Stibine, triphenyl-
- Formula: C18H15Sb
- Molecular weight: 353.072
- IUPAC Standard InChIKey: HVYVMSPIJIWUNA-UHFFFAOYSA-N
- CAS Registry Number: 603-36-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Triphenylantimony; Triphenylstibine; Trifenylstibin; Triphenylstibane
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 328.2 | K | N/A | Forward, Bowden, et al., 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
Tfus | 325.15 | K | N/A | Smith and Andrews, 1931 | Uncertainty assigned by TRC = 1.5 K; with Hg thermometer; TRC |
Tfus | 321.15 | K | N/A | Smith and Andrews, 1931 | Uncertainty assigned by TRC = 1.5 K; with thermocouple; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 106.3 ± 8.4 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Birr, 1960.; AC |
ΔsubH° | 106.3 ± 8.4 | kJ/mol | CC-SB | Skinner H.A., 1964 | Please also see Forward, Bowden, et al., 1949, 2.; MS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
83.3 | 518. | A | Stephenson and Malanowski, 1987 | Based on data from 503. to 553. K. See also Forward, Bowden, et al., 1949, 3.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J.,
Physical Properties of Triphenyl Compounds of Group VB Elements,
J. Chem. Soc., 1949, 1949, 121-6. [all data]
Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H.,
Thermal Energy Studies II. Phenyl Derivatives of Metals,
J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Birr, 1960
Birr, Karl-Heinz,
Bildungsw«65533»rmen von Triphenylphosphin und Triphenylstibin,
Z. Anorg. Allg. Chem., 1960, 306, 1-2, 21-24, https://doi.org/10.1002/zaac.19603060104
. [all data]
Skinner H.A., 1964
Skinner H.A.,
In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]
Forward, Bowden, et al., 1949, 2
Forward, M.V.; Bowden, S.T.; Jones, W.J.,
J. Chem. Soc., 1949, S121.. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Forward, Bowden, et al., 1949, 3
Forward, M.V.; Bowden, S.T.; Jones, W.J.,
S 26. Physical properties of triphenyl compounds of group V B elements,
J. Chem. Soc., 1949, S121, https://doi.org/10.1039/jr949000s121
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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