Tricyclo[3.3.1.1(3,7)]decane-1-carbonitrile

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tfus458.KN/AFoulon, Amoureux, et al., 1984Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δsub16.1 ± 0.2kcal/molVAbboud, Jimenez, et al., 1992ALS
Δsub16.1kcal/molN/AAbboud, Jimenez, et al., 1992DRB
Δsub16.1 ± 0.2kcal/molMEAbboud, Jimenez, et al., 1992Based on data from 294. to 312. K.; AC
Δsub18.16 ± 0.27kcal/molVMeier, Dogan, et al., 1987ALS
Δsub18.2kcal/molN/AMeier, Dogan, et al., 1987DRB

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
16.0 ± 0.2303.MEAbboud, Jimenez, et al., 1992Based on data from 294. to 312. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.59458.Foulon, Amoureux, et al., 2000AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
4.694280.Foulon, Amoureux, et al., 1984CAL
7.827458.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 118387

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Foulon, Amoureux, et al., 1984
Foulon, M.; Amoureux, J.P.; Sauvajol, J.L.; Cavrot, J.P.; Muller, M., Different aspects of an interesting glassy crystal: 1-cyanoadamantane, J. Phys. C, 1984, 17, 24, 4213, https://doi.org/10.1088/0022-3719/17/24/005 . [all data]

Abboud, Jimenez, et al., 1992
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C., Structural effects on the thermochemical properties of organic compounds. III. Enthalpies of combustion, vapour pressures and enthalpies of sublimation, and standard enthalpies of formation in the gaseous phase, of adamantane-1-carboxylic acid methyl ester and of adamantane-1-carbonitrile, J. Chem. Thermodyn., 1992, 24, 1299-1304. [all data]

Meier, Dogan, et al., 1987
Meier, M.; Dogan, B.; Beckhaus, H.; Ruchardt, C., Heats of formation and heats of isomerization of isocyanides, New J. Chem., 1987, 11, 1-6. [all data]

Foulon, Amoureux, et al., 2000
Foulon, M.; Amoureux, J.P.; Sauvajol, J.L.; Cavrot, J.P.; Muller, M., Different aspects of an interesting glassy crystal: 1-cyanoadamantane, J. Phys. C: Solid State Phys., 2000, 17, 24, 4213-4229, https://doi.org/10.1088/0022-3719/17/24/005 . [all data]


Notes

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References