cyc-(HC=NCH2)+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 46200 ± 800 gas Bock and Solouki, 1981
Bock, Dammel, et al., 1983
Bock and Dammel, 1987

State:   C


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 41200 ± 800 gas Bock and Solouki, 1981
Bock, Dammel, et al., 1983
Bock and Dammel, 1987

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 23240 ± 160 gas Bock and Solouki, 1981
Bock, Dammel, et al., 1983
Bock and Dammel, 1987

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txx = 7900 ± 160 gas Bock and Solouki, 1981
Bock, Dammel, et al., 1983

Additional references: Jacox, 1998, page 311

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bock and Solouki, 1981
Bock, H.; Solouki, B., Photoelektronen-Spektren und Moleküleigenschaften: Echtzeit-Gasanalytik in strömenden Systemen, Angew. Chem., 1981, 93, 5, 425, https://doi.org/10.1002/ange.19810930504 . [all data]

Bock, Dammel, et al., 1983
Bock, H.; Dammel, R.; Aygen, S., Gas-phase reactions. 36. Pyrolysis of vinyl azide, J. Am. Chem. Soc., 1983, 105, 7681. [all data]

Bock and Dammel, 1987
Bock, H.; Dammel, R., Cycloalkanimine 2H-azirin, 1-azetin, 1-pyrrolin, 1-piperidein, und 3,4,5,6-tetrahydro-2H-azepin: Darstellung und photoelektronen-spektren, Chem. Ber., 1987, 120, 1971. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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