Carbon monoxide

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Carbon monoxide = (Silver ion (1+) • Carbon monoxide)

By formula: Ag+ + CO = (Ag+ • CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.2 (+1.2,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 2Carbon monoxide)

By formula: (Ag+ • CO) + CO = (Ag+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.1 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 3Carbon monoxide)

By formula: (Ag+ • 2CO) + CO = (Ag+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.8,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Silver ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Silver ion (1+) • 4Carbon monoxide)

By formula: (Ag+ • 3CO) + CO = (Ag+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
10.8 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

Ar+ + Carbon monoxide = (Ar+ • Carbon monoxide)

By formula: Ar+ + CO = (Ar+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°18. ± 4.kcal/molPIPECONorwood, Guo, et al., 1989gas phase; Ar+(2P3/2); M

(Ar+ • Carbon monoxide) + Carbon monoxide = (Ar+ • 2Carbon monoxide)

By formula: (Ar+ • CO) + CO = (Ar+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°3.kcal/molPIPECONorwood, Guo, et al., 1989gas phase; approximate value from Ar+(2P3/2) 2CO -> Ar+(2P3/2) + 2CO; M

Trifluoromethyl cation + Carbon monoxide = (Trifluoromethyl cation • Carbon monoxide)

By formula: CF3+ + CO = (CF3+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°16.0kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°30.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation • 2Carbon monoxide)

By formula: (CF3+ • CO) + CO = (CF3+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°6.3kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 2Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation • 3Carbon monoxide)

By formula: (CF3+ • 2CO) + CO = (CF3+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°5.8kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 3Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation • 4Carbon monoxide)

By formula: (CF3+ • 3CO) + CO = (CF3+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°5.4kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 4Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation • 5Carbon monoxide)

By formula: (CF3+ • 4CO) + CO = (CF3+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°3.2kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 5Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation • 6Carbon monoxide)

By formula: (CF3+ • 5CO) + CO = (CF3+ • 6CO)

Quantity Value Units Method Reference Comment
ΔrH°2.9kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 6Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation • 7Carbon monoxide)

By formula: (CF3+ • 6CO) + CO = (CF3+ • 7CO)

Quantity Value Units Method Reference Comment
ΔrH°2.6kcal/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.cal/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(CFeO- • 4294967295Carbon monoxide) + Carbon monoxide = CFeO-

By formula: (CFeO- • 4294967295CO) + CO = CFeO-

Quantity Value Units Method Reference Comment
ΔrH°34.8 ± 3.5kcal/molN/AVillalta and Leopold, 1993gas phase; B
ΔrH°33.7 ± 3.5kcal/molCIDTSunderlin, Wang, et al., 1992gas phase; B

Formyl cation + Carbon monoxide = (Formyl cation • Carbon monoxide)

By formula: CHO+ + CO = (CHO+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°10.8kcal/molPHPMSJennings, Headley, et al., 1982gas phase; M
ΔrH°12.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrH°11.7kcal/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.5cal/mol*KPHPMSJennings, Headley, et al., 1982gas phase; M
ΔrS°24.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrS°20.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

(Formyl cation • Carbon monoxide) + Carbon monoxide = (Formyl cation • 2Carbon monoxide)

By formula: (CHO+ • CO) + CO = (CHO+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°4.9 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°6.6kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°24.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(Formyl cation • 2Carbon monoxide) + Carbon monoxide = (Formyl cation • 3Carbon monoxide)

By formula: (CHO+ • 2CO) + CO = (CHO+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°4.7 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°6.3kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°26.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(Formyl cation • 3Carbon monoxide) + Carbon monoxide = (Formyl cation • 4Carbon monoxide)

By formula: (CHO+ • 3CO) + CO = (CHO+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°4.5 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°6.2kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°29.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(Formyl cation • 4Carbon monoxide) + Carbon monoxide = (Formyl cation • 5Carbon monoxide)

By formula: (CHO+ • 4CO) + CO = (CHO+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°4.2 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°5.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°32.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(Formyl cation • 5Carbon monoxide) + Carbon monoxide = (Formyl cation • 6Carbon monoxide)

By formula: (CHO+ • 5CO) + CO = (CHO+ • 6CO)

Quantity Value Units Method Reference Comment
ΔrH°2.4 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°19.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 6Carbon monoxide) + Carbon monoxide = (Formyl cation • 7Carbon monoxide)

