Cl3 anion
- Formula: Cl3-
- Molecular weight: 106.360
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -326.5 | kJ/mol | Ther | Nizzi, Pommerening, et al., 1998 | |
| ΔfH°gas | -300.4 | kJ/mol | IMRE | Robbiani and Franklin, 1979 | ΔG≈+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2 |
| ΔfH°gas | -300. ± 21. | kJ/mol | IMRB | Robbiani and Franklin, 1979, 2 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| <4.640 ± 0.010 | LPES | Kaledin, Heaven, et al., 1999 | |
| 5.10 ± 0.20 | NBAE | Bowen, Liesegang, et al., 1983 | |
| >4.30 ± 0.22 | R-A | Robbiani and Franklin, 1979, 2 |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S.,
Gas-phase thermochemistry of polyhalide anions,
J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508
. [all data]
Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L.,
Formation of the trihalide ion Cl3- in the gas phase,
J. Am. Chem. Soc., 1979, 101, 764. [all data]
Robbiani and Franklin, 1979, 2
Robbiani, R.; Franklin, J.L.,
Negative ion-molecule reaction in sulfuryl halides,
J. Am. Chem. Soc., 1979, 101, 3709. [all data]
Kaledin, Heaven, et al., 1999
Kaledin, A.L.; Heaven, M.C.; Morokuma, K.; Neumark, D.M.,
Cl-3(-) electron photodetachment spectrum: measurement and assignment,
Chem. Phys. Lett., 1999, 306, 1-2, 48-52, https://doi.org/10.1016/S0009-2614(99)00419-4
. [all data]
Bowen, Liesegang, et al., 1983
Bowen, K.H.; Liesegang, G.W.; Sanders, R.A.; Herschbach, D.W.,
Electron Attachment to Molecular Clusters by Collisional Charge Transfer,
J. Phys. Chem., 1983, 87, 4, 557-565, https://doi.org/10.1021/j100227a009
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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