Ethane, 1,1,2,2-tetrachloro-1,2-difluoro-

• Formula: C₂Cl₄F₂
• Molecular weight: 203.830
• IUPAC Standard InChI: InChI=1S/C2Cl4F2/c3-1(4,7)2(5,6)8 Copy

  
• IUPAC Standard InChIKey: UGCSPKPEHQEOSR-UHFFFAOYSA-N Copy
• CAS Registry Number: 76-12-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: s-Tetrachlorodifluoroethane; F-112; Freon R 112; Freon 112; Genetron 112; Tetrachloro-1,2-Difluoroethane; Ucon 112; 1,1,2,2-Tetrachloro-1,2-difluoroethane; 1,2-Difluoro-1,1,2,2-tetrachloroethane; CFCl2CFCl2; 1,1,2,2-Tetrachlorodifluoroethane; Difluorotetrachloroethane; 1,2-Difluorotetrachloroethane; Ethane, 1,2-difluoro-1,1,2,2-tetrachloro-; FC 112; Halocarbon 112; Refrigerant 112; sym-Tetrachlorodifluoroethane; Daiflon 112; R 112; Daiflon S2
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Henry's Law data
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Yarrington and Kay, 1957
Yarrington, R.M.; Kay, W.B., The Liquid Specific Heats of Some Fluorocarbon Compounds, J. Phys. Chem., 1957, 61, 1259. [all data]

Miller and Dittman, 1956
Miller, W.T.; Dittman, A.L., The MEchanism of Fluorination I. Fluorine Sensitized Oxidation of Trichlro- and Tetrachloroethylene, J. Am. Chem. Soc., 1956, 78, 2793-7. [all data]

Kishimoto, Suga, et al., 1978
Kishimoto, K.; Suga, H.; Seki, S., Calorimetric study of the glassy state. XIV. calorimetric study on unusual glass transition pehenomena in CFCl2-CFCl2, Bull. Chem. SOc. Jpn., 1978, 51%, 1691-6. [all data]

Kosarukina, Kolesov, et al., 1978
Kosarukina, E.A.; Kolesov, V.P.; Vorob'ev, V.N.; Vogel, L., The heat capacity of 1,1,2,2-tetrachloro-1,2-difluoroethane in the temperature range 12-310 K, Zhur. Fiz. Khim., 1978, 52, 509. [all data]

Varushchenko, Druzhinina, et al., 2007
Varushchenko, R.M.; Druzhinina, A.I.; Kuramshina, G.M.; Dorofeeva, O.V., Thermodynamics of vaporization of some freons and halogenated ethanes and propanes, Fluid Phase Equilibria, 2007, 256, 1-2, 112-122, https://doi.org/10.1016/j.fluid.2007.02.017 . [all data]

Varushchenko and Bulgakova, 1976
Varushchenko, R.M.; Bulgakova, L.L., Tr. Khim. Khim. Tekhnol., 1976, 3, 29. [all data]

Hovorka and Geiger, 1933
Hovorka, Frank; Geiger, Francis E., Thermodynamic Properties of Trifluorotrichloroethane and Difluorotetrachloroethane, J. Am. Chem. Soc., 1933, 55, 12, 4759-4761, https://doi.org/10.1021/ja01339a004 . [all data]

Svoboda, Kubes, et al., 1992
Svoboda, V.; Kubes, V.; Basarova, P., Enthalpies of vaporization and cohesive energies of 1,1,2,2-tetrachloro-1,2-difluoroethane, 1,2-dibromoethane, 1-bromo-2-chloroethane, 1,3-dibromo-propane, and 1,4-dibromo-2,3-dichloro-1,1,2,3,4,4-hexafluorobutane, J. Chem. Thermodyn., 1992, 24, 555-558. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Kishimoto, Suga, et al., 1978, 2
Kishimoto, K.; Suga, H.; Seki, S., Calorimetri study of the glassy state. XIV. Calorimetric study on unusual glass transition phenomena in CFCl₂-CFCl₂, Bull. Chem. Soc. Jpn., 1978, 51, 1691-1696. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Notes

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• Symbols used in this document:
  

  Tboil	Boiling point
  Ttriple	Triple point temperature
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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