GA1, 13-O-glucoside, permethylated
- Formula: C31H46O11
- Molecular weight: 594.6903
- IUPAC Standard InChI: InChI=1S/C31H46O11/c1-16-13-29-15-30(16,41-26-23(38-7)22(37-6)21(36-5)17(40-26)14-34-3)11-9-18(29)31-12-10-19(35-4)28(2,27(33)42-31)24(31)20(29)25(32)39-8/h17-24,26H,1,9-15H2,2-8H3/t17-,18-,19+,20-,21-,22+,23-,24-,26+,28-,29+,30+,31-/m0/s1
- IUPAC Standard InChIKey: HYBNOVUMHWAGNC-VWAQXLAKSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Methyl Silicone | 3532. | Schmidt, Schneider, et al., 1988 | 25. m/0.31 mm/0.17 μm, He, 60. C @ 1. min, 25. K/min; Tend: 260. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 3529. | Schneider, Fuchs, et al., 2002 | 15. m/0.25 mm/0.25 μm, He |
| Capillary | DB-5MS | 3530. | Schneider, Fuchs, et al., 2002 | 15. m/0.25 mm/0.25 μm, He |
| Capillary | DB-5MS | 3531. | Schneider, Fuchs, et al., 2002 | 15. m/0.25 mm/0.25 μm, He; Program: 60 0C 91 min) 30 K/min -> 270 0C 30 K/min -> 290 0C (40 min) |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Schmidt, Schneider, et al., 1988
Schmidt, J.; Schneider, G.; Jensen, E.,
Capillary gas chromatography/mass spectrometry of permethylated gibberellin glucosides,
Biomed. Environ. Mass Spectrom., 1988, 17, 1, 7-13, https://doi.org/10.1002/bms.1200170105
. [all data]
Schneider, Fuchs, et al., 2002
Schneider, G.; Fuchs, P.; Schmidt, J.,
Evidence for the direct 2β- and 3β-hydroxylation of [2H2]GA20-13-O-[6'-2H2]glucoside in seedlings of Phaseolus coccineus,
Physiol. Plant., 2002, 116, 2, 144-147, https://doi.org/10.1034/j.1399-3054.2002.1160202.x
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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