Boron hydride oxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-198.32kJ/molReviewChase, 1998Data last reviewed in December, 1975
Quantity Value Units Method Reference Comment
gas,1 bar202.62J/mol*KReviewChase, 1998Data last reviewed in December, 1975

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1200.1200. to 6000.
A 26.2053154.19744
B 40.981285.060506
C -18.72813-1.220665
D 3.1753560.108302
E -0.141106-7.123009
F -208.2712-230.3150
G 222.1206246.8560
H -198.3224-198.3224
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1975 Data last reviewed in December, 1975

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

BO- + Hydrogen cation = Boron hydride oxide

By formula: BO- + H+ = HBO

Quantity Value Units Method Reference Comment
Δr1508. ± 27.kJ/molD-EAWenthold, Kim, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

BO- + Hydrogen cation = Boron hydride oxide

By formula: BO- + H+ = HBO

Quantity Value Units Method Reference Comment
Δr1508. ± 27.kJ/molD-EAWenthold, Kim, et al., 1997gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Wenthold, Kim, et al., 1997
Wenthold, P.G.; Kim, J.B.; Jonas, K.-L.; Lineberger, W.C., An Experimental and Computational Study of the Electron Affinity of Boron Oxide, J. Phys. Chem. A, 1997, 101, 24, 4472, https://doi.org/10.1021/jp970645u . [all data]


Notes

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