Borane, triethyl-

• Formula: C₆H₁₅B
• Molecular weight: 97.994
• IUPAC Standard InChI: InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3 Copy

  
• IUPAC Standard InChIKey: LALRXNPLTWZJIJ-UHFFFAOYSA-N Copy
• CAS Registry Number: 97-94-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Triethylborane; Triethylboron; (C2H5)3B; Triethylborine; Borethyl
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • IR Spectrum
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Entropy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of fusion

Entropy of fusion

Enthalpy of phase transition

Entropy of phase transition

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Gas Phase Spectrum

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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kostryukov, Samorukov, et al., 1977
Kostryukov, V.N.; Samorukov, O.P.; Samorukova, N.Kh.; Krasavin, A.M.; Petrunin, A.B., Heat capacity of triethylboron at low temperature, Vses. Konf. Kalorim. [Russhir. Tezisy Dokl.] 7th, 1977, 2, 387-390. [all data]

Furukawa, 1955
Furukawa, G.T., Heat capacity, heats of fusion and vaporization, and vapor pressure of triethylborane, (C₂H₅)₃B, NBS Report, 1955, No. 3712, 1-16. [all data]

Kostryukov, Samorukov, et al., 1977, 2
Kostryukov, V.N.; Samorukov, O.P.; Samorukova, N.K.; Krasavin, A.M.; Petrunin, A.B., Heat capacity of triethylboron at low temperature in Vses. Konf. Kalorim. [Rasshir. Tezisy Dokl.], 7th, Vol. 2, 387, 1977. [all data]

Furukawa, 1955, 2
Furukawa, G.T., Heat capacity, heatsof fusion and vaporization, and vapor pressure of triethylborane, (C2H5)3B, Natl. Bur. Stand., 1955. [all data]

House, 1983
House, J.E., Cohesion energies and solubility parameters for triethylboron and diethylzinc, Thermochimica Acta, 1983, 71, 1-2, 215-218, https://doi.org/10.1016/0040-6031(83)80370-0 . [all data]

Stock and Zeidler, 1921
Stock, A.; Zeidler, F., Zur Kenntnis des Bormethyls und Borathyls, Ber. Dtsch. Chem. Ges., 1921, 54, 3, 531-541, https://doi.org/10.1002/cber.19210540321 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  Tboil	Boiling point
  Ttriple	Triple point temperature
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔvapH	Enthalpy of vaporization
  ΔvapS	Entropy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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