Ethene, chloro-
- Formula: C2H3Cl
- Molecular weight: 62.498
- IUPAC Standard InChIKey: BZHJMEDXRYGGRV-UHFFFAOYSA-N
- CAS Registry Number: 75-01-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethylene, chloro-; Chloroethene; Chloroethylene; Monochloroethylene; Vinyl chloride; Vinyl chloride monomer; Vinyl C monomer; C2H3Cl; Ethylene monochloride; Monochloroethene; Chlorethene; Chlorethylene; Chlorure de vinyle; Cloruro di vinile; Rcra waste number U043; Trovidur; UN 1086; VC; VCM; Vinylchlorid; Vinyle(chlorure de); Winylu chlorek
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 259.45 | K | N/A | Dreisbach and Martin, 1949 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tboil | 259.05 | K | N/A | Stull, 1946 | Uncertainty assigned by TRC = 0.4 K; TRC |
Tboil | 259.3 | K | N/A | Dana, Burdick, et al., 1927 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 94.43 | K | N/A | McDonald, Shrader, et al., 1959 | Uncertainty assigned by TRC = 0.1 K; TRC |
Tfus | 119.36 | K | N/A | Dreisbach, 1955 | Uncertainty assigned by TRC = 0.02 K; TRC |
Tfus | 113.5 | K | N/A | Dana, Burdick, et al., 1927 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 119.31 | K | N/A | Lebedev, Rabinovich, et al., 1967 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 21. ± 1. | kJ/mol | Review | Manion, 2002 | derived from vapor pressure data of Dana, Burdick, et al., 1927 plus a correction for non-ideality; DRB |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
23.3 | 245. | A | Stephenson and Malanowski, 1987 | Based on data from 209. to 260. K. See also McDonald, Shrader, et al., 1959, 2 and Dykyj, 1970.; AC |
22.7 | 265. | N/A | Danov and Golubev, 1967 | Based on data from 243. to 288. K.; AC |
22.9 | 258. | N/A | Haccuria and Mathieu, 1967 | Based on data from 213. to 273. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
165.3 to 259.4 | 3.98598 | 892.757 | -35.051 | McDonald, Shrader, et al., 1959, 2 |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
4.916 | 119.31 | Lebedev, Rabinovich, et al., 1967, 2 | DH |
4.92 | 119.3 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
41.2 | 119.31 | Lebedev, Rabinovich, et al., 1967, 2 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A.,
Physical Data on Some Organic Compounds,
Ind. Eng. Chem., 1949, 41, 2875-8. [all data]
Stull, 1946
Stull, D.R.,
Anal. Chem., 1946, 18, 234. [all data]
Dana, Burdick, et al., 1927
Dana, L.I.; Burdick, J.N.; Jenkins, A.C.,
SOME PHYSICAL PROPERTIES OF VINYL CHLORIDE,
J. Am. Chem. Soc., 1927, 49, 11, 2801, https://doi.org/10.1021/ja01410a021
. [all data]
McDonald, Shrader, et al., 1959
McDonald, R.A.; Shrader, S.A.; Stull, D.R.,
Vapor Pressures and Freezing Points of 30 Organics,
J. Chem. Eng. Data, 1959, 4, 311. [all data]
Dreisbach, 1955
Dreisbach, R.R.,
Physical Properties of Chemical Compounds, Advances in Chemistry Series No. 15, Am. Chem. Soc.: Washington, D. C., 1955. [all data]
Lebedev, Rabinovich, et al., 1967
Lebedev, B.V.; Rabinovich, I.B.; Budarina, V.A.,
Heat Capacity of vinyl chloride, polyvinylchloride and polyvinylidene chloride in the region of 60-300 K,
Polym. Sci. USSR (Engl. Transl.), 1967, 9, 545. [all data]
Manion, 2002
Manion, J.A.,
Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons,
J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
McDonald, Shrader, et al., 1959, 2
McDonald, R.A.; Shrader, S.A.; Stull, D.R.,
Vapor Pressures and Freezing Points of Thirty Pure Organic Compounds.,
J. Chem. Eng. Data, 1959, 4, 4, 311-313, https://doi.org/10.1021/je60004a009
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Danov and Golubev, 1967
Danov, S.M.; Golubev, Y.D.,
Tr. Khim. Khim. Tekhnol, 1967, 52. [all data]
Haccuria and Mathieu, 1967
Haccuria, M.; Mathieu, M.P.,
Ind. Chim. Belg., 1967, 32, 165. [all data]
Lebedev, Rabinovich, et al., 1967, 2
Lebedev, B.V.; Rabinovich, I.B.; Budarina, V.A.,
Heat capacity of vinyl chloride, polyvinylchloride and polyvinylidene chloride in the region of 60-300°K,
Polymer Sci., 1967, USSR 9A, 545-552. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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