By formula: (CHO+ • 6CO) + CO = (CHO+ • 7CO)

Quantity Value Units Method Reference Comment
ΔrH°2.3 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 7Carbon monoxide) + Carbon monoxide = (Formyl cation • 8Carbon monoxide)

By formula: (CHO+ • 7CO) + CO = (CHO+ • 8CO)

Quantity Value Units Method Reference Comment
ΔrH°2.2 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 8Carbon monoxide) + Carbon monoxide = (Formyl cation • 9Carbon monoxide)

By formula: (CHO+ • 8CO) + CO = (CHO+ • 9CO)

Quantity Value Units Method Reference Comment
ΔrH°2.1 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.6cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 9Carbon monoxide) + Carbon monoxide = (Formyl cation • 10Carbon monoxide)

By formula: (CHO+ • 9CO) + CO = (CHO+ • 10CO)

Quantity Value Units Method Reference Comment
ΔrH°2.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.3cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 10Carbon monoxide) + Carbon monoxide = (Formyl cation • 11Carbon monoxide)

By formula: (CHO+ • 10CO) + CO = (CHO+ • 11CO)

Quantity Value Units Method Reference Comment
ΔrH°2.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 11Carbon monoxide) + Carbon monoxide = (Formyl cation • 12Carbon monoxide)

By formula: (CHO+ • 11CO) + CO = (CHO+ • 12CO)

Quantity Value Units Method Reference Comment
ΔrH°1.9 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 12Carbon monoxide) + Carbon monoxide = (Formyl cation • 13Carbon monoxide)

By formula: (CHO+ • 12CO) + CO = (CHO+ • 13CO)

Quantity Value Units Method Reference Comment
ΔrH°1.8 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 13Carbon monoxide) + Carbon monoxide = (Formyl cation • 14Carbon monoxide)

By formula: (CHO+ • 13CO) + CO = (CHO+ • 14CO)

Quantity Value Units Method Reference Comment
ΔrH°1.8 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(Formyl cation • 14Carbon monoxide) + Carbon monoxide = (Formyl cation • 15Carbon monoxide)

By formula: (CHO+ • 14CO) + CO = (CHO+ • 15CO)

Quantity Value Units Method Reference Comment
ΔrH°1.76kcal/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

(CHO- • 4294967295Carbon monoxide) + Carbon monoxide = CHO-

By formula: (CHO- • 4294967295CO) + CO = CHO-

Quantity Value Units Method Reference Comment
ΔrH°5.42 ± 0.45kcal/molN/AMurray, Miller, et al., 1986gas phase; B

(CNiO- • 4294967295Carbon monoxide) + Carbon monoxide = CNiO-

By formula: (CNiO- • 4294967295CO) + CO = CNiO-

Quantity Value Units Method Reference Comment
ΔrH°33.0 ± 5.8kcal/molN/AStevens, Feigerle, et al., 1982gas phase; B
ΔrH°32.4 ± 5.8kcal/molCIDTSunderlin, Wang, et al., 1992gas phase; Affinity: CO..Ni-; B

CO+ + Carbon monoxide = (CO+ • Carbon monoxide)

By formula: CO+ + CO = (CO+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°16.kcal/molPIPECONorwood, Guo, et al., 1988gas phase; CO+ in state B, ΔrH>; M
ΔrH°22.4kcal/molPILinn, Ono, et al., 1981gas phase; M
ΔrH°28. ± 7.kcal/molEIMunson and Franlin, 1962gas phase; from IP'switching reaction and heats of formation; M
ΔrH°25.4kcal/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; ΔrH>, DG>; M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; ΔrH>, DG>; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.9340.HPMSChong and Franklin, 1971gas phase; equilibrium uncertain; M
11.5695.PHPMSMeot-Ner (Mautner) and Field, 1974gas phase; ΔrH>, DG>; M

(CO+ • Carbon monoxide) + Carbon monoxide = (CO+ • 2Carbon monoxide)

By formula: (CO+ • CO) + CO = (CO+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°12.5kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
ΔrH°3.7kcal/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°35.5cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 2Carbon monoxide) + Carbon monoxide = (CO+ • 3Carbon monoxide)

By formula: (CO+ • 2CO) + CO = (CO+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°7.21kcal/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures; M
Quantity Value Units Method Reference Comment
ΔrS°24.5cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures; M

