: (H3O+ • N2 • 3H2O) + N2 = (H3O+ • 2N2 • 3H2O)

Quantity Value Units Method Reference Comment
Δr18.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr65.7J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Nitrogen • Water) + Nitrogen = (Hydronium cation • 3Nitrogen • Water)

By formula: (H3O+ • 2N2 • H2O) + N2 = (H3O+ • 3N2 • H2O)

Quantity Value Units Method Reference Comment
Δr33. ± 8.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 2Water)

By formula: (H3O+ • 2N2 • 2H2O) + N2 = (H3O+ • 3N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr38. ± 11.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr119.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 3Water)

By formula: (H3O+ • 2N2 • 3H2O) + N2 = (H3O+ • 3N2 • 3H2O)

Quantity Value Units Method Reference Comment
Δr5.0kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr27.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Hydronium cation • 3Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 4Nitrogen • 2Water)

By formula: (H3O+ • 3N2 • 2H2O) + N2 = (H3O+ • 4N2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr10.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr50.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

NH4+ + Nitrogen = (NH4+ • Nitrogen)

By formula: H4N+ + N2 = (H4N+ • N2)

Quantity Value Units Method Reference Comment
Δr50. ± 20.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KDTGheno and Fitaire, 1987gas phase; M

Potassium ion (1+) + Nitrogen = (Potassium ion (1+) • Nitrogen)

By formula: K+ + N2 = (K+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.2310.DTBeyer and Keller, 1971gas phase; low E/N; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) • Nitrogen)

By formula: Li+ + N2 = (Li+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

(Lithium ion (1+) • Nitrogen) + Nitrogen = (Lithium ion (1+) • 2Nitrogen)

By formula: (Li+ • N2) + N2 = (Li+ • 2N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

N+ + Nitrogen = (N+ • Nitrogen)

By formula: N+ + N2 = (N+ • N2)

Quantity Value Units Method Reference Comment
Δr249.kJ/molN/ANational Bureau of Standards, 1968gas phase; from ΔrH(f); M
Δr250.kJ/molEISaporoschenko, 1965gas phase; M
Δr250.kJ/molEIFranklin, Dibeler, et al., 1958gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
361. (+7.5,-0.) CIDHaynes, Freysinger, et al., 1995gas phase; guided ion beam CID; M

Nitric oxide anion + Nitrogen = (Nitric oxide anion • Nitrogen)

By formula: NO- + N2 = (NO- • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr20.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
Δr18.kJ/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Δr22.kJ/molHPMSTurner and Conway, 1976gas phase; M
Δr19.kJ/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr57.7J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
Δr55.6J/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Δr79.1J/mol*KHPMSTurner and Conway, 1976gas phase; M
Δr65.7J/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

(Nitric oxide anion • Nitrogen) + Nitrogen = (Nitric oxide anion • 2Nitrogen)

By formula: (NO- • N2) + N2 = (NO- • 2N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr16.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr52.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion • 2Nitrogen) + Nitrogen = (Nitric oxide anion • 3Nitrogen)

By formula: (NO- • 2N2) + N2 = (NO- • 3N2)

Quantity Value Units Method Reference Comment
Δr16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr70.3J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 3Nitrogen) + Nitrogen = (Nitric oxide anion • 4Nitrogen)

By formula: (NO- • 3N2) + N2 = (NO- • 4N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 4Nitrogen) + Nitrogen = (Nitric oxide anion • 5Nitrogen)

By formula: (NO- • 4N2) + N2 = (NO- • 5N2)

Quantity Value Units Method Reference Comment
Δr13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr89.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 5Nitrogen) + Nitrogen = (Nitric oxide anion • 6Nitrogen)

By formula: (NO- • 5N2) + N2 = (NO- • 6N2)

Quantity Value Units Method Reference Comment
Δr13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 6Nitrogen) + Nitrogen = (Nitric oxide anion • 7Nitrogen)

By formula: (NO- • 6N2) + N2 = (NO- • 7N2)

