Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)-

• Formula: C₈H₅MnO₃
• Molecular weight: 204.0615
• IUPAC Standard InChI: InChI=1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;; Copy

  
• IUPAC Standard InChIKey: CZPHEHHRMHXAIK-UHFFFAOYSA-N Copy
• CAS Registry Number: 12079-65-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Manganese, tricarbonyl-π-cyclopentadienyl-; π-Cyclopentadienylmanganese tricarbonyl; Cyclopentadienylmanganese tricarbonyl; Cyclopentadienyltricarbonylmanganese; Cymantrene; Manganese, cyclopentadienyltricarbonyl-; Tricarbonyl-π-cyclopentadienylmanganese; Tricarbonylcyclopentadienylmanganese; (η⁵-Cyclopentadienyl) manganese tricarbonyl; Cyklopentadientrikarbonylmanganium; MCT; Tricarbonyl(η5-cyclopentadienyl)manganese; tricarbonyl(η-cyclopentadienyl)manganese
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• Information on this page:
  • Phase change data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

Temperature of phase transition

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chhor, Pommier, et al., 1983
Chhor, K.; Pommier, C.; Diot, M., Low-temp. thermodynamic study of cymantrene (C5H5Mn(CO)3) and azacymantrene (C4H4NMn(CO)3), Mol. Cryst. Liq. Cryst., 1983, 100, 193. [all data]

Picciochi, Canongia Lopes, et al., 2008
Picciochi, Ricardo; Canongia Lopes, Jose N.; Diogo, Herminio P.; Minas da Piedade, Manuel E., Experimental and Molecular Dynamics Simulation Study of the Sublimation Energetics of Cyclopentadienyltricarbonylmanganese (Cymantrene), J. Phys. Chem. A, 2008, 112, 41, 10429-10434, https://doi.org/10.1021/jp805607d . [all data]

Baev and Demyanchuck, 1970
Baev, A.K.; Demyanchuck, V.V., Obshch. Prikl. Khim., 1970, 3, 65. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Evstigneeva and Shmyreva, 1965
Evstigneeva, E.V.; Shmyreva, G.O., Russ. J. Phys. Chem., 1965, 39, 529. [all data]

Cordes and Schreiner, 1959
Cordes, J.F.; Schreiner, S., Dampfdruckmessungen bei einigen Aromatenkomplexen, Z. Anorg. Allg. Chem., 1959, 299, 1-2, 87-91, https://doi.org/10.1002/zaac.19592990111 . [all data]

Chhor, Pommier, et al., 1983, 2
Chhor, K.; Pommier, C.; Diot, M., Low-temperature thermodynamic study of cymantrene (C₅H₅Mn(CO)₃) and azacymantrene (C₄H₄NMn(CO)₃), Mol. Cryst. Liq. Cryst., 1983, 100, 193-209. [all data]

Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Ttriple	Triple point temperature
  Ttrs	Temperature of phase transition
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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