(CO+ • 3Carbon monoxide) + Carbon monoxide = (CO+ • 4Carbon monoxide)

By formula: (CO+ • 3CO) + CO = (CO+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°4.40kcal/molPHPMSHiraoka and Mori, 1991gas phase; two isomers; M
Quantity Value Units Method Reference Comment
ΔrS°20.5cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers; M

(CO+ • 4Carbon monoxide) + Carbon monoxide = (CO+ • 5Carbon monoxide)

By formula: (CO+ • 4CO) + CO = (CO+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°4.25kcal/molPHPMSHiraoka and Mori, 1991gas phase; two isomers; M
Quantity Value Units Method Reference Comment
ΔrS°24.4cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers; M

(CO+ • 5Carbon monoxide) + Carbon monoxide = (CO+ • 6Carbon monoxide)

By formula: (CO+ • 5CO) + CO = (CO+ • 6CO)

Quantity Value Units Method Reference Comment
ΔrH°2.70kcal/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures; M
Quantity Value Units Method Reference Comment
ΔrS°19.1cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures; M

(CO+ • 6Carbon monoxide) + Carbon monoxide = (CO+ • 7Carbon monoxide)

By formula: (CO+ • 6CO) + CO = (CO+ • 7CO)

Quantity Value Units Method Reference Comment
ΔrH°2.25kcal/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot; M
Quantity Value Units Method Reference Comment
ΔrS°21.1cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot; M

(CO+ • 7Carbon monoxide) + Carbon monoxide = (CO+ • 8Carbon monoxide)

By formula: (CO+ • 7CO) + CO = (CO+ • 8CO)

Quantity Value Units Method Reference Comment
ΔrH°1.58kcal/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot; M
Quantity Value Units Method Reference Comment
ΔrS°12.4cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot; M

(CO+ • 9Carbon monoxide) + Carbon monoxide = (CO+ • 10Carbon monoxide)

By formula: (CO+ • 9CO) + CO = (CO+ • 10CO)

Quantity Value Units Method Reference Comment
ΔrH°1.85kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°19.1cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 11Carbon monoxide) + Carbon monoxide = (CO+ • 12Carbon monoxide)

By formula: (CO+ • 11CO) + CO = (CO+ • 12CO)

Quantity Value Units Method Reference Comment
ΔrH°2.13kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.1cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 12Carbon monoxide) + Carbon monoxide = (CO+ • 13Carbon monoxide)

By formula: (CO+ • 12CO) + CO = (CO+ • 13CO)

Quantity Value Units Method Reference Comment
ΔrH°2.10kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.7cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 13Carbon monoxide) + Carbon monoxide = (CO+ • 14Carbon monoxide)

By formula: (CO+ • 13CO) + CO = (CO+ • 14CO)

Quantity Value Units Method Reference Comment
ΔrH°2.08kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.6cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 14Carbon monoxide) + Carbon monoxide = (CO+ • 15Carbon monoxide)

By formula: (CO+ • 14CO) + CO = (CO+ • 15CO)

Quantity Value Units Method Reference Comment
ΔrH°1.92kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.8cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 15Carbon monoxide) + Carbon monoxide = (CO+ • 16Carbon monoxide)

By formula: (CO+ • 15CO) + CO = (CO+ • 16CO)

Quantity Value Units Method Reference Comment
ΔrH°1.92kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.6cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

(CO+ • 16Carbon monoxide) + Carbon monoxide = (CO+ • 17Carbon monoxide)

By formula: (CO+ • 16CO) + CO = (CO+ • 17CO)

Quantity Value Units Method Reference Comment
ΔrH°1.88kcal/molPHPMSHiraoka and Mori, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.6cal/mol*KPHPMSHiraoka and Mori, 1991gas phase; M

COPt3- + Carbon monoxide = C2O2Pt3-

By formula: COPt3- + CO = C2O2Pt3-

Quantity Value Units Method Reference Comment
ΔrH°53. ± 12.kcal/molN/AGrushow and Ervin, 1997gas phase; B

C2O2Pt3- + Carbon monoxide = C3O3Pt3-

By formula: C2O2Pt3- + CO = C3O3Pt3-

Quantity Value Units Method Reference Comment
ΔrH°52.6 ± 5.3kcal/molN/AGrushow and Ervin, 1997gas phase; B
ΔrH°49.2 ± 3.3kcal/molPDisShi, Spasov, et al., 2001gas phase; B