Quantity Value Units Method Reference Comment
Δr12. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 7Nitrogen) + Nitrogen = (Nitric oxide anion • 8Nitrogen)

By formula: (NO- • 7N2) + N2 = (NO- • 8N2)

Quantity Value Units Method Reference Comment
Δr11. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 8Nitrogen) + Nitrogen = (Nitric oxide anion • 9Nitrogen)

By formula: (NO- • 8N2) + N2 = (NO- • 9N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 9Nitrogen) + Nitrogen = (Nitric oxide anion • 10Nitrogen)

By formula: (NO- • 9N2) + N2 = (NO- • 10N2)

Quantity Value Units Method Reference Comment
Δr7.03kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr79.J/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Nitrogen cation + Nitrogen = (Nitrogen cation • Nitrogen)

By formula: N2+ + N2 = (N2+ • N2)

Quantity Value Units Method Reference Comment
Δr102. to 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr67.8J/mol*KPHPMSTeng and Conway, 1973gas phase; M
Δr81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase; M
Δr46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable; M
Δr-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable; M

(Nitrogen cation • Nitrogen) + Nitrogen = (Nitrogen cation • 2Nitrogen)

By formula: (N2+ • N2) + N2 = (N2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr5.9kJ/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 2Nitrogen) + Nitrogen = (Nitrogen cation • 3Nitrogen)

By formula: (N2+ • 2N2) + N2 = (N2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr66.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 3Nitrogen) + Nitrogen = (Nitrogen cation • 4Nitrogen)

By formula: (N2+ • 3N2) + N2 = (N2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr10.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr69.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 4Nitrogen) + Nitrogen = (Nitrogen cation • 5Nitrogen)

By formula: (N2+ • 4N2) + N2 = (N2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr85.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 5Nitrogen) + Nitrogen = (Nitrogen cation • 6Nitrogen)

By formula: (N2+ • 5N2) + N2 = (N2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 6Nitrogen) + Nitrogen = (Nitrogen cation • 7Nitrogen)

By formula: (N2+ • 6N2) + N2 = (N2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr8.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 7Nitrogen) + Nitrogen = (Nitrogen cation • 8Nitrogen)

By formula: (N2+ • 7N2) + N2 = (N2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr7.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 8Nitrogen) + Nitrogen = (Nitrogen cation • 9Nitrogen)

By formula: (N2+ • 8N2) + N2 = (N2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 9Nitrogen) + Nitrogen = (Nitrogen cation • 10Nitrogen)

By formula: (N2+ • 9N2) + N2 = (N2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr86.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 10Nitrogen) + Nitrogen = (Nitrogen cation • 11Nitrogen)

By formula: (N2+ • 10N2) + N2 = (N2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

N3+ + Nitrogen = (N3+ • Nitrogen)

By formula: N3+ + N2 = (N3+ • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr83.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • Nitrogen) + Nitrogen = (N3+ • 2Nitrogen)

By formula: (N3+ • N2) + N2 = (N3+ • 2N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 2Nitrogen) + Nitrogen = (N3+ • 3Nitrogen)

By formula: (N3+ • 2N2) + N2 = (N3+ • 3N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 3Nitrogen) + Nitrogen = (N3+ • 4Nitrogen)

By formula: (N3+ • 3N2) + N2 = (N3+ • 4N2)

Quantity Value Units Method Reference Comment
Δr15. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 4Nitrogen) + Nitrogen = (N3+ • 5Nitrogen)

By formula: (N3+ • 4N2) + N2 = (N3+ • 5N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 5Nitrogen) + Nitrogen = (N3+ • 6Nitrogen)

By formula: (N3+ • 5N2) + N2 = (N3+ • 6N2)

Quantity Value Units Method Reference Comment
Δr10. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 6Nitrogen) + Nitrogen = (N3+ • 7Nitrogen)

By formula: (N3+ • 6N2) + N2 = (N3+ • 7N2)

Quantity Value Units Method Reference Comment
Δr9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr80.8J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 7Nitrogen) + Nitrogen = (N3+ • 8Nitrogen)

