Tromethamine
- Formula: C4H11NO3
- Molecular weight: 121.1350
- IUPAC Standard InChIKey: LENZDBCJOHFCAS-UHFFFAOYSA-N
- CAS Registry Number: 77-86-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 1,3-Propanediol, 2-amino-2-(hydroxymethyl)-; Addex-Tham; Aminotrimethylolmethane; Aminotris(hydroxymethyl)methane; Methanamine, 1,1,1-tris(hydroxymethyl)-; Pehanorm; Talatrol; Tham-E; Trimethylolaminomethane; Tris; Tris amino; Tris buffer; Tris(hydroxymethyl)aminomethane; Tris(hydroxymethyl)methanamine; Tris(hydroxymethyl)methylamine; Tris-steril; Trisamin; Trisamine; Trisaminol; Trispuffer; Trizma; Trometamol; Trometamole; Tromethane; Tromethanmin; Tutofusin tris; THAM; Apiroserum Tham; Methylamine, 1,1,1-tris(hydroxymethyl)-; 2-(Hydroxymethyl)-2-amino-1,3-propanediol; 2-Amino-2-(hydroxymethyl)propane-1,3-diol; 2-Amino-2-methylol-1,3-propanediol; Tromethamin; Aminotri(hydroxymethyl)methane; TAM; Trigmo base; Triladyl; 2-Amino-2-hydroxymethylpropanediol; 2-Amino-2-(hydroxymethyl)-1,3-propanediol; Tris (hydroxymethyl)aminoethane; Tris base; Tris, free base; Trizma base; NSC 6365; Tris (buffering agent)
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Condensed phase thermochemistry data
Go To: Top, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -717.84 ± 0.82 | kJ/mol | Ccr | Laynez, Ringer, et al., 1970 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -2426.41 ± 0.73 | kJ/mol | Ccb | Xue, Wu, et al., 1985 | ALS |
ΔcH°solid | -2428.27 ± 0.78 | kJ/mol | Ccr | Laynez, Ringer, et al., 1970 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 175.44 | J/mol*K | N/A | Arvidsson and Westrum, 1972 | DH |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
171.27 | 298.15 | Ying and Lin, 1990 | T = 290 to 450 K.; DH |
167.19 | 298.15 | Arvidsson and Westrum, 1972 | T = 5 to 300 K.; DH |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | Copyright (C) 1987 by the Coblentz Society Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | WYANDOTTE CHEMICALS CORP. |
Source reference | COBLENTZ NO. 5998 |
Date | Not specified, most likely prior to 1970 |
Name(s) | 2-amino-2-(hydroxymethyl)-1,3-propanediol |
State | SOLID (OIL MULL) |
Instrument | BAIRD (GRATING) |
Instrument parameters | NaCl PRISM |
Path length | CAPILLARY SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1 |
Resolution | 2 |
Melting point | 171 C |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-1766 |
NIST MS number | 229605 |
UV/Visible spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | Parish, 1971 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 19878 |
Instrument | Unicam SP 500 |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Other | Methyl Silicone | 1645. | Ardrey and Moffat, 1981 | Program: not specified |
References
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Laynez, Ringer, et al., 1970
Laynez, J.; Ringer, B.; Sunner, S.,
On the accuracy of rotating-bomb combustion calorimetry for organic chlorine and bromine compounds,
J. Chem. Thermodyn., 1970, 2, 603-610. [all data]
Xue, Wu, et al., 1985
Xue, R.; Wu, D.; Qu, S.,
Studies on thermochemistry of porphyrins. I. A precision combustion calorimetric apparatus and calibration,
Wuli Huaxue Xuebao, 1985, 1, 76-81. [all data]
Arvidsson and Westrum, 1972
Arvidsson, K.; Westrum, E.F., Jr.,
Tris(hydroxymethane.yl)aminomethane. Heat capacities and thermodynamic properties from 5 to 350K,
J. Chem. Thermodynam., 1972, 4, 449-453. [all data]
Ying and Lin, 1990
Ying, Z.Z.; Lin, Y.M.,
Heat capacity and phase transitions of 2-amino-2-hydroxymethylpropan-1,3-diol from 290 to 455 K,
J. Chem. Thermodynam., 1990, 22, 617-622. [all data]
Parish, 1971
Parish, C.,
UV atlas of organic compounds, 1971, 5, K2/4. [all data]
Ardrey and Moffat, 1981
Ardrey, R.E.; Moffat, A.C.,
Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase,
J. Chromatogr., 1981, 220, 3, 195-252, https://doi.org/10.1016/S0021-9673(00)81925-1
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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