C3CrO3- + Carbon monoxide = (C3CrO3- • Carbon monoxide)

By formula: C3CrO3- + CO = (C3CrO3- • CO)

Quantity Value Units Method Reference Comment
ΔrH°39.7 ± 3.9kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C3MnO3- + Carbon monoxide = C4MnO4-

By formula: C3MnO3- + CO = C4MnO4-

Quantity Value Units Method Reference Comment
ΔrH°41.1 ± 3.0kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C3O3Pt3- + Carbon monoxide = C4O4Pt3-

By formula: C3O3Pt3- + CO = C4O4Pt3-

Quantity Value Units Method Reference Comment
ΔrH°24.4 ± 3.2kcal/molN/AGrushow and Ervin, 1997gas phase; B

C3O3V- + Carbon monoxide = C4O4V-

By formula: C3O3V- + CO = C4O4V-

Quantity Value Units Method Reference Comment
ΔrH°40.4 ± 5.8kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C4O4Pt3- + Carbon monoxide = C5O5Pt3-

By formula: C4O4Pt3- + CO = C5O5Pt3-

Quantity Value Units Method Reference Comment
ΔrH°26.1 ± 4.4kcal/molN/AGrushow and Ervin, 1997gas phase; B

C4O4V- + Carbon monoxide = C5O5V-

By formula: C4O4V- + CO = C5O5V-

Quantity Value Units Method Reference Comment
ΔrH°31.1 ± 3.0kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C5O5Pt3- + Carbon monoxide = C6O6Pt3-

By formula: C5O5Pt3- + CO = C6O6Pt3-

Quantity Value Units Method Reference Comment
ΔrH°41.5 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B
ΔrH°39.7 ± 3.3kcal/molPDisShi, Spasov, et al., 2001gas phase; B

C5O5V- + Carbon monoxide = C6O6V-

By formula: C5O5V- + CO = C6O6V-

Quantity Value Units Method Reference Comment
ΔrH°30.8 ± 3.5kcal/molCIDTSunderlin, Wang, et al., 1993gas phase; B

C6H5MnO- + Carbon monoxide = C6H5MnO-

By formula: C6H5MnO- + CO = C6H5MnO-

Quantity Value Units Method Reference Comment
ΔrH°5.00 ± 0.50kcal/molN/ASunderlin and Squires, 1999gas phase; B

C6H5MnO- + Carbon monoxide = C7H5MnO2-

By formula: C6H5MnO- + CO = C7H5MnO2-

Quantity Value Units Method Reference Comment
ΔrH°7.80 ± 0.60kcal/molN/ASunderlin and Squires, 1999gas phase; B

C6O6Pt4- + Carbon monoxide = C8O8Pt4-

By formula: C6O6Pt4- + CO = C8O8Pt4-

Quantity Value Units Method Reference Comment
ΔrH°18.4 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

C7H5CrO2- + Carbon monoxide = C8H5CrO3-

By formula: C7H5CrO2- + CO = C8H5CrO3-

Quantity Value Units Method Reference Comment
ΔrH°8.70 ± 0.80kcal/molN/ASunderlin and Squires, 1999gas phase; B

C7H5O2V- + Carbon monoxide = C7H5O2V-

By formula: C7H5O2V- + CO = C7H5O2V-

Quantity Value Units Method Reference Comment
ΔrH°7.90 ± 0.70kcal/molN/ASunderlin and Squires, 1999gas phase; B

C7H5O2V- + Carbon monoxide = C8H5O3V-

By formula: C7H5O2V- + CO = C8H5O3V-

Quantity Value Units Method Reference Comment
ΔrH°7.60 ± 0.60kcal/molN/ASunderlin and Squires, 1999gas phase; B

Cobalt ion (1+) + Carbon monoxide = (Cobalt ion (1+) • Carbon monoxide)

By formula: Co+ + CO = (Co+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°41.6 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°39. ± 3.kcal/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
41.5 (+1.6,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
39.0 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 2Carbon monoxide)

By formula: (Co+ • CO) + CO = (Co+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°36.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
36.4 (+2.1,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
32.9 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 3Carbon monoxide)