By formula: (N3+ • 7N2) + N2 = (N3+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr69.9J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 8Nitrogen) + Nitrogen = (N3+ • 9Nitrogen)

By formula: (N3+ • 8N2) + N2 = (N3+ • 9N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr68.2J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 9Nitrogen) + Nitrogen = (N3+ • 10Nitrogen)

By formula: (N3+ • 9N2) + N2 = (N3+ • 10N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr69.0J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 10Nitrogen) + Nitrogen = (N3+ • 11Nitrogen)

By formula: (N3+ • 10N2) + N2 = (N3+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr70.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
Δr33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
Δr22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

Nickel ion (1+) + Nitrogen = (Nickel ion (1+) • Nitrogen)

By formula: Ni+ + N2 = (Ni+ • N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
111. (+10.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) • Nitrogen) + Nitrogen = (Nickel ion (1+) • 2Nitrogen)

By formula: (Ni+ • N2) + N2 = (Ni+ • 2N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
111. (+10.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) • 2Nitrogen) + Nitrogen = (Nickel ion (1+) • 3Nitrogen)

By formula: (Ni+ • 2N2) + N2 = (Ni+ • 3N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
56. (+4.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) • 3Nitrogen) + Nitrogen = (Nickel ion (1+) • 4Nitrogen)

By formula: (Ni+ • 3N2) + N2 = (Ni+ • 4N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
42.3 (+9.6,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

Oxygen cation + Nitrogen = (Oxygen cation • Nitrogen)

By formula: O2+ + N2 = (O2+ • N2)

Quantity Value Units Method Reference Comment
Δr21. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr22.kJ/molHPMSSpeller and Fitaire, 1983gas phase; M
Δr24.kJ/molPHPMSJanik and Conway, 1967gas phase; M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr66.1J/mol*KHPMSSpeller and Fitaire, 1983gas phase; M
Δr79.1J/mol*KPHPMSJanik and Conway, 1967gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0296.FAHoward, Bierbaum, et al., 1972gas phase; M

(Oxygen cation • Nitrogen) + Nitrogen = (Oxygen cation • 2Nitrogen)

By formula: (O2+ • N2) + N2 = (O2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr18.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr57.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • 2Nitrogen) + Nitrogen = (Oxygen cation • 3Nitrogen)

By formula: (O2+ • 2N2) + N2 = (O2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr18. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr15.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Δr50.6J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • 3Nitrogen) + Nitrogen = (Oxygen cation • 4Nitrogen)

By formula: (O2+ • 3N2) + N2 = (O2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.204.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation • 4Nitrogen) + Nitrogen = (Oxygen cation • 5Nitrogen)

By formula: (O2+ • 4N2) + N2 = (O2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr67.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.184.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation • 5Nitrogen) + Nitrogen = (Oxygen cation • 6Nitrogen)

By formula: (O2+ • 5N2) + N2 = (O2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr67.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 6Nitrogen) + Nitrogen = (Oxygen cation • 7Nitrogen)

By formula: (O2+ • 6N2) + N2 = (O2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr77.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 7Nitrogen) + Nitrogen = (Oxygen cation • 8Nitrogen)

By formula: (O2+ • 7N2) + N2 = (O2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 8Nitrogen) + Nitrogen = (Oxygen cation • 9Nitrogen)

By formula: (O2+ • 8N2) + N2 = (O2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr7.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 9Nitrogen) + Nitrogen = (Oxygen cation • 10Nitrogen)

By formula: (O2+ • 9N2) + N2 = (O2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7.0 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 10Nitrogen) + Nitrogen = (Oxygen cation • 11Nitrogen)

By formula: (O2+ • 10N2) + N2 = (O2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • Nitrogen • Oxygen) + Nitrogen = (Oxygen cation • 2Nitrogen • Oxygen)

By formula: (O2+ • N2 • O2) + N2 = (O2+ • 2N2 • O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.230.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation • Oxygen) + Nitrogen = (Oxygen cation • Nitrogen • Oxygen)

