Dimethylzinc
- Formula: C2H6Zn
- Molecular weight: 95.45
- IUPAC Standard InChIKey: AXAZMDOAUQTMOW-UHFFFAOYSA-N
- CAS Registry Number: 544-97-8
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 230.13 | K | N/A | Sheiman, Nistratov, et al., 1984 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 30.4 ± 0.2 | kJ/mol | CC-SB | Sokolovskii and Baev, 1984 | Another value for the enthalpy of vaporization has been reported: 29.5 ± 0.4 kJ/mol Long and Cattanach, 1961.; MS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
30.4 ± 0.1 | 273. to 313. | N/A | Baev, 1997 | AC |
29.9 | 283. | BG | Bamford, Levi, et al., 1946 | Based on data from 248. to 318. K.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
6.83 | 230.1 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
5.05 | 210.3 | Domalski and Hearing, 1996 | CAL |
29.68 | 230.1 |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
1.061 | 210.26 | crystaline, II | crystaline, I | Sheiman, Nistratov, et al., 1984, 2 | DH |
6.830 | 230.13 | crystaline, I | liquid | Sheiman, Nistratov, et al., 1984, 2 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
5.05 | 210.26 | crystaline, II | crystaline, I | Sheiman, Nistratov, et al., 1984, 2 | DH |
29.67 | 230.13 | crystaline, I | liquid | Sheiman, Nistratov, et al., 1984, 2 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sheiman, Nistratov, et al., 1984
Sheiman, M.S.; Nistratov, V.P.; Kamelova, G.P.; Rabinovich, I.B.,
Low-temperature heat capacity of organic compounds of aluminum and zinc
in Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, Akad. Nauk SSSS Inst. Khim. Fiz.: Chernogolovka, USSR, Vol. 2 2, 1984. [all data]
Sokolovskii and Baev, 1984
Sokolovskii, A.E.; Baev, A.K.,
Zh. Obshch. Khim., 1984, 54, 103. [all data]
Long and Cattanach, 1961
Long, L.H.; Cattanach, J.,
J. Inorg. Nucl. Chem., 1961, 20, 340. [all data]
Baev, 1997
Baev, A.K.,
Thermodynamic study of structural changes in solutions of dimethyl-zinc with methyl compounds of Group VIB elements,
Zh. Neorg. Khim., 1997, 42, 4, 662. [all data]
Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M.,
91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V,
J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Sheiman, Nistratov, et al., 1984, 2
Sheiman, M.S.; Nistratov, V.P.; Kamelova, G.P.; Rabinovich, I.B.,
Low-temperature heat capacity of organic compounds of aluminum and zinc, Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf.,
10th, 1984, 2, 457-459. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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