Stibine, triethyl-
- Formula: C6H15Sb
- Molecular weight: 208.943
- IUPAC Standard InChIKey: KKOFCVMVBJXDFP-UHFFFAOYSA-N
- CAS Registry Number: 617-85-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Triethylantimony; Triethylstibine; (C2H5)3Sb
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 153.9 | K | N/A | Maslova, Novoselova, et al., 1973 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10.9 | kcal/mol | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K.; AC |
ΔvapH° | 10.4 ± 1.0 | kcal/mol | CC-SB | Bamford, Levi, et al., 1946 | MS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
11.4 | 260. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K.; AC |
10.6 | 320. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K.; AC |
9.89 | 360. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K. See also Bamford, Levi, et al., 1946, 2.; AC |
9.15 | 400. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K. See also Bamford, Levi, et al., 1946, 2.; AC |
9.54 ± 0.31 | 306. | N/A | Baev, 2001 | Based on data from 193. to 333. K.; AC |
9.99 | 273. to 393. | BG | Bamford, Levi, et al., 1946, 2 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.259 | 153.9 | Maslova, Novoselova, et al., 1973, 2 | DH |
2.26 | 153.9 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
14.68 | 153.9 | Maslova, Novoselova, et al., 1973, 2 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Maslova, Novoselova, et al., 1973
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B.,
Specific Heat and Phase Changes of Triethylindium, Triethylantimony, and Trimethylgallium,
Tr. Khim. Khim. Tekhnol., 1973, 1973, 51. [all data]
Fulem, Ruzicka, et al., 2006
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Simecek, T.; Hulicius, E.; Pangrác, J.,
Vapour pressure measurement of metal organic precursors used for MOVPE,
The Journal of Chemical Thermodynamics, 2006, 38, 3, 312-322, https://doi.org/10.1016/j.jct.2005.05.018
. [all data]
Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M.,
J. Chem. Soc., 1946, 468.. [all data]
Bamford, Levi, et al., 1946, 2
Bamford, C.H.; Levi, D.L.; Newitt, D.M.,
91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V,
J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468
. [all data]
Baev, 2001
Baev, A.K.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]
Maslova, Novoselova, et al., 1973, 2
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B.,
Specific heat and phase changes of triethylindium, triethyl antimony, and trimethyl gallium,
Trudy. Khim. Khim. Tekhnol., 1973, (2), 51-52. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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