Naphthalene
- Formula: C10H8
- Molecular weight: 128.1705
- IUPAC Standard InChIKey: UFWIBTONFRDIAS-UHFFFAOYSA-N
- CAS Registry Number: 91-20-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Albocarbon; Dezodorator; Moth flakes; Naphthalin; Naphthaline; Naphthene; Tar camphor; White tar; Camphor tar; Moth balls; Naftalen; NCI-C52904; Mighty 150; Mighty RD1; Rcra waste number U165; UN 1334; UN 2304; NSC 37565
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 490. ± 5. | K | AVG | N/A | Average of 10 out of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 353.2 ± 0.7 | K | AVG | N/A | Average of 55 out of 57 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 353.39 ± 0.09 | K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 748. ± 6. | K | AVG | N/A | Average of 13 out of 14 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 41. ± 1. | bar | AVG | N/A | Average of 10 out of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.407 | l/mol | N/A | Tsonopoulos and Ambrose, 1995 | |
Vc | 0.409 | l/mol | N/A | Cheng, 1963 | Uncertainty assigned by TRC = 0.06 l/mol; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 2.46 ± 0.05 | mol/l | N/A | Tsonopoulos and Ambrose, 1995 | |
ρc | 2.497 | mol/l | N/A | Chirico, Knipmeyer, et al., 1993 | Uncertainty assigned by TRC = 0.078 mol/l; TRC |
ρc | 2.450 | mol/l | N/A | Schroeer, 1941 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
ρc | 2.456 | mol/l | N/A | Zhuravlev, 1937 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 54.6 | kJ/mol | CGC | Zhao, Unhannanant, et al., 2008 | AC |
ΔvapH° | 60.3 ± 1.1 | kJ/mol | GC | Haftka, Parsons, et al., 2006 | Based on data from 333. to 403. K.; AC |
ΔvapH° | 53.4 | kJ/mol | CGC | Chickos, Hesse, et al., 1998 | AC |
ΔvapH° | 56.6 | kJ/mol | CGC | Chickos, Hosseini, et al., 1995 | Based on data from 403. to 453. K.; AC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 71. ± 5. | kJ/mol | AVG | N/A | Average of 17 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
70.850 | 323. | N/A | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | DH |
56.1 | 398. | GC | Lei, Chankalal, et al., 2002 | Based on data from 323. to 473. K.; AC |
47.6 ± 1.8 | 491. to 747. | DSC | Boller and Wiedemann, 1998 | AC |
45.4 | 475. | DSC | Back, Grzyll, et al., 1996 | Based on data from 460. to 647. K.; AC |
48.7 ± 0.3 | 400. | EB | Chirico, Knipmeyer, et al., 1993, 2 | AC |
46.4 | 440. | EB | Chirico, Knipmeyer, et al., 1993, 2 | AC |
44.0 | 480. | EB | Chirico, Knipmeyer, et al., 1993, 2 | AC |
41.5 | 520. | EB | Chirico, Knipmeyer, et al., 1993, 2 | AC |
44.4 | 528. | N/A | Lee and Holder, 1993 | Based on data from 513. to 613. K.; AC |
47.9 | 423. | EB | Ambrose, Ewing, et al., 1990 | Based on data from 418. to 613. K.; AC |
50.6 | 367. | A | Stephenson and Malanowski, 1987 | Based on data from 352. to 500. K.; AC |
44.8 | 506. | A | Stephenson and Malanowski, 1987 | Based on data from 491. to 565. K.; AC |
43.2 | 578. | A | Stephenson and Malanowski, 1987 | Based on data from 563. to 663. K.; AC |
43.3 | 676. | A | Stephenson and Malanowski, 1987 | Based on data from 661. to 750. K.; AC |
50.3 ± 0.2 | 370. | N/A | de Kruif, Kuipers, et al., 1981 | Based on data from 353. to 388. K.; AC |
44.7 | 466. | N/A | Wilson, Johnston, et al., 1981 | Based on data from 441. to 727. K.; AC |
50.7 | 369. | N/A | Fowler, Trump, et al., 1968 | Based on data from 354. to 453. K.; AC |
49.0 | 414. | N/A | Camin and Rossini, 1955 | Based on data from 399. to 491. K.; AC |
46.4 | 441. | C | Barrow and McClellan, 1951 | AC |
48.3 | 379. | I | Cramer, 1943 | AC |
47.2 | 423. | I | Mortimer and Murphy, 1923 | Based on data from 373. to 473. K.; AC |
