Nitric oxide anion
- Formula: NO-
- Molecular weight: 30.0066
- IUPAC Standard InChI: InChI=1S/NO/c1-2/q-1
- IUPAC Standard InChIKey: FZRKAZHKEDOPNN-UHFFFAOYSA-N
- CAS Registry Number: 14967-78-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: NO-; Nitrogen oxide, ion
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- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 71
- Gas phase ion energetics data
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Constants of diatomic molecules
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through March, 1977
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Evidence for additional compound states ("resonance" related to the "grandparents" b 3Π, A 1Π, and c 3Π, of NO+) in the 12-18 eV region of the electron transmission Sanche and Schulz, 1971, Schulz, 1973 and electroionization Carbonneau and Marmet, 1974 spectra of NO. | ||||||||||||
| The nature of the state (or states) involved in the production of N(2D) + O- by dissociative electron attachmnet (7-12 eV) has been discussed by van Brunt and Kieffer, 1974; see also Thulstrup, Thulstrup, et al., 1974. | ||||||||||||
| (3Σ-) | 51700 1 | 2320 | 13 2 | |||||||||
| (3Σ+) | 43800 1 | 2380 | 12 2 | |||||||||
| (3Π) | 43400 1 | 2370 | 12 2 | |||||||||
| (1Σ+) | 40400 1 | 2330 | 8 2 | |||||||||
| b 1Σ+ | (9300) 3 | |||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| a 1Δ | 6050 | 1492 3 | (8) | 1.262 3 | ||||||||
| X 3Σ- | 0 | 1363 3 | 8 | 1.427 4 | 1.258 4 | |||||||
Notes
| 1 | Symmetries assigned on the basis of theoretical calculations Lefebvre-Brion, 1973. The states consist of two Rydberg electrons temporarily bound to the NO+ X 1Σ+ core. |
| 2 | Short vibrational progressions of resonances in teh electron transmission current Sanche and Schulz, 1971 predicted widths range from 1 to 25 meV Pearson and Lefebvre-Brion, 1976. |
| 3 | From the analysis Tronc, Huetz, et al., 1975, Teillet-Billy and Fiquet-Fayard, 1977 of electron scattering data Spence and Schulz, 1971, Schulz, 1973, Burrow, 1974, Zecca, Lazzizzera, et al., 1974. For the ground state Siegel, Celotta, et al., 1972 estimate ωe ~1470 cm-1 Siegel, Celotta, et al., 1972, see 4. |
| 4 | Franck-Condon factor analysis of the photodetachment spectrum Siegel, Celotta, et al., 1972. The analysis of electron scattering data Teillet-Billy and Fiquet-Fayard, 1977 leads to re = 1.267 Å Teillet-Billy and Fiquet-Fayard, 1977. |
| 5 | From D00(NO) and the electron affinities of O and NO. |
| 6 | From the photodetachment spectrum Siegel, Celotta, et al., 1972. Good agreement with McFarland, Dunkin, et al., 1972 and Parkes and Sugden, 1972. |
References
Go To: Top, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sanche and Schulz, 1971
Sanche, L.; Schulz, G.J.,
Vibrational progressions and Rydberg series of O2 and NO,
Phys. Rev. Lett., 1971, 27, 1333. [all data]
Schulz, 1973
Schulz, G.J.,
Resonances in electron impact on diatomic molecules,
Rev. Mod. Phys., 1973, 45, 423. [all data]
Carbonneau and Marmet, 1974
Carbonneau, R.; Marmet, P.,
The electroionization spectrum of nitric oxide,
Can. J. Phys., 1974, 52, 1885. [all data]
van Brunt and Kieffer, 1974
van Brunt, R.J.; Kieffer, L.J.,
Angular distribution of O- from dissociative electron attachment to NO,
Phys. Rev. A: Gen. Phys., 1974, 10, 1633. [all data]
Thulstrup, Thulstrup, et al., 1974
Thulstrup, P.W.; Thulstrup, E.W.; Andersen, A.; Ohrn, Y.,
Configuration interaction calculations of some observed states of NO-, NO, NO+, and NO2+,
J. Chem. Phys., 1974, 60, 3975. [all data]
Lefebvre-Brion, 1973
Lefebvre-Brion, H.,
Nature of the resonant states of NO-,
Chem. Phys. Lett., 1973, 19, 456. [all data]
Pearson and Lefebvre-Brion, 1976
Pearson, P.K.; Lefebvre-Brion, H.,
Calculations of the widths of some Feshbach resonances in CO- and NO-,
Phys. Rev. A: Gen. Phys., 1976, 13, 2106-2113. [all data]
Tronc, Huetz, et al., 1975
Tronc, M.; Huetz, A.; Landau, M.; Pichou, F.; Reinhardt, J.,
Resonant vibrational excitation of the NO ground state by electron impact in the 0.1-3 eV energy range,
J. Phys. B:, 1975, 8, 1160. [all data]
Teillet-Billy and Fiquet-Fayard, 1977
Teillet-Billy, D.; Fiquet-Fayard, F.,
The NO- 3Σ- and 1Δ resonances: theoretical analysis of electron scattering data,
J. Phys. B:, 1977, 10, 111. [all data]
Spence and Schulz, 1971
Spence, D.; Schulz, G.J.,
Vibrational excitation and compound states in NO,
Phys. Rev. A: Gen. Phys., 1971, 3, 1968. [all data]
Burrow, 1974
Burrow, P.D.,
Temporary negative ion formation in NO and O2,
Chem. Phys. Lett., 1974, 26, 265. [all data]
Zecca, Lazzizzera, et al., 1974
Zecca, A.; Lazzizzera, I.; Krauss, M.; Kuyatt, C.E.,
Electron scattering from NO and N2O below 10 eV,
J. Chem. Phys., 1974, 61, 4560. [all data]
Siegel, Celotta, et al., 1972
Siegel, M.W.; Celotta, R.J.; Hall, J.L.; Levine, J.; Bennett, R.A.,
Molecular Photodetachment Spectroscopy. I. The Electron Affinity of Nitric Oxide and the Molecular Constants of NO-,
Phys. Rev. A, 1972, 6, 2, 607, https://doi.org/10.1103/PhysRevA.6.607
. [all data]
McFarland, Dunkin, et al., 1972
McFarland, M.; Dunkin, D.B.; Fehsenfeld, F.C.; Schmeltekopf, A.L.; Ferguson, E.E.,
Collisional detachment studies of NO-,
J. Chem. Phys., 1972, 56, 2358. [all data]
Parkes and Sugden, 1972
Parkes, D.A.; Sugden, T.M.,
Electron attachment and detachment in nitric oxide,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 600. [all data]
Notes
Go To: Top, Constants of diatomic molecules, References
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