Nitric oxide anion
- Formula: NO-
- Molecular weight: 30.0066
- IUPAC Standard InChIKey: FZRKAZHKEDOPNN-UHFFFAOYSA-N
- CAS Registry Number: 14967-78-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: NO-; Nitrogen oxide, ion
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 71
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Gas phase ion energetics data
Go To: Top, Ion clustering data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
0.040 ± 0.010 | N/A | Velarde, Habteyes, et al., 2007 | |
0.0260 ± 0.0050 | LPES | Travers, Cowles, et al., 1989 | ground state triplet anion |
0.024 ± 0.010 | LPES | Siegel, Celotta, et al., 1972 | |
0.02 ± 0.10 | CIDT | Tiernan and Wu, 1978 | |
0.0250 ± 0.0070 | ETS | Burrow, 1974 | |
0.10 ± 0.10 | ECD | Chen and Wentworth, 1983 | |
0.02 ± 0.10 | Endo | Hughes, Lifschitz, et al., 1973 | |
0.026 ± 0.022 | Kine | Parkes and Sugden, 1972 | |
0.68 ± 0.20 | Endo | Refaey, 1976 | |
>0.10 ± 0.10 | NBIE | Nalley, Compton, et al., 1973 | |
>0.089982 | Endo | Berkowitz, Chupka, et al., 1971 | |
>0.06 ± 0.10 | Endo | Chantry, 1971 | |
>0.65 ± 0.10 | EIAE | Stockdale, Compton, et al., 1969 | From NO2 |
0.85 ± 0.10 | EIAE | Williams and Hamill, 1968 | From EtONO, nBuONO |
0.828255 | SI | Page and Goode, 1969 | The Magnetron method, lacking mass analysis, is not considered reliable. |
0.910647 | SI | Farragher, Page, et al., 1964 | The Magnetron method, lacking mass analysis, is not considered reliable. |
Protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 361.27 ± 0.15 | kcal/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 354.68 ± 0.34 | kcal/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion |
Ion clustering data
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: NO- + Ar = (NO- • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.30 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 1.60 ± 0.30 | kcal/mol | N/A | Bowen and Eaton, 1988 | gas phase; B |
By formula: NO- + CO2 = (NO- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.5 ± 0.3 | kcal/mol | DT | Illies, 1988 | gas phase; ΔrH(0 K)=8.60 kcal/mol; M |
ΔrH° | 7.7 ± 0.4 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
ΔrH° | 13.8 | kcal/mol | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; switching reaction(NO+)NO, ΔrH<; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.0 | cal/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=8.60 kcal/mol; M |
ΔrS° | 13.7 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • CO2) + CO2 = (NO- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.4 ± 0.4 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.1 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 2CO2) + CO2 = (NO- • 3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 ± 0.4 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.8 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 3CO2) + CO2 = (NO- • 4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.7 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.4 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 4CO2) + CO2 = (NO- • 5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.2 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 26.9 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 5CO2) + CO2 = (NO- • 6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.0 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 28. | cal/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: NO- + C2H4O = (NO- • C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.1 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
+ = C2H6NO3-
By formula: NO- + C2H6O2 = C2H6NO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 27.00 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
By formula: NO- + C3H6O = (NO- • C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.0 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C3H6O = (NO- • C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 38.1 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978, ref. to PA(NH3)=208. kcal/mol; M |
By formula: NO- + C3H6O2 = (NO- • C3H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.8 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
+ = C4H4N3O-
By formula: NO- + C4H4N2 = C4H4N3O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16.6 ± 2.3 | kcal/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
By formula: NO- + C4H8O = (NO- • C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.2 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H8O = (NO- • C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.2 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H8O2 = (NO- • C4H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.5 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H10O = (NO- • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.3 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
+ = C5H5N2O-
By formula: NO- + C5H5N = C5H5N2O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.6 ± 2.3 | kcal/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
By formula: NO- + C5H10O = (NO- • C5H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.9 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C5H10O2 = (NO- • C5H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.0 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H5Cl = (NO- • C6H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 38.5 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H5F = (NO- • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37.8 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H5NO2 = (NO- • C6H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.3 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
+ = C6H6NO-
By formula: NO- + C6H6 = C6H6NO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.5 ± 2.3 | kcal/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
By formula: NO- + C6H6 = (NO- • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.1 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H5F3 = (NO- • C7H5F3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35. | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H5N = (NO- • C7H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.1 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H6O = (NO- • C7H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.7 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H8 = (NO- • C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.2 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H14O = (NO- • C7H14O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.6 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C8H10 = (NO- • C8H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.5 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C9H12 = (NO- • C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 45.1 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C9H12 = (NO- • C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 45.1 | kcal/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
+ = C10H8NO-
By formula: NO- + C10H8 = C10H8NO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.5 ± 2.3 | kcal/mol | N/A | Le Barbu, Schiedt, et al., 2002 | gas phase; Affinity is difference in EAs of lesser solvated species; B |
By formula: NO- + H2O = (NO- • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.5 | kcal/mol | PHPMS | French, Hills, et al., 1973 | gas phase; M |
ΔrH° | 16.6 | kcal/mol | PES | Eaton, Arnold, et al., 1990 | gas phase; M |
ΔrH° | 22.7 | kcal/mol | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, about 1600 K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.0 | cal/mol*K | PHPMS | French, Hills, et al., 1973 | gas phase; M |
ΔrS° | 23.9 | cal/mol*K | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, about 1600 K; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
12.7 | 296. | SAMS | Puckett and Teague, 1971 | gas phase; switching reaction(NO+)NO; M |
By formula: (NO- • H2O) + H2O = (NO- • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.70 | kcal/mol | N/A | Eaton, Arnold, et al., 1990 | gas phase; Vertical Detachment Energy: 1.860±0.020 eV; B,M |
ΔrH° | 16.1 | kcal/mol | PHPMS | French, Hills, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25.5 | cal/mol*K | PHPMS | French, Hills, et al., 1973 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
8.4 | 293. | HPMS | McAdams and Bone, 1972 | gas phase; M |
8.5 | 296. | FA | Howard, Rundle, et al., 1971 | gas phase; M |
8.5 | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
By formula: (NO- • 2H2O) + H2O = (NO- • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.8 | kcal/mol | PES | Eaton, Arnold, et al., 1990 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
5.4 | 308. | PHPMS | French, Hills, et al., 1973 | gas phase; M |
5.9 | 293. | HPMS | McAdams and Bone, 1972 | gas phase; M |
6.0 | 296. | FA | Howard, Rundle, et al., 1971 | gas phase; M |
6.0 | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
+ = H2NOS-
By formula: NO- + H2S = H2NOS-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.60 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
+ = H3N2O-
By formula: NO- + H3N = H3N2O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.40 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
By formula: NO- + Kr = (NO- • Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.30 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 2.50 ± 0.40 | kcal/mol | N/A | Bowen and Eaton, 1988 | gas phase; B |
By formula: NO- + NO = (NO- • NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.8 | kcal/mol | PI | Linn, Ono, et al., 1981 | gas phase; M |
ΔrH° | 13.6 | kcal/mol | PI | Ng, Tiedemann, et al., 1977 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
7.0 | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
By formula: (NO- • NO) + NO = (NO- • 2NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.4 | kcal/mol | PI | Linn, Ono, et al., 1981 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
1.9 | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
By formula: (NO- • 2NO) + NO = (NO- • 3NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.7 | kcal/mol | PI | Linn, Ono, et al., 1981 | gas phase; M |
By formula: (NO- • 3NO) + NO = (NO- • 4NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.5 | kcal/mol | PI | Linn, Ono, et al., 1981 | gas phase; M |
By formula: (NO- • 4NO) + NO = (NO- • 5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.3 | kcal/mol | PI | Linn, Ono, et al., 1981 | gas phase; M |
By formula: NO- + N2O = (NO- • N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10. ± 30. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18. | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
ΔrS° | 14.9 | cal/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=7.70 kcal/mol; M |
By formula: (NO- • N2O) + N2O = (NO- • 2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.90 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 4.60 | kcal/mol | N/A | Coe, Snodgrass, et al., 1987 | gas phase; B |
ΔrH° | 5.6 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
ΔrH° | 6. | kcal/mol | PES | Coe, Snodgrass, et al., 1986 | gas phase; D(N2O)2 not accounted for; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.0 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 2N2O) + N2O = (NO- • 3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.20 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 5.1 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23. | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
ΔrS° | 21. | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.2 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 3N2O) + N2O = (NO- • 4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.00 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 4.5 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.2 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 4N2O) + N2O = (NO- • 5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.20 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 4.5 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.5 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 5N2O) + N2O = (NO- • 6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.40 ± 0.20 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B,M,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1.9 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 6N2O) + N2O = (NO- • 7N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.20 ± 0.30 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B,M,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -2.7 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: NO- + N2 = (NO- • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.6 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrH° | 4.7 | kcal/mol | DT | Gheno and Fitaire, 1987 | gas phase; ΔrS+-2.9 cal/mol*K; M |
ΔrH° | 4.4 | kcal/mol | HPMS | Speller, Fitaire, et al., 1983 | gas phase; Entropy change is questionable; M |
ΔrH° | 5.2 | kcal/mol | HPMS | Turner and Conway, 1976 | gas phase; M |
ΔrH° | 4.5 | kcal/mol | DT | Johnsen, Huang, et al., 1975 | gas phase; corrected for ln T by Keesee and Castleman, 1986; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.0 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrS° | 13.8 | cal/mol*K | DT | Gheno and Fitaire, 1987 | gas phase; ΔrS+-2.9 cal/mol*K; M |
ΔrS° | 13.3 | cal/mol*K | HPMS | Speller, Fitaire, et al., 1983 | gas phase; Entropy change is questionable; M |
ΔrS° | 18.9 | cal/mol*K | HPMS | Turner and Conway, 1976 | gas phase; M |
ΔrS° | 15.7 | cal/mol*K | DT | Johnsen, Huang, et al., 1975 | gas phase; corrected for ln T by Keesee and Castleman, 1986; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.5 | 200. | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; M |
By formula: (NO- • N2) + N2 = (NO- • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrH° | 3.9 | kcal/mol | HPMS | Speller and Fitaire, 1983 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrS° | 12.6 | cal/mol*K | HPMS | Speller and Fitaire, 1983 | gas phase; Entropy change is questionable; M |
By formula: (NO- • 2N2) + N2 = (NO- • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.8 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.8 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.9 | 204. | HPMS | Speller, Fitaire, et al., 1983 | gas phase; M |
By formula: (NO- • 3N2) + N2 = (NO- • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.4 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.9 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.4 | 204. | HPMS | Speller, Fitaire, et al., 1983 | gas phase; M |
By formula: (NO- • 4N2) + N2 = (NO- • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.2 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21.3 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 5N2) + N2 = (NO- • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.0 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.9 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 6N2) + N2 = (NO- • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.8 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.8 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 7N2) + N2 = (NO- • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.6 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.3 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 8N2) + N2 = (NO- • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.9 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.5 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 9N2) + N2 = (NO- • 10N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.68 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19. | cal/mol*K | N/A | Hiraoka and Yamabe, 1989 | gas phase; Entropy change calculated or estimated; M |
By formula: NO- + O2S = (NO- • O2S)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
7.8 | 296. | SAMS | Vanderhoff and Heimerl, 1977 | gas phase; switching reaction(NO+)NO; Puckett and Teague, 1971, 2; M |
By formula: NO- + O2 = (NO- • O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.9 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 14.5 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-0.4 | 200. | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; DG>; M |
By formula: (NO- • O2) + O2 = (NO- • 2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.9 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.7 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 2O2) + O2 = (NO- • 3O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.8 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.7 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 3O2) + O2 = (NO- • 4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.4 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.1 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 4O2) + O2 = (NO- • 5O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.4 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.2 | cal/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: NO- + O3 = (NO- • O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.8 | kcal/mol | FA | Fehsenfeld, 1974 | gas phase; switching reaction(NO+)CO2, ΔrH<; M |
