Dimanganese decacarbonyl

• Formula: C₁₀Mn₂O₁₀
• Molecular weight: 389.9771
• IUPAC Standard InChI: InChI=1S/10CO.2Mn/c10*1-2;; Copy

  
• IUPAC Standard InChIKey: QFEOTYVTTQCYAZ-UHFFFAOYSA-N Copy
• CAS Registry Number: 10170-69-1
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Mn2(CO)10; Manganese carbonyl; Manganese, decacarbonyldi-,; Decacarbonyldimanganese; Manganese carbonyl (Mn2(CO)10); Manganese, decacarbonyldi-, (Mn-Mn)
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Enthalpy of vaporization

Enthalpy of sublimation

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Good, Fairbrother, et al., 1958
Good, W.D.; Fairbrother, D.M.; Waddington, Guy, Manganese Carbonyl: Heat of Formation by Rotating-Bomb Calorimetry, J. Phys. Chem., 1958, 62, 7, 853-856, https://doi.org/10.1021/j150565a021 . [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Behrens, 1976
Behrens, R.G., J. Organometal. Chem., 1976, 121, C63. [all data]

Cotton and Monchamp, 1960
Cotton, F.A.; Monchamp, R.R., J. Chem. Soc., 1960, 533.. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Notes

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• Symbols used in this document:
  

  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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