Ferric tris(acetylacetonate)

• Formula: C₁₅H₂₁FeO₆
• Molecular weight: 353.169
• IUPAC Standard InChI: InChI=1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; Copy

  
• IUPAC Standard InChIKey: AQBLLJNPHDIAPN-LNTINUHCSA-K Copy
• CAS Registry Number: 14024-18-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Iron, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-; (Acetylacetonato)iron(iii); Iron, tris(2,4-pentanedionato)-; Ferric acetylacetonate; Ferric tris(acetoacetonate); Iron acetylacetonate; Iron triacetylacetonate; Iron tris(acetoacetonate); Iron tris(acetylacetonate); Iron tris(2,4-pentanedionate); Iron(iii) acetylacetonate; Iron(3+) acetylacetonate; Tris(acetylacetonato)iron; Tris(acetylacetone)iron; Tris(2,4-pentanedionato)iron; Iron(III) 2,4-pentanedionate; Ferric(III) acetylacetonate; Ferric triacetylacetonate; Acetope Fe(II); Nacem Iron; NSC 43622; tris(pentane-2,4-dionato)iron(II)
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Enthalpy of fusion

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murray and Hill, 1984
Murray, J.P.; Hill, J.O., DSC determination of the fusion and sublimation enthalpy of tris(2,4-pentanedionato)chromium(III) and iron(III), Thermochim. Acta, 1984, 72, 341. [all data]

Ribeiro da Silva, Monte, et al., 1996
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Huinink, Jan, Vapour pressures and standard molar enthalpies of sublimation of two crystalline iron(III) β-diketonates. The mean molar (Fe-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1996, 28, 4, 413-419, https://doi.org/10.1006/jcht.1996.0041 . [all data]

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S., Sublimation calorimetric studies using a calvet microcalorimeter, Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Hill and Irving, 1968
Hill, J.O.; Irving, R.J., The heat of formation of tris(acetylacetonato)iron(III) and the metal?oxygen bond energy, J. Chem. Soc., A, 1968, 1052, https://doi.org/10.1039/j19680001052 . [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Gerasimova, Gerasimova, et al., 1992
Gerasimova, P.A.; Gerasimova, A.I.; Fedotova, N.E.; Morozova, N.B.; Igumenov, I.K., Thermochemical study of iron(III) tris(β-diketonates), Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1992, 35, 9, 38. [all data]

Maslowska and Baranowski, 1981
Maslowska, J.; Baranowski, J.B., Chemia Analityczna, 1981, 26, 1017. [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 4₆, 314-320, https://doi.org/10.1524/zpch.1970.73.4₆.314 . [all data]

Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August, Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?, Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u . [all data]

Murray and Hill, 1984, 2
Murray, J.P.; Hill, J.O., DSC determination of the fusion and sublimation enthalpy of tris(2,4-pentanedionato)chromium(III) and iron(III), Thermochimica Acta, 1984, 72, 3, 341-347, https://doi.org/10.1016/0040-6031(84)85092-3 . [all data]

Melia and Merrifield, 1970
Melia, T.P.; Merrifield, R., Thermal properties of transition metal compounds, Journal of Inorganic and Nuclear Chemistry, 1970, 32, 8, 2573-2579, https://doi.org/10.1016/0022-1902(70)80304-9 . [all data]

Notes

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• Symbols used in this document:
  

  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

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