Heneicosane, 11-decyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus283.2KN/AFoehr and Fenske, 1949Uncertainty assigned by TRC = 2. K; TRC
Tfus282.2KN/ASchiessler, 1947Uncertainty assigned by TRC = 1. K; TRC
Tfus281.850KN/AParks, West, et al., 1946Uncertainty assigned by TRC = 0.4 K; TRC
Tfus281.9KN/AAnonymous, 1944Uncertainty assigned by TRC = 0.5 K; TRC
Tfus282.4KN/ANaylor, 1943Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Ttriple282.34KN/AFischl, Naylor, et al., 1945Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Δvap34.0 ± 0.2kcal/molEParks, West, et al., 1946, 2Heat of vaporization estimated by Cox and Pilcher, 1970; ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
26.51305.A,MGStephenson and Malanowski, 1987Based on data from 298. to 313. K. See also Schiessler and Whitmore, 1955.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
17.019282.34Fischl, Naylor, et al., 1945, 2Stanford data give H = 71044 J/mol; Tm 282.2 K.; DH
17.00282.3Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
60.277282.34Fischl, Naylor, et al., 1945, 2Stanford; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Foehr and Fenske, 1949
Foehr, E.G.; Fenske, M.R., Magneto-optic Rotation of Hydrocarbons, Ind. Eng. Chem., 1949, 41, 1956. [all data]

Schiessler, 1947
Schiessler, R.W., , Am. Pet. Inst. Res. Proj. 42, Twelfth Meeting, 1947. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal Data on Organic Compounds XXIII. Modern Combustion Data for Fourteen Hydrocarbons and Five Polyhydric Alcohols, J. Am. Chem. Soc., 1946, 68, 2524. [all data]

Anonymous, 1944
Anonymous, R., , Sunbury Rep., Anglo-Iranian Oil Co., March 22, 1944. [all data]

Naylor, 1943
Naylor, , Thesis, Stanford Univ., 1943. [all data]

Fischl, Naylor, et al., 1945
Fischl, F.B.; Naylor, B.F.; Ziemer, C.W.; Parks, G.S.; Aston, J.G., The Heat Capacity, Heat of Fusion and Entropy of 11-n-Dodecylheneicosane, J. Am. Chem. Soc., 1945, 67, 2075. [all data]

Parks, West, et al., 1946, 2
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Schiessler and Whitmore, 1955
Schiessler, R.W.; Whitmore, F.C., Properties of High Molecular Weight Hydrocarbons, Ind. Eng. Chem., 1955, 47, 8, 1660-1665, https://doi.org/10.1021/ie50548a054 . [all data]

Fischl, Naylor, et al., 1945, 2
Fischl, F.B.; Naylor, B.G.; Ziemer, C.W.; Parks, G.S.; Aston, J.G., The heat capacity, heat of fusion and entropy of 11-n-decylheneicosane, J. Am. Chem. Soc., 1945, 67, 2075-2079. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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