47.7 | 427. | I | NELSON and SENSEMAN, 1922 | Based on data from 360. to 494. K.; AC |
Entropy of vaporization
ΔvapS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
219.3 | 323. | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
353.48 to 452.30 | 4.27117 | 1831.571 | -61.329 | Fowler, Trump, et al., 1968 | Coefficents calculated by NIST from author's data. |
399.47 to 491.79 | 3.97067 | 1606.529 | -85.923 | Camin and Rossini, 1955 |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
72.320 | 298.15 | N/A | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | DH |
72.8 | 327. | GS | Grayson and Fosbraey, 2006 | Based on data from 302. to 352. K.; AC |
64. ± 0.5 | 281. to 290. | LE | McEachern and Sandoval, 2001 | AC |
88.0 ± 2.5 | 267. to 303. | ME | Boller and Wiedemann, 1998 | AC |
71.7 | 333. | GS | Nass, Lenoir, et al., 1995 | Based on data from 313. to 353. K.; AC |
73.7 ± 1.0 | 258. | GS | Wania, Shiu, et al., 1994 | Based on data from 243. to 273. K.; AC |
78. ± 1. | 337. to 352. | GC | Khudyakov, 1988 | AC |
71. ± 4. | 323. | DSC | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | AC |
73.4 | 315. | GS | SATO, INOMATA, et al., 1986 | Based on data from 299. to 331. K.; AC |
72.3 ± 0.8 | 293. to 331. | QR | Glukhova, Arkhangelova, et al., 1985 | AC |
69.9 | 333. to 393. | GS | Matsubara and Kuwamoto, 1985 | AC |
75.8 ± 1.1 | 303. | GS | Sonnefeld, Zoller, et al., 1983 | Based on data from 283. to 323. K.; AC |
72.8 ± 0.3 | 271. to 285. | ME | Colomina, Jimenez, et al., 1982 | AC |
72.5 ± 0.1 | 274. to 353. | DM | de Kruif, Kuipers, et al., 1981 | AC |
72.6 ± 0.6 | 253. to 273. | TE | Kruif, 1980 | AC |
76.0 ± 2.0 | 328. to 398. | DSC | Murray, Cavell, et al., 1980 | AC |
71.3 | 293. | GS | Macknick and Prausnitz, 1979 | Based on data from 280. to 305. K.; AC |
74.8 ± 0.4 | 253. to 273. | TE | De Kruif and Van Ginkel, 1977 | AC |
73.9 ± 0.2 | 253. to 273. | ME | De Kruif and Van Ginkel, 1977 | AC |
72.5 ± 0.3 | 263. to 343. | DM | Ambrose, Lawrenson, et al., 1975 | AC |
67.8 ± 3.5 | 280. | HSA | Chickos, 1975 | AC |
74.4 ± 1.7 | 303. to 329. | TSGC | McEachern, Sandoval, et al., 1975 | AC |
72.7 ± 1.7 | 283. | V | Radchenko and Kitaigorodskii, 1974 | ALS |
72.7 | 283. to 323. | ME | Radchenko, 1971 | AC |
66.53 ± 0.84 | 283. | V | Karyakin, Rabinovich, et al., 1968 | ALS |
72.7 ± 0.3 | 230. to 260. | KG | Miller, 1963 | See also Cox and Pilcher, 1970.; AC |
66.3 ± 2.3 | 354.7 | V | Aihara, 1959 | crystal phase; ALS |
66.3 | 276. to 283. | V | Aihara, 1959, 2 | AC |
69.2 | 268. | N/A | Hoyer and Peperle, 1958 | Based on data from 253. to 283. K.; AC |
65.8 | 293. | Effusion | Sklyarenko, Markin, et al., 1958 | Based on data from 283. to 303. K.; AC |
72.1 | 292. | N/A | Sherwood and Bryant, 1957 | Based on data from 273. to 311. K.; AC |
72.4 | 279. to 294. | N/A | Bradley and Cleasby, 1953 | See also Jones, 1960 and Sears and Hopke, 1954.; AC |
72.383 | 279.7 | V | Bradley and Cleasby, 1953, 2 | ALS |
65.7 | 297. | Effusion | Zibberman-Granovskaya, 1940 | Based on data from 288. to 306. K.; AC |
76.6 | 237. to 276. | N/A | Andrews, 1925 | AC |
82.0 | 293. | ME | Swan and Mack, 1925 | Based on data from 283. to 303. K.; AC |
Entropy of sublimation
ΔsubS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
242.6 | 298.15 | Torres-Gomez, Barreiro-Rodriguez, et al., 1988 | DH |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
18.811 | 353.44 | N/A | Mastrangelo, 1957 | DH |
18.226 | 353.43 | N/A | McCullough, Finke, et al., 1957 | DH |
19.200 | 353.0 | N/A | Spaght, Thomas, et al., 1932 | DH |
19.1 | 353.5 | DSC | Sharma, Gupta, et al., 2008 | AC |
16.44 | 353.8 | DSC | Hafsaoui and Mahmoud, 2007 | AC |