By formula: (Co+ • 2CO) + CO = (Co+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°19.6 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
19.6 (+2.8,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 4Carbon monoxide)

By formula: (Co+ • 3CO) + CO = (Co+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°17.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.4,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 5Carbon monoxide)

By formula: (Co+ • 4CO) + CO = (Co+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°17.9 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.2,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

Chromium ion (1+) + Carbon monoxide = (Chromium ion (1+) • Carbon monoxide)

By formula: Cr+ + CO = (Cr+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°21.4 ± 0.9kcal/molCIDTKhan, Clemmer, et al., 1993RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.5 (+1.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • Carbon monoxide) + Carbon monoxide = (Chromium ion (1+) • 2Carbon monoxide)

By formula: (Cr+ • CO) + CO = (Cr+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°22.6 ± 0.7kcal/molCIDTKhan, Clemmer, et al., 1993RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.7 (+0.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Chromium ion (1+) • 3Carbon monoxide)

By formula: (Cr+ • 2CO) + CO = (Cr+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°12.9 ± 1.4kcal/molCIDTKhan, Clemmer, et al., 1993RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
12.9 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Chromium ion (1+) • 4Carbon monoxide)

By formula: (Cr+ • 3CO) + CO = (Cr+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°12.2 ± 1.8kcal/molCIDTKhan, Clemmer, et al., 1993RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
12.2 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Chromium ion (1+) • 5Carbon monoxide)

By formula: (Cr+ • 4CO) + CO = (Cr+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°14.8 ± 0.7kcal/molCIDTKhan, Clemmer, et al., 1993RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
14.8 (+0.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Chromium ion (1+) • 6Carbon monoxide)

By formula: (Cr+ • 5CO) + CO = (Cr+ • 6CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
31.0 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Copper ion (1+) + Carbon monoxide = (Copper ion (1+) • Carbon monoxide)

By formula: Cu+ + CO = (Cu+ • CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
35.5 (+1.6,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Copper ion (1+) • Carbon monoxide) + Carbon monoxide = (Copper ion (1+) • 2Carbon monoxide)

By formula: (Cu+ • CO) + CO = (Cu+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
41.1 (+0.7,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Copper ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Copper ion (1+) • 3Carbon monoxide)

By formula: (Cu+ • 2CO) + CO = (Cu+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
18.0 (+0.9,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

(Copper ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Copper ion (1+) • 4Carbon monoxide)

By formula: (Cu+ • 3CO) + CO = (Cu+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
12.6 (+0.7,-0.) CIDMeyer, Chen, et al., 1995gas phase; guided ion beam CID; M

Iron ion (1+) + Carbon monoxide = (Iron ion (1+) • Carbon monoxide)

By formula: Fe+ + CO = (Fe+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°30.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°32. ± 3.kcal/molMKERCarpenter, van Koppen, et al., 1995gas phase; determined from MKER and theory; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
31.3 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 2Carbon monoxide)

By formula: (Fe+ • CO) + CO = (Fe+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°35.4 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
36.1 (+3.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 3Carbon monoxide)

By formula: (Fe+ • 2CO) + CO = (Fe+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°16.5 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
15.8 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 4Carbon monoxide)

By formula: (Fe+ • 3CO) + CO = (Fe+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°23.4 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
24.6 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Iron ion (1+) • 5Carbon monoxide)

By formula: (Fe+ • 4CO) + CO = (Fe+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°23.2 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.8 (+1.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Carbon monoxide • 2iron) + Carbon monoxide = (Iron ion (1+) • 4Carbon monoxide • 2iron)

By formula: (Fe+ • 3CO • 2Fe) + CO = (Fe+ • 4CO • 2Fe)

Quantity Value Units Method Reference Comment
ΔrH°56.9kcal/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

(Iron ion (1+) • iron) + Carbon monoxide = (Iron ion (1+) • Carbon monoxide • iron)

By formula: (Fe+ • Fe) + CO = (Fe+ • CO • Fe)

Quantity Value Units Method Reference Comment
ΔrH°58.6kcal/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

Potassium ion (1+) + Carbon monoxide = (Potassium ion (1+) • Carbon monoxide)

By formula: K+ + CO = (K+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°4.3 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Kr+ + Carbon monoxide = (Kr+ • Carbon monoxide)

