1,3-Dioxolan-2-one
- Formula: C3H4O3
- Molecular weight: 88.0621
- IUPAC Standard InChIKey: KMTRUDSVKNLOMY-UHFFFAOYSA-N
- CAS Registry Number: 96-49-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Carbonic acid, cyclic ethylene ester; Cyclic ethylene carbonate; Ethylene carbonate; Ethylene glycol carbonate; Glycol carbonate; 2-Dioxolone; Dioxolone-2; Ethylene glycol, cyclic carbonate; 1,3-Dioxacyclopentan-2-one; Ethylenester kyseliny uhlicite; Texacar EC; NSC 11801
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 310. ± 3. | K | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 309.47 | K | N/A | Marsh, 1987 | Uncertainty assigned by TRC = 0.004 K; recommended as calibration standard; TRC |
Ttriple | 309.49 | K | N/A | Vasil'ev and Korkhov, 1973 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 80. ± 80. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
516.7 | 0.987 | Aldrich Chemical Company Inc., 1990 | BS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
59.6 | 396. | A | Stephenson and Malanowski, 1987 | Based on data from 381. to 437. K.; AC |
60.3 | 383. | EB | Hong, Wakslak, et al., 1982 | Based on data from 368. to 449. K.; AC |
56.3 | 423. | EB | Hong, Wakslak, et al., 1982 | Based on data from 368. to 449. K.; AC |
55.0 | 433. | EB | Hong, Wakslak, et al., 1982 | Based on data from 368. to 433. K.; AC |
56.484 | 423. | V | Peppel, 1958 | ALS |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
68.7 | 285. | A | Stephenson and Malanowski, 1987 | Based on data from 273. to 297. K.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
13.295 | 309.49 | N/A | Vasil'ev and Korkhov, 1974 | DH |
13.295 | 309.49 | N/A | Vasil'ev and Korkhov, 1973 | DH |
13.02 | 311.2 | DSC | Ding, 2004 | AC |
13.3 | 309.5 | N/A | Vasil'ev and Korkhov, 1973 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
42.96 | 309.49 | Vasil'ev and Korkhov, 1974 | DH |
42.96 | 309.49 | Vasil'ev and Korkhov, 1973 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Marsh, 1987
Marsh, K.N.,
Recommended Reference Materials for the Realization of Physicochemical Properties, Blackwell Sci. Pub., Oxford, 1987. [all data]
Vasil'ev and Korkhov, 1973
Vasil'ev, I.A.; Korkhov, A.D.,
The heat capacities and enthalpies of fusion and the thermodynamic properties of solid and liquid ethylene carbonate,
Zhur. Fiz. Khim., 1973, 47, 2710. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Hong, Wakslak, et al., 1982
Hong, C.S.; Wakslak, R.; Finston, H.; Fried, V.,
Some thermodynamic properties of systems containing propylene carbonate and ethylene carbonate,
J. Chem. Eng. Data, 1982, 27, 2, 146-148, https://doi.org/10.1021/je00028a012
. [all data]
Peppel, 1958
Peppel, W.J.,
Preparation and properties of the alkylene carbonates,
Ind. Eng. Chem., 1958, 50, 767-770. [all data]
Vasil'ev and Korkhov, 1974
Vasil'ev, I.A.; Korkhov, A.D.,
Thermodynamic properties of alkylene carbonates at low temperatures, Tr. Khim. Khim. Tekhnol.,
Gor'kii, 1974, 36, 103-105. [all data]
Ding, 2004
Ding, Michael S.,
Liquid-Solid Phase Equilibria and Thermodynamic Modeling for Binary Organic Carbonates,
J. Chem. Eng. Data, 2004, 49, 2, 276-282, https://doi.org/10.1021/je034134e
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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