19.55 | 354.7 | DSC | Khimeche and Dahmani, 2006 | AC |
19.55 | 354.7 | DSC | Khimeche and Dahmani, 2006, 2 | AC |
19.0 | 353.4 | AC | Chirico, Knipmeyer, et al., 2002 | Based on data from 5. to 440. K.; AC |
19.1 | 353.4 | N/A | Acree, 1991 | AC |
19.020 | 354.1 | N/A | Syunyaev, Tumanyan, et al., 1984 | Relative error in determination ± 5%.; DH |
19.100 | 353.5 | N/A | Rastogi and Bassi, 1964 | DH |
18.785 | 353. | N/A | Ueberreiter and Orthmann, 1950 | DH |
18.790 | 353.4 | N/A | Eibert, 1944 | DH |
19.040 | 353.4 | N/A | Schmidt, 1941 | DH |
19.000 | 353.1 | N/A | Andrews, Lynn, et al., 1926 | DH |
19.250 | 353. | N/A | David, 1964 | Temperature not measured.; DH |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
51.57 | 353.43 | McCullough, Finke, et al., 1957 | DH |
54.4 | 353.0 | Spaght, Thomas, et al., 1932 | DH |
53.7 | 354.1 | Syunyaev, Tumanyan, et al., 1984 | Relative; DH |
54.0 | 353.5 | Rastogi and Bassi, 1964 | DH |
53.2 | 353. | Ueberreiter and Orthmann, 1950 | DH |
53.2 | 353.4 | Eibert, 1944 | DH |
53.9 | 353.4 | Schmidt, 1941 | DH |
53.8 | 353.1 | Andrews, Lynn, et al., 1926 | DH |
55. | 353. | David, 1964 | Temperature; DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
19.046 | 353.376 | crystaline, I | liquid | Andon and Connett, 1980 | DH |
19.000 | 353.8 | crystaline, I | liquid | Radomska and Radomski, 1980 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
53.90 | 353.376 | crystaline, I | liquid | Andon and Connett, 1980 | DH |
53.70 | 353.8 | crystaline, I | liquid | Radomska and Radomski, 1980 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tsonopoulos and Ambrose, 1995
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The thermodynamic properties to the temperature 700 K of naphthalene and of 2,7-dimethylnaphthalene,
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Schroeer, 1941
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A new method for the measurement of enthalpies of sublimation using differential scanning calorimetry,
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Lei, Ying Duan; Chankalal, Raymond; Chan, Anita; Wania, Frank,
Supercooled Liquid Vapor Pressures of the Polycyclic Aromatic Hydrocarbons,
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DSC enthalpy of vaporization measurements of high temperature two-phase working fluids,
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The thermodynamic properties to the temperature 700 K of naphthalene and of 2,7-dimethylnaphthalene,
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Vapor-liquid equilibria in the systems toluene/naphthalene and cyclohexane/naphthalene,
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The ebulliometric method of vapour-pressure measurement: vapour pressures of benzene, hexafluorobenzene, and naphthalene,
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Torsion-weighing effusion vapour-pressure measurements on organic compounds,
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Ambrose, Lawrenson, et al., 1975
Ambrose, D.; Lawrenson, I.J.; Sprake, C.H.S.,
The vapour pressure of naphthalene,
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Chickos, 1975
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A simple equilibrium method for determining heats of sublimation,
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Notes
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- Symbols used in this document:
Pc Critical pressure Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔsubS Entropy of sublimation ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ΔvapS Entropy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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