By formula: Kr+ + CO = (Kr+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°24.7 ± 1.8kcal/molSIFTPraxmarer, Jordan, et al., 1993gas phase; switching reaction(Kr+)Kr; Wadt, 1978, Radzig and Smirnov, 1985; M

Lithium ion (1+) + Carbon monoxide = (Lithium ion (1+) • Carbon monoxide)

By formula: Li+ + CO = (Li+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°13.1 ± 2.9kcal/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) • Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) • 2Carbon monoxide)

By formula: (Li+ • CO) + CO = (Li+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°8.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°8.6 ± 1.0kcal/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) • 3Carbon monoxide)

By formula: (Li+ • 2CO) + CO = (Li+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°8.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°8.4 ± 1.0kcal/molCIDTWalter, Sievers, et al., 1998RCD

Magnesium ion (1+) + Carbon monoxide = (Magnesium ion (1+) • Carbon monoxide)

By formula: Mg+ + CO = (Mg+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°9.9 ± 1.4kcal/molCIDTAndersen, Muntean, et al., 2000RCD

(Magnesium ion (1+) • Carbon monoxide) + Carbon monoxide = (Magnesium ion (1+) • 2Carbon monoxide)

By formula: (Mg+ • CO) + CO = (Mg+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°9.2 ± 0.7kcal/molCIDTAndersen, Muntean, et al., 2000RCD

Manganese ion (1+) + Carbon monoxide = (Manganese ion (1+) • Carbon monoxide)

By formula: Mn+ + CO = (Mn+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°7.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; ΔrH>; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
6.0 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) • 2Carbon monoxide)

By formula: (Mn+ • CO) + CO = (Mn+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°25.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; ΔrH<; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
15.1 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) • 3Carbon monoxide)

By formula: (Mn+ • 2CO) + CO = (Mn+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°31. ± 6.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
17.7 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) • 4Carbon monoxide)

By formula: (Mn+ • 3CO) + CO = (Mn+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 3.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
15.5 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) • 5Carbon monoxide)

By formula: (Mn+ • 4CO) + CO = (Mn+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°16. ± 3.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
28.9 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Manganese ion (1+) • 6Carbon monoxide)

By formula: (Mn+ • 5CO) + CO = (Mn+ • 6CO)

Quantity Value Units Method Reference Comment
ΔrH°32. ± 5.kcal/molKERDSDearden, Hayashibara, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
34.0 (+2.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Sodium ion (1+) + Carbon monoxide = (Sodium ion (1+) • Carbon monoxide)

By formula: Na+ + CO = (Na+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°7.6 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°7.6 ± 1.9kcal/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°12.6kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.4cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • Carbon monoxide) + Carbon monoxide = (Sodium ion (1+) • 2Carbon monoxide)

By formula: (Na+ • CO) + CO = (Na+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°5.7 ± 0.7kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°5.7 ± 0.7kcal/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°7.5kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.1cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Nickel ion (1+) + Carbon monoxide = (Nickel ion (1+) • Carbon monoxide)

By formula: Ni+ + CO = (Ni+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°39. ± 3.kcal/molMKERCarpenter, van Koppen, et al., 1995gas phase; determined from MKER and theory; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
41.7 (+2.5,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M
42.5 (+2.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • Carbon monoxide) + Carbon monoxide = (Nickel ion (1+) • 2Carbon monoxide)

By formula: (Ni+ • CO) + CO = (Ni+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
40.1 (+2.5,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion bema CID; M
40.4 (+2.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Nickel ion (1+) • 3Carbon monoxide)

By formula: (Ni+ • 2CO) + CO = (Ni+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.9 (+1.4,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M
22.7 (+1.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Nickel ion (1+) • 4Carbon monoxide)

By formula: (Ni+ • 3CO) + CO = (Ni+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
17.3 (+0.7,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M
17.2 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Oxygen anion + Carbon monoxide = (Oxygen anion • Carbon monoxide)

By formula: O2- + CO = (O2- • CO)

Quantity Value Units Method Reference Comment
ΔrH°<13.60kcal/molIMRBAdams and Bohme, 1970gas phase; CO..O2- + O2 -> O4- + CO. G3MP2B3 calculations indicate a HOF(A-) ca. -38 kcal/mol; B

Platinum ion (1+) + Carbon monoxide = (Platinum ion (1+) • Carbon monoxide)

