sulphur trioxide
- Formula: O3S
- Molecular weight: 80.063
- IUPAC Standard InChIKey: AKEJUJNQAAGONA-UHFFFAOYSA-N
- CAS Registry Number: 7446-11-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Sulfur trioxide
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 290.1 | K | N/A | Kondrat'ev and Strizhov, 1985 | Uncertainty assigned by TRC = 0.1 K; gamma phase; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10.9 ± 0.2 | kcal/mol | N/A | Kondrat'ev and Strizhov, 1985 | Based on data from 290. to 318. K.; AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
11.2 | 290. | Kondrat'ev and Strizhov, 1985 | Based on data from 290. to 318. K.; AC |
7.74 | 368. | Abercromby and Tiley, 1963 | Based on data from 353. to 473. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
333. to 483. | 4.19944 | 892.175 | -103.564 | Abercromby and Tiley, 1963, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
2.23 | 290.2 | AC | Kondrat'ev and Strizhov, 1989 | Based on data from 16. to 332. K.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kondrat'ev and Strizhov, 1985
Kondrat'ev, S.N.; Strizhov, B.V.,
Zh. Fiz. Khim., 1985, 59, 2933. [all data]
Abercromby and Tiley, 1963
Abercromby, D.C.; Tiley, P.F.,
937. The Condensed phases of sulphur trioxide. Part II. Vapour pressure of the liquid at temperatures up to the critical point,
J. Chem. Soc., 1963, 4902, https://doi.org/10.1039/jr9630004902
. [all data]
Abercromby and Tiley, 1963, 2
Abercromby, D.C.; Tiley, P.F.,
The Condensed Phases of Sulphur Trioxide. Part II. Vapour Pressure of the Liquid at Temperatures up to the Critical Point,
J. Chem. Soc., 1963, 4902-4904, https://doi.org/10.1039/jr9630004902
. [all data]
Kondrat'ev and Strizhov, 1989
Kondrat'ev, S.N.; Strizhov, B.V.,
Russ. J. Phys. Chem., 1989, 63, 656. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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