Ethylene, 1,2-dichloro-, (Z)-
- Formula: C2H2Cl2
- Molecular weight: 96.943
- IUPAC Standard InChIKey: KFUSEUYYWQURPO-UPHRSURJSA-N
- CAS Registry Number: 156-59-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: Ethene, 1,2-dichloro-, (Z)-; (Z)-1,2-Dichloroethylene; cis-Di-1,2-Chloroethylene; cis-Dichloroethylene; cis-1,2-Dichloroethene; cis-1,2-Dichloroethylene; 1,2-cis-Dichloroethylene; (Z)-CHCl=CHCl; (Z)-1,2-Dichloroethene; 1,2-cis-Dichloroethene; Acetylene dichloride, cis-; 1,cis-2-Dichloroethene; Ethylene, 1,2-dichloro-, cis-; Ethene, 1,2-dichloro-, (1Z)-; HCC 1130c; R 1130c
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 333.5 | K | N/A | Weast and Grasselli, 1989 | BS |
Tboil | 333.5 | K | N/A | Amaya, 1961 | Uncertainty assigned by TRC = 0.4 K; TRC |
Tboil | 333.2 | K | N/A | Andrews and Keefer, 1951 | Uncertainty assigned by TRC = 0.6 K; TRC |
Tboil | 333.5 | K | N/A | Maryott, Hobbs, et al., 1941 | Uncertainty assigned by TRC = 0.3 K; TRC |
Tboil | 333.0 | K | N/A | Awbery and Griffiths, 1936 | Uncertainty assigned by TRC = 2. K; estimate based on distillation curve; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 193. | K | N/A | Broers, Ketelaar, et al., 1950 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 31. ± 1. | kJ/mol | Review | Manion, 2002 | adopted Cox and Pilcher, 1970 recommendation plus a correction for non-ideality; DRB |
ΔvapH° | 30.90 | kJ/mol | V | Ketelaar, Van Velden, et al., 1947 | ALS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
31.8 | 288. | N/A | Ketelaar, van Velden, et al., 2010 | Based on data from 273. to 356. K.; AC |
29.3 | 347. | A | Stephenson and Malanowski, 1987 | Based on data from 332. to 495. K.; AC |
31.5 | 288. | A | Stephenson and Malanowski, 1987 | Based on data from 273. to 334. K. See also Dykyj, 1970.; AC |
31.6 | 307. | N/A | Flom, Alpert, et al., 1951 | Based on data from 292. to 335. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
273.91 to 356.78 | 4.0690 | 1163.729 | -47.174 | Ketelaar, van Velden, et al., 1947 | Coefficents calculated by NIST from author's data. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Amaya, 1961
Amaya, K.,
Thermodynamical studies on bionary systems consisting of polar and non-polar liquids. II. the measurement of the heats of mixing for binary systems of polar and non-polar liquids,
Bull. Chem. Soc. Jpn., 1961, 34, 1278. [all data]
Andrews and Keefer, 1951
Andrews, L.J.; Keefer, R.M.,
The Argentation of Organic Iodides,
J. Am. Chem. Soc., 1951, 73, 5733-5736. [all data]
Maryott, Hobbs, et al., 1941
Maryott, A.A.; Hobbs, M.E.; Gross, P.M.,
Bond Moment Additivity and the Electric Moments of Some Halogenated Hydrocarbons,
J. Am. Chem. Soc., 1941, 63, 659. [all data]
Awbery and Griffiths, 1936
Awbery, J.H.; Griffiths, E.,
The Viscosities of Some Liquid Refrigerants,
Proc. Phys. Soc. London, 1936, 48, 372-80. [all data]
Broers, Ketelaar, et al., 1950
Broers, G.H.J.; Ketelaar, J.A.A.; Van Velden, P.F.,
Melting-point Diagram and Hets of Fusion of cis- and trans-1,2-Dichloro-ethene,
Recl. Trav. Chim. Pays-Bas, 1950, 69, 1122. [all data]
Manion, 2002
Manion, J.A.,
Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons,
J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703
. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic, London, 1970, 636. [all data]
Ketelaar, Van Velden, et al., 1947
Ketelaar, J.A.A.; Van Velden, P.F.; Zalm, P.,
Vapour pressures and heats of vaporization of cis- and trans-1,2-dichloroethene,
Rec. Trav. Chim. Pays/Bas, 1947, 66, 27. [all data]
Ketelaar, van Velden, et al., 2010
Ketelaar, J.A.A.; van Velden, P.F.; Zalm, P.,
Vapour pressures and heats of vaporization of cis- and trans-1,2-dichloroethene,
Recl. Trav. Chim. Pays-Bas, 2010, 66, 12, 721-732, https://doi.org/10.1002/recl.19470661202
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Flom, Alpert, et al., 1951
Flom, Donald G.; Alpert, Norman; Elving, Philip J.,
Systems Involving cis-or trans-Dichloroethylene and an Acetal or Ether,
Ind. Eng. Chem., 1951, 43, 5, 1178-1181, https://doi.org/10.1021/ie50497a051
. [all data]
Ketelaar, van Velden, et al., 1947
Ketelaar, J.A.A.; van Velden, P.F.; Zalm, P.,
Vapour Pressures and Heats of Vaporization of cis- and trans-1,2-Dichloroethene,
Recl. Trav. Chim. Pays-Bas, 1947, 66, 12, 721-732, https://doi.org/10.1002/recl.19470661202
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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