By formula: (O2+ • O2) + N2 = (O2+ • N2 • O2)

Quantity Value Units Method Reference Comment
Δr12.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr42.3J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

Oxygen anion + Nitrogen = (Oxygen anion • Nitrogen)

By formula: O2- + N2 = (O2- • N2)

Quantity Value Units Method Reference Comment
Δr25. ± 4.2kJ/molN/APosey and Johnson, 1988gas phase; B
Δr<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2..O2- + O2 -> O4-; B

(Oxygen anion • Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 2Nitrogen • Oxygen)

By formula: (O2- • N2 • O2) + N2 = (O2- • 2N2 • O2)

Quantity Value Units Method Reference Comment
Δr11.7 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 2Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 3Nitrogen • Oxygen)

By formula: (O2- • 2N2 • O2) + N2 = (O2- • 3N2 • O2)

Quantity Value Units Method Reference Comment
Δr10.3 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr76.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 3Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 4Nitrogen • Oxygen)

By formula: (O2- • 3N2 • O2) + N2 = (O2- • 4N2 • O2)

Quantity Value Units Method Reference Comment
Δr9.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 4Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 5Nitrogen • Oxygen)

By formula: (O2- • 4N2 • O2) + N2 = (O2- • 5N2 • O2)

Quantity Value Units Method Reference Comment
Δr8.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 5Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 6Nitrogen • Oxygen)

By formula: (O2- • 5N2 • O2) + N2 = (O2- • 6N2 • O2)

Quantity Value Units Method Reference Comment
Δr7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 6Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 7Nitrogen • Oxygen)

By formula: (O2- • 6N2 • O2) + N2 = (O2- • 7N2 • O2)

Quantity Value Units Method Reference Comment
Δr7.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 7Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 8Nitrogen • Oxygen)

By formula: (O2- • 7N2 • O2) + N2 = (O2- • 8N2 • O2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Δr6.40kJ/molPHPMSHiraoka, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, 1988gas phase; M
Δr75.3J/mol*KN/AHiraoka, 1988gas phase; Entropy change calculated or estimated; M

(Oxygen anion • Oxygen) + Nitrogen = (Oxygen anion • Nitrogen • Oxygen)

By formula: (O2- • O2) + N2 = (O2- • N2 • O2)

Quantity Value Units Method Reference Comment
Δr12.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr69.0J/mol*KPHPMSHiraoka, 1988gas phase; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
Δr11.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
Δr10.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
Δr9.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
Δr8.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
Δr8.2 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
Δr7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr73.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
Δr6. ± 2.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr70.7J/mol*KPHPMSHiraoka, 1988gas phase; M

O4- + Nitrogen + Oxygen = N2O4-

By formula: O4- + N2 + O2 = N2O4-

Quantity Value Units Method Reference Comment
Δr12.1 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B
Quantity Value Units Method Reference Comment
Δr-8.8 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

References

Go To: Top, Reaction thermochemistry data, Henry's Law data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., How are Nitrogen Molecules Bound to NO2+ and NO+?, J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880 . [all data]

Gheno and Fitaire, 1987
Gheno, F.; Fitaire, M., Association of N2 with NH4+ and H3O+(H2O)n, n = 1,2,3, J. Chem. Phys., 1987, 87, 2, 953, https://doi.org/10.1063/1.453250 . [all data]

Speller, Fitaire, et al., 1983
Speller, C.V.; Fitaire, M.; Pointu, A.M., Three - Body Association Reactions of NO+ and O2+ with N2, J. Chem. Phys., 1983, 79, 5, 2190, https://doi.org/10.1063/1.446067 . [all data]

Turner and Conway, 1976
Turner, D.L.; Conway, D.C., Stability of the NO+.N2 Ion Cluster, J. Chem. Phys., 1976, 65, 10, 3944, https://doi.org/10.1063/1.432887 . [all data]

