Ozone anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-61.13 ± 0.25kJ/molR-EANovich, Engelking, et al., 1979 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

O3- + Oxygen = (O3- • Oxygen)

By formula: O3- + O2 = (O3- • O2)

Quantity Value Units Method Reference Comment
Δr8.79 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-15.1 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(O3- • 4Oxygen) + Oxygen = (O3- • 5Oxygen)

By formula: (O3- • 4O2) + O2 = (O3- • 5O2)

Quantity Value Units Method Reference Comment
Δr6.44kJ/molPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr68.6J/mol*KPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
Δr10.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Oxygen) + Oxygen = (O3- • 3Oxygen)

By formula: (O3- • 2O2) + O2 = (O3- • 3O2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr83.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
Δr9.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Oxygen) + Oxygen = (O3- • 4Oxygen)

By formula: (O3- • 3O2) + O2 = (O3- • 4O2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr64.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
Δr8.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
Δr8.2 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
Δr7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr73.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
Δr6. ± 2.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr70.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
Δr11.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • Oxygen) + Oxygen = (O3- • 2Oxygen)

By formula: (O3- • O2) + O2 = (O3- • 2O2)

Quantity Value Units Method Reference Comment
Δr8.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Water) + Water = (O3- • 3Water)

By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- • Water) + Water = (O3- • 2Water)

By formula: (O3- • H2O) + H2O = (O3- • 2H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.296.FAFehsenfeld and Ferguson, 1974gas phase; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(O3- • Water) + Water = (O3- • 2Water)

By formula: (O3- • H2O) + H2O = (O3- • 2H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- • 2Water) + Water = (O3- • 3Water)

By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.296.FAFehsenfeld and Ferguson, 1974gas phase; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
Δr11.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
Δr10.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
Δr9.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
Δr8.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
Δr8.2 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
Δr7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr73.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
Δr6. ± 2.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr70.7J/mol*KPHPMSHiraoka, 1988gas phase; M

O3- + Oxygen = (O3- • Oxygen)

By formula: O3- + O2 = (O3- • O2)

Quantity Value Units Method Reference Comment
Δr8.79 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-15.1 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(O3- • Oxygen) + Oxygen = (O3- • 2Oxygen)

By formula: (O3- • O2) + O2 = (O3- • 2O2)

Quantity Value Units Method Reference Comment
Δr8.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr81.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Oxygen) + Oxygen = (O3- • 3Oxygen)

By formula: (O3- • 2O2) + O2 = (O3- • 3O2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr83.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Oxygen) + Oxygen = (O3- • 4Oxygen)

By formula: (O3- • 3O2) + O2 = (O3- • 4O2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr64.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Oxygen) + Oxygen = (O3- • 5Oxygen)

By formula: (O3- • 4O2) + O2 = (O3- • 5O2)

Quantity Value Units Method Reference Comment
Δr6.44kJ/molPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr68.6J/mol*KPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References