Ruthenium, tris(2,4-pentanedionato)-
- Formula: C15H21O6Ru
- Molecular weight: 398.39
- IUPAC Standard InChIKey: RTZYCRSRNSTRGC-LNTINUHCSA-K
- CAS Registry Number: 14284-93-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: tris(pentane-2,4-dionato-O,O')ruthenium; tris(2,4-pentanedionato)ruthenium(III)
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 145.1 ± 2.5 | kJ/mol | ME | Ribeiro da Silva, Giera, et al., 1993 |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
129.1 ± 2.0 | 374. to 434. | ME | Morozova, Zherikova, et al., 2009 | |
148.8 ± 1.7 | 418. | ME | Siddiqi, Siddiqui, et al., 2009 | Based on data from 394. to 441. K. |
128.9 ± 1.9 | 377. to 435. | ME | Igumenov, Semyannikov, et al., 2007 | |
127.0 ± 0.9 | 423. to 493. | N/A | Bykov, Morozova, et al., 1996 | |
139.7 ± 2.5 | 406. | ME | Ribeiro da Silva, Giera, et al., 1993 | Based on data from 398. to 413. K. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro da Silva, Giera, et al., 1993
Ribeiro da Silva, Manuel A.V.; Giera, Edward; Monte, Manuel J.S.,
Vapour pressures and standard molar enthalpy of sublimation of crystalline tris(pentane-2,4-dionato)ruthenium(III),
Journal of Alloys and Compounds, 1993, 197, 1, 105-107, https://doi.org/10.1016/0925-8388(93)90627-Y
. [all data]
Morozova, Zherikova, et al., 2009
Morozova, N.B.; Zherikova, K.V.; Semyannikov, P.P.; Trubin, S.V.; Igumenov, I.K.,
Study of temperature dependencies of saturated vapor pressure of ruthenium(III) beta-diketonate derivatives,
J Therm Anal Calorim, 2009, 98, 2, 395-399, https://doi.org/10.1007/s10973-009-0309-8
. [all data]
Siddiqi, Siddiqui, et al., 2009
Siddiqi, M. Aslam; Siddiqui, Rehan A.; Atakan, Burak,
Thermal Stability, Sublimation Pressures, and Diffusion Coefficients of Anthracene, Pyrene, and Some Metal β-Diketonates,
J. Chem. Eng. Data, 2009, 54, 10, 2795-2802, https://doi.org/10.1021/je9001653
. [all data]
Igumenov, Semyannikov, et al., 2007
Igumenov, Igor K.; Semyannikov, Pyotr P.; Trubin, Sergei V.; Morozova, Natalia B.; Gelfond, Nikolay V.; Mischenko, Alexander V.; Norman, John A.,
Approach to control deposition of ultra thin films from metal organic precursors: Ru deposition,
Surface and Coatings Technology, 2007, 201, 22-23, 9003-9008, https://doi.org/10.1016/j.surfcoat.2007.04.129
. [all data]
Bykov, Morozova, et al., 1996
Bykov, A.F.; Morozova, N.B.; Igumenov, I.K.; Sysoev, S.V.,
Investigation of thermal properties of ruthenium(III) Β-diketonate precursors for preparation of RuO2 films by CVD,
Journal of Thermal Analysis, 1996, 46, 6, 1551-1565, https://doi.org/10.1007/BF01980761
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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