Johnsen, Huang, et al., 1975
Johnsen, R.; Huang, C.M.; Biondi, M.A., The Formation and Breakup of NO2+.N2 Clusters in N2 at Low Temperatures, J. Chem. Phys., 1975, 63, 8, 3374, https://doi.org/10.1063/1.431751 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Dunkin, Fehsenfeld, et al., 1971
Dunkin, D.B.; Fehsenfeld, F.C.; Schelmetekopf, A.L.; Ferguson, E.E., Three-Body Association Reactions of NO+ with O2, N2, and CO2, J. Chem. Phys., 1971, 54, 9, 3817, https://doi.org/10.1063/1.1675432 . [all data]

Hiraoka and Nakajima, 1988
Hiraoka, K.; Nakajima, G., A Determination of the Stabilities of N2+(N2)n and O2+(N2)n with n = 1 - 11 from Measurements of the Gas - Phase Ion Equilibria, J. Chem. Phys., 1988, 88, 12, 7709, https://doi.org/10.1063/1.454285 . [all data]

Teng and Conway, 1973
Teng, H.H.; Conway, D.C., Ion - Molecule Equilibria in Mixtures of N2 and Ar, J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338 . [all data]

Payzant and Kebarle, 1970
Payzant, J.D.; Kebarle, P., Clustering Equilibrium N2+ + 2N2 = N4+ + N2 and the Bond Dissociation Energy of N4+, J. Chem. Phys., 1970, 53, 12, 4723, https://doi.org/10.1063/1.1674010 . [all data]

Varney, 1968
Varney, R.N., Equilibrium Constant and Rates for the Reversible Reaction N4+ -> N2+ + N2, Phys. Rev., 1968, 174, 1, 165, https://doi.org/10.1103/PhysRev.174.165 . [all data]

Varney, 1959
Varney, R.N., Molecular Ions, J. Chem. Phys., 1959, 31, 5, 1314, https://doi.org/10.1063/1.1730590 . [all data]

Speller and Fitaire, 1983
Speller, C.V.; Fitaire, M., Proceedings of the 16th International Conference on Phenomena of Ionized Gases, H. Boetticher, H. Wenk and E. Shulz - Gulde, ed(s)., ICPIG, Dusseldorf, 1983, 568. [all data]

Janik and Conway, 1967
Janik, G.S.; Conway, D.C., Bonding in Heteromolecular Ion Clusters. N2O2+, J. Phys. Chem., 1967, 71, 4, 823, https://doi.org/10.1021/j100863a007 . [all data]

Howard, Bierbaum, et al., 1972
Howard, C.J.; Bierbaum, V.M.; Rundle, H.W.; Kaufman, F., Kinetics and Mechanism of Formation of Water Cluster Ions from O2+ and H2O+, J. Chem. Phys., 1972, 57, 8, 3491, https://doi.org/10.1063/1.1678783 . [all data]

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Turner, Simpson, et al., 1983
Turner, J.J.; Simpson, M.B.; Poliakoff, M.; Maier II, W.B., J. Am. Chem. Soc., 1983, 105, 3898. [all data]

National Bureau of Standards, 1968
National Bureau of Standards, US, Technical Note 270 - 3 in The NBS Tables of Chemical Thermodynamic Properties, 1968. [all data]

Saporoschenko, 1965
Saporoschenko, M., Mobility of Mass Analyzed N+, N2+, N3+, and N4+ Ions in Nitrogen Gas, Phys. Rev. A, 1965, 139, 352. [all data]

Franklin, Dibeler, et al., 1958
Franklin, J.L.; Dibeler, V.H.; Reese, R.M.; Krauss, M., Ionization and dissociation of hydrazoic acid and methyl azide by electron impact, J. Am. Chem. Soc., 1958, 80, 298. [all data]

Haynes, Freysinger, et al., 1995
Haynes, C.L.; Freysinger, W.; Armentrout, P.B., Collision-induced dissociation of N3+(X3-) with Ne, Ar, Kr, and Xe, Int. J. Mass Spectrom. Ion Processes, 1995, 149/150, 267. [all data]

