GA38, methyl ester TMS
- Formula: C27H44O6Si2
- Molecular weight: 520.8057
- IUPAC Standard InChI: InChI=1S/C27H44O6Si2/c1-17-14-26-15-27(17,33-35(7,8)9)13-10-18(26)25-12-11-19(32-34(4,5)6)24(2,23(29)31-16-25)21(25)20(26)22(28)30-3/h18-21H,1,10-16H2,2-9H3/t18?,19-,20+,21?,24+,25+,26-,27-/m1/s1
- IUPAC Standard InChIKey: FGHFKLKJWQGLGR-JUCSEYGPSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA38, MeTMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2940. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BPX-5 | 2988. | Stokes, Mander, et al., 2003 | 25. m/0.22 mm/0.25 μm, He; Program: 60C (1min) => 20C/min => 220C => 4C/min => 300C |
| Capillary | BPX-5 | 2989. | Stokes, Mander, et al., 2003 | 25. m/0.22 mm/0.25 μm, He; Program: 60C (1min) => 20C/min => 220C => 4C/min => 300C |
| Capillary | BPX-5 | 2991. | Stokes, Mander, et al., 2003 | 25. m/0.22 mm/0.25 μm, He; Program: 60C (1min) => 20C/min => 220C => 4C/min => 300C |
| Capillary | OV-1 | 2939. | Itoh, Ueguchi-Tanaka, et al., 2001 | Program: not specified |
| Capillary | OV-1 | 2940. | Itoh, Ueguchi-Tanaka, et al., 2001 | Program: not specified |
| Capillary | BP-1 | 2961. | Lange, Hedden, et al., 1993 | 25. m/0.25 mm/0.33 μm, He; Program: 60C(1min) => 20C/min => 240C => 4C/min => 300C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Stokes, Mander, et al., 2003
Stokes, T.S.; Mander, L.N.; Croker, S.J.; Twitchin, B.; Hanke, D.E.,
3β,13-Dihydroxylated C20 gibberellins from inflorescences of Rumex acetosa L.,
Phytochemistry, 2003, 62, 2, 165-174, https://doi.org/10.1016/S0031-9422(02)00442-9
. [all data]
Itoh, Ueguchi-Tanaka, et al., 2001
Itoh, H.; Ueguchi-Tanaka, M.; Sentoku, N.; Kitano, H.; Matsuoka, M.; Kobayashi, M.,
Cloning and functional analysis of two gibberellin 3β-hydroxylