2-Thiatricyclo[3.3.1.1(3,7)]decane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-143.5 ± 1.1kJ/molCcrLacina, Good, et al., 1961ALS
Quantity Value Units Method Reference Comment
Δcsolid-6000.86 ± 0.96kJ/molCcrLacina, Good, et al., 1961ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
213.298.15Lacina, Good, et al., 1961DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus597.KN/AAndrews, Carpenter, et al., 1978Crystal phase 1 phase; Uncertainty assigned by TRC = 3. K; TRC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
8.1597.DSCAndrews, Carpenter, et al., 1978, 2AC

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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 21656

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryApiezon L190.1429.Janku and Popl, 1974N2; Column length: 50. m; Column diameter: 0.2 mm
CapillaryApiezon L200.1439.Janku and Popl, 1974N2; Column length: 50. m; Column diameter: 0.2 mm
CapillaryApiezon L210.1449.Janku and Popl, 1974N2; Column length: 50. m; Column diameter: 0.2 mm

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lacina, Good, et al., 1961
Lacina, J.L.; Good, W.D.; McCullough, J.P., The heats of combustion and formation of thiaadamantane, J. Phys. Chem., 1961, 65, 1026-1027. [all data]

Andrews, Carpenter, et al., 1978
Andrews, J.T.S.; Carpenter, R.E.; Martinko, T.M.; Fort, R.C.; Flood, T.A.; Adlington, M.G., Transition and Fusion Thermodynamics of Heteroadamantanes, Mol. Cryst. Liq. Cryst., 1978, 41, 357-61. [all data]

Andrews, Carpenter, et al., 1978, 2
Andrews, J.T.S.; Carpenter, R.E.; Martinko, T.M.; Fort, R.C.; Flood, T.A.; Adlington, M.G., Transition and Fusion Thermodynamics of Heteroadamantanes, Molecular Crystals and Liquid Crystals, 1978, 41, 10, 257-261, https://doi.org/10.1080/00268947808070312 . [all data]

Janku and Popl, 1974
Janku, J.; Popl, M., The gas chromatographic characterization of 2-thiaadamantane derivatives, J. Chromatogr., 1974, 89, 2, 319-324, https://doi.org/10.1016/S0021-9673(01)99406-3 . [all data]


Notes

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