El-Shall, Schriver, et al., 1989
El-Shall, M.S.; Schriver, K.E.; Whetten, R.L.; Meot-Ner (Mautner), M., Ion/Molecule Clustering Thermochemistry by Laser Ionization High - Pressure Mass Spectrometry, J. Phys. Chem., 1989, 93, 24, 7969, https://doi.org/10.1021/j100361a002 . [all data]

Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., Laboratory Measurements of Stratospheric Sodium Ion Measurements, Geophys. Res. Lett., 1980, 7, 9, 693, https://doi.org/10.1029/GL007i009p00693 . [all data]

Beyer and Keller, 1971
Beyer, R.A.; Keller, G.E., The Clustering of Atmospheric Gases to Alkali Ions, Trans. Am. Geophys. Union, 1971, 52, 303. [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Gonzalez and Hoff, 1989
Gonzalez, A.A.; Hoff, C.D., Inorg. Chem., 1989, 28, 4295. [all data]

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Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]

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Howard, P.B.; Skinner, H.A., Thermochemistry of some reactions of aqueous hydrazine with halogens, hydrogen halides and N-halogenosuccinimides, J. Chem. Soc. A, 1966, 1536-1540. [all data]

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Posey and Johnson, 1988
Posey, L.A.; Johnson, M.A., Pulsed Photoelectron Spectroscopy of Negative Cluster Ions: Isolation of Three Distinguishable Forms of N2O2-, J. Chem. Phys., 1988, 88, 9, 5385, https://doi.org/10.1063/1.454576 . [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

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Johnson, Popov, et al., 1991
Johnson, F.P.A.; Popov, V.K.; George, M.W.; Bagratashvili, V.N.; Poliakoff, M.; Turner, J.J., Mendeleev Commun., 1991, 145.. [all data]

Shul, Passarella, et al., 1987
Shul, R.J.; Passarella, R.; Upshulte, B.L.; Keesee, R.G.; Castleman, A.W., Thermal Energy Reactions Invoving Ar+ Monomer and Dimer with N2, H2, Xe, and Kr, J. Chem. Phys., 1987, 86, 8, 4446, https://doi.org/10.1063/1.452718 . [all data]

Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T., Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions, J. Chem. Phys., 1982, 77, 4804. [all data]

Hiraoka, Nasu, et al., 1996
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Gas-Phase Stability and Structure of the Cluster Ions CF3+(CO)n, CF3+(N2)n, CF3+((CF4)n, and CF4H+(CF4)n, J. Phys. Chem., 1996, 100, 13, 5245, https://doi.org/10.1021/jp9530010 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Spears and Fehsenfeld, 1972
Spears, K.G.; Fehsenfeld, F.C., Termolecular Association Reactions of Mg, Ca, and Ba Ions, J. Chem. Phys., 1972, 56, 11, 5698, https://doi.org/10.1063/1.1677091 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Gatland, Colonna-Romano, et al., 1975
Gatland, I.R.; Colonna-Romano, L.M.; Keller, G.E., Single and Double Clustering of Nitrogen to Li+, Phys. Rev. A, 1975, 12, 5, 1885, https://doi.org/10.1103/PhysRevA.12.1885 . [all data]

Hiraoka and Yamabe, 1989, 2
Hiraoka, K.; Yamabe, S., Stabilities of the N3+(N2)n Cluster Ions with n = 1 - 11, Chem. Phys. Lett., 1989, 154, 2, 139, https://doi.org/10.1016/S0009-2614(89)87275-6 . [all data]

Khan, Steele, et al., 1995
Khan, F.A.; Steele, D.L.; Armentrout, P.B., Ligand effects in organometallic thermochemistry: The sequential bond energies of Ni(CO)x+ and Ni(N2)x+ (x = 1-4) and Ni(NO)x+ (x = 1-3) [Data derived from reported bond energies taking value of 8.273±0.046 eV for IE[Ni(CO)4]], J. Phys. Chem., 1995, 99, 7819. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Henry's Law data, Ion clustering data, References