Tromethamine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-171.57 ± 0.20kcal/molCcrLaynez, Ringer, et al., 1970ALS
Quantity Value Units Method Reference Comment
Δcsolid-579.93 ± 0.17kcal/molCcbXue, Wu, et al., 1985ALS
Δcsolid-580.37 ± 0.19kcal/molCcrLaynez, Ringer, et al., 1970ALS
Quantity Value Units Method Reference Comment
solid,1 bar41.931cal/mol*KN/AArvidsson and Westrum, 1972DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
40.935298.15Ying and Lin, 1990T = 290 to 450 K.; DH
39.959298.15Arvidsson and Westrum, 1972T = 5 to 300 K.; DH

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin WYANDOTTE CHEMICALS CORP.
Source reference COBLENTZ NO. 5998
Date Not specified, most likely prior to 1970
Name(s) 2-amino-2-(hydroxymethyl)-1,3-propanediol
State SOLID (OIL MULL)
Instrument BAIRD (GRATING)
Instrument parameters NaCl PRISM
Path length CAPILLARY
SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1
Resolution 2
Melting point 171 C

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-1766
NIST MS number 229605

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Parish, 1971
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 19878
Instrument Unicam SP 500

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
OtherMethyl Silicone1645.Ardrey and Moffat, 1981Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Laynez, Ringer, et al., 1970
Laynez, J.; Ringer, B.; Sunner, S., On the accuracy of rotating-bomb combustion calorimetry for organic chlorine and bromine compounds, J. Chem. Thermodyn., 1970, 2, 603-610. [all data]

Xue, Wu, et al., 1985
Xue, R.; Wu, D.; Qu, S., Studies on thermochemistry of porphyrins. I. A precision combustion calorimetric apparatus and calibration, Wuli Huaxue Xuebao, 1985, 1, 76-81. [all data]

Arvidsson and Westrum, 1972
Arvidsson, K.; Westrum, E.F., Jr., Tris(hydroxymethane.yl)aminomethane. Heat capacities and thermodynamic properties from 5 to 350K, J. Chem. Thermodynam., 1972, 4, 449-453. [all data]

Ying and Lin, 1990
Ying, Z.Z.; Lin, Y.M., Heat capacity and phase transitions of 2-amino-2-hydroxymethylpropan-1,3-diol from 290 to 455 K, J. Chem. Thermodynam., 1990, 22, 617-622. [all data]

Parish, 1971
Parish, C., UV atlas of organic compounds, 1971, 5, K2/4. [all data]

Ardrey and Moffat, 1981
Ardrey, R.E.; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Chromatogr., 1981, 220, 3, 195-252, https://doi.org/10.1016/S0021-9673(00)81925-1 . [all data]


Notes

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