Ethylene ion
- Formula: C2H4+
- Molecular weight: 28.0526
- CAS Registry Number: 34470-02-5
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C2H4+ + C2H6 = (C2H4+ • C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.3 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1980 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21. | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1980 | gas phase |
By formula: C2H4+ + C2H4 = (C2H4+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.8 | kcal/mol | PI | Ono, Linn, et al., 1984 | gas phase |
ΔrH° | 18.2 | kcal/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase |
By formula: (C2H4+ • C2H4) + C2H4 = (C2H4+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 | kcal/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: C2H4+ + C2H4 = (C2H4+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.8 | kcal/mol | PI | Ono, Linn, et al., 1984 | gas phase |
ΔrH° | 18.2 | kcal/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase |
By formula: (C2H4+ • C2H4) + C2H4 = (C2H4+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 | kcal/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase |
By formula: C2H4+ + C2H6 = (C2H4+ • C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.3 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1980 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21. | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1980 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Kebarle, 1980
Hiraoka, K.; Kebarle, P.,
Ion Molecule Reactions in Ethane. Thermochemistry and Structures of the Intermediate Complexes: C4H11+ and C4H10+ Formed in the Reactions of C2H5+ and C2H4+ with C2H6,
Can. J. Chem., 1980, 58, 21, 2262, https://doi.org/10.1139/v80-364
. [all data]
Ono, Linn, et al., 1984
Ono, Y.; Linn, S.H.; Tzeng, W.-B.; Ng, C.Y.,
A Study of the Unimolecular Decomposition of the (C2H4)2+ Complex,
J. Chem. Phys., 1984, 80, 4, 1482, https://doi.org/10.1063/1.446897
. [all data]
Ceyer, Tiedemann, et al., 1979
Ceyer, S.T.; Tiedemann, P.W.; Ng, C.Y.; Mahan, B.H.; Lee, Y.T.,
Photoionization of Ethylene Clusters,
J. Chem. Phys., 1979, 70, 5, 2138, https://doi.org/10.1063/1.437758
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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