By formula: Pt+ + CO = (Pt+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°50.7 ± 2.4kcal/molCIDTZhang and Armentrout, 2001RCD

(Platinum ion (1+) • Carbon monoxide) + Carbon monoxide = (Platinum ion (1+) • 2Carbon monoxide)

By formula: (Pt+ • CO) + CO = (Pt+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°46.1 ± 2.4kcal/molCIDTZhang and Armentrout, 2001RCD

(Platinum ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Platinum ion (1+) • 3Carbon monoxide)

By formula: (Pt+ • 2CO) + CO = (Pt+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°23.4 ± 1.2kcal/molCIDTZhang and Armentrout, 2001RCD

(Platinum ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Platinum ion (1+) • 4Carbon monoxide)

By formula: (Pt+ • 3CO) + CO = (Pt+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°12.7 ± 1.2kcal/molCIDTZhang and Armentrout, 2001RCD

Pt3- + Carbon monoxide = COPt3-

By formula: Pt3- + CO = COPt3-

Quantity Value Units Method Reference Comment
ΔrH°53.0 ± 6.9kcal/molN/AGrushow and Ervin, 1997gas phase; B

Pt4- + Carbon monoxide = (Pt4- • Carbon monoxide)

By formula: Pt4- + CO = (Pt4- • CO)

Quantity Value Units Method Reference Comment
ΔrH°60.0 ± 9.2kcal/molN/AGrushow and Ervin, 1997gas phase; B

Pt5- + Carbon monoxide = (Pt5- • Carbon monoxide)

By formula: Pt5- + CO = (Pt5- • CO)

Quantity Value Units Method Reference Comment
ΔrH°57.7 ± 9.2kcal/molN/AGrushow and Ervin, 1997gas phase; B

Titanium ion (1+) + Carbon monoxide = (Titanium ion (1+) • Carbon monoxide)

By formula: Ti+ + CO = (Ti+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°28.2 ± 1.4kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 2Carbon monoxide)

By formula: (Ti+ • CO) + CO = (Ti+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°27.0 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 3Carbon monoxide)

By formula: (Ti+ • 2CO) + CO = (Ti+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°23.9 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 4Carbon monoxide)

By formula: (Ti+ • 3CO) + CO = (Ti+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°20.8 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 5Carbon monoxide)

By formula: (Ti+ • 4CO) + CO = (Ti+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 1.0kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 6Carbon monoxide)

By formula: (Ti+ • 5CO) + CO = (Ti+ • 6CO)

Quantity Value Units Method Reference Comment
ΔrH°17.7 ± 0.7kcal/molCIDTMeyer and Armentrout, 1996RCD

(Titanium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Titanium ion (1+) • 7Carbon monoxide)

By formula: (Ti+ • 6CO) + CO = (Ti+ • 7CO)

Quantity Value Units Method Reference Comment
ΔrH°12.4 ± 1.7kcal/molCIDTMeyer and Armentrout, 1996RCD

Vanadium ion (1+) + Carbon monoxide = (Vanadium ion (1+) • Carbon monoxide)

By formula: V+ + CO = (V+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°28.7 ± 3.3kcal/molCIDArmentrout and Kickel, 1994gas phase; ΔrH(0 K0, guided ion beam CID; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
27.0 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 2Carbon monoxide)

By formula: (V+ • CO) + CO = (V+ • 2CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.7 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
25.3 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 3Carbon monoxide)

By formula: (V+ • 2CO) + CO = (V+ • 3CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.6 (+0.9,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
14.6 (+2.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 4Carbon monoxide)

By formula: (V+ • 3CO) + CO = (V+ • 4CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
20.5 (+2.3,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
22.7 (+3.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 5Carbon monoxide)

By formula: (V+ • 4CO) + CO = (V+ • 5CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.7 (+0.7,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
22.2 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 5Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 6Carbon monoxide)

By formula: (V+ • 5CO) + CO = (V+ • 6CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
23.8 (+1.6,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M
29.6 (+1.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 6Carbon monoxide) + Carbon monoxide = (Vanadium ion (1+) • 7Carbon monoxide)

By formula: (V+ • 6CO) + CO = (V+ • 7CO)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
12.0 (+2.1,-0.) CIDSievers and Armentrout, 1995gas phase; guided ion beam CID; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

Go To: Top, Ion clustering data, References