Sulfur dioxide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus200.75KN/AHoffman and Vanderwerf, 1946Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple197.64KN/AGiauque and Stephenson, 1938Uncertainty assigned by TRC = 0.05 K; Temp. Scale based on T0 = 273.10 K; TRC
Quantity Value Units Method Reference Comment
Ptriple0.0167barN/AGiauque and Stephenson, 1938Uncertainty assigned by TRC = 0.000067 bar; TRC
Quantity Value Units Method Reference Comment
Tc430.34KN/ATravers and Usher, 1906Uncertainty assigned by TRC = 0.4 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
24.9263.N/AGiauque and Stephenson, 1938, 2Based on data from 200. to 263. K.; AC
24.9263.CGiauque and Stephenson, 1938, 2AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
177.7 to 263.3.48586668.225-72.252Stull, 1947Coefficents calculated by NIST from author's data.
263. to 414.94.37798966.575-42.071Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hoffman and Vanderwerf, 1946
Hoffman, K.R.; Vanderwerf, C.A., Addition Compounds of Sulfur Dioxide with Pyridine and the Picolines, J. Am. Chem. Soc., 1946, 68, 997. [all data]

Giauque and Stephenson, 1938
Giauque, W.F.; Stephenson, C.C., Sulfur Dioxide. The Heat Capacity of Solid and Liquid. Vapor Pressure. Heat of Vap. The Entropy Values from Termal and Molecular Data, J. Am. Chem. Soc., 1938, 60, 1389. [all data]

Travers and Usher, 1906
Travers, M.W.; Usher, F.L., The behavior of certain substance at the critical point, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1906, 57, 365-81. [all data]

Giauque and Stephenson, 1938, 2
Giauque, W.F.; Stephenson, C.C., Sulfur Dioxide. The Heat Capacity of Solid and Liquid. Vapor Pressure. Heat of Vaporization. The Entropy Values from Thermal and Molecular Data, J. Am. Chem. Soc., 1938, 60, 6, 1389-1394, https://doi.org/10.1021/ja01273a034 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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