By formula: NO- + Xe = (NO- • Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.90 ± 0.90 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 4.10 ± 0.60 | kcal/mol | N/A | Bowen and Eaton, 1988 | gas phase; B |
Constants of diatomic molecules
Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through March, 1977
Symbol | Meaning |
---|---|
State | electronic state and / or symmetry symbol |
Te | minimum electronic energy (cm-1) |
ωe | vibrational constant – first term (cm-1) |
ωexe | vibrational constant – second term (cm-1) |
ωeye | vibrational constant – third term (cm-1) |
Be | rotational constant in equilibrium position (cm-1) |
αe | rotational constant – first term (cm-1) |
γe | rotation-vibration interaction constant (cm-1) |
De | centrifugal distortion constant (cm-1) |
βe | rotational constant – first term, centrifugal force (cm-1) |
re | internuclear distance (Å) |
Trans. | observed transition(s) corresponding to electronic state |
ν00 | position of 0-0 band (units noted in table) |
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Evidence for additional compound states ("resonance" related to the "grandparents" b 3Π, A 1Π, and c 3Π, of NO+) in the 12-18 eV region of the electron transmission Sanche and Schulz, 1971, Schulz, 1973 and electroionization Carbonneau and Marmet, 1974 spectra of NO. | ||||||||||||
The nature of the state (or states) involved in the production of N(2D) + O- by dissociative electron attachmnet (7-12 eV) has been discussed by van Brunt and Kieffer, 1974; see also Thulstrup, Thulstrup, et al., 1974. | ||||||||||||
(3Σ-) | 51700 1 | 2320 | 13 2 | |||||||||
(3Σ+) | 43800 1 | 2380 | 12 2 | |||||||||
(3Π) | 43400 1 | 2370 | 12 2 | |||||||||
(1Σ+) | 40400 1 | 2330 | 8 2 | |||||||||
b 1Σ+ | (9300) 3 | |||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
a 1Δ | 6050 | 1492 3 | (8) | 1.262 3 | ||||||||
X 3Σ- | 0 | 1363 3 | 8 | 1.427 4 | 1.258 4 |
Notes
1 | Symmetries assigned on the basis of theoretical calculations Lefebvre-Brion, 1973. The states consist of two Rydberg electrons temporarily bound to the NO+ X 1Σ+ core. |
2 | Short vibrational progressions of resonances in teh electron transmission current Sanche and Schulz, 1971 predicted widths range from 1 to 25 meV Pearson and Lefebvre-Brion, 1976. |
3 | From the analysis Tronc, Huetz, et al., 1975, Teillet-Billy and Fiquet-Fayard, 1977 of electron scattering data Spence and Schulz, 1971, Schulz, 1973, Burrow, 1974, Zecca, Lazzizzera, et al., 1974. For the ground state Siegel, Celotta, et al., 1972 estimate ωe ~1470 cm-1 Siegel, Celotta, et al., 1972, see 4. |
4 | Franck-Condon factor analysis of the photodetachment spectrum Siegel, Celotta, et al., 1972. The analysis of electron scattering data Teillet-Billy and Fiquet-Fayard, 1977 leads to re = 1.267 Å Teillet-Billy and Fiquet-Fayard, 1977. |
5 | From D00(NO) and the electron affinities of O and NO. |
6 | From the photodetachment spectrum Siegel, Celotta, et al., 1972. Good agreement with McFarland, Dunkin, et al., 1972 and Parkes and Sugden, 1972. |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Fehsenfeld, F.C.,
Clustering of O3 to O2+ and NO+,
J. Chem. Phys., 1974, 61, 4, 1588, https://doi.org/10.1063/1.1682129
. [all data]
Sanche and Schulz, 1971
Sanche, L.; Schulz, G.J.,
Vibrational progressions and Rydberg series of O2 and NO,
Phys. Rev. Lett., 1971, 27, 1333. [all data]
Schulz, 1973
Schulz, G.J.,
Resonances in electron impact on diatomic molecules,
Rev. Mod. Phys., 1973, 45, 423. [all data]
Carbonneau and Marmet, 1974
Carbonneau, R.; Marmet, P.,
The electroionization spectrum of nitric oxide,
Can. J. Phys., 1974, 52, 1885. [all data]
van Brunt and Kieffer, 1974
van Brunt, R.J.; Kieffer, L.J.,
Angular distribution of O- from dissociative electron attachment to NO,
Phys. Rev. A: Gen. Phys., 1974, 10, 1633. [all data]
Thulstrup, Thulstrup, et al., 1974
Thulstrup, P.W.; Thulstrup, E.W.; Andersen, A.; Ohrn, Y.,
Configuration interaction calculations of some observed states of NO-, NO, NO+, and NO2+,
J. Chem. Phys., 1974, 60, 3975. [all data]
Lefebvre-Brion, 1973
Lefebvre-Brion, H.,
Nature of the resonant states of NO-,
Chem. Phys. Lett., 1973, 19, 456. [all data]
Pearson and Lefebvre-Brion, 1976
Pearson, P.K.; Lefebvre-Brion, H.,
Calculations of the widths of some Feshbach resonances in CO- and NO-,
Phys. Rev. A: Gen. Phys., 1976, 13, 2106-2113. [all data]
Tronc, Huetz, et al., 1975
Tronc, M.; Huetz, A.; Landau, M.; Pichou, F.; Reinhardt, J.,
Resonant vibrational excitation of the NO ground state by electron impact in the 0.1-3 eV energy range,
J. Phys. B:, 1975, 8, 1160. [all data]
Teillet-Billy and Fiquet-Fayard, 1977
Teillet-Billy, D.; Fiquet-Fayard, F.,
The NO- 3Σ- and 1Δ resonances: theoretical analysis of electron scattering data,
J. Phys. B:, 1977, 10, 111. [all data]
Spence and Schulz, 1971
Spence, D.; Schulz, G.J.,
Vibrational excitation and compound states in NO,
Phys. Rev. A: Gen. Phys., 1971, 3, 1968. [all data]
Zecca, Lazzizzera, et al., 1974
Zecca, A.; Lazzizzera, I.; Krauss, M.; Kuyatt, C.E.,
Electron scattering from NO and N2O below 10 eV,
J. Chem. Phys., 1974, 61, 4560. [all data]
McFarland, Dunkin, et al., 1972
McFarland, M.; Dunkin, D.B.; Fehsenfeld, F.C.; Schmeltekopf, A.L.; Ferguson, E.E.,
Collisional detachment studies of NO-,
J. Chem. Phys., 1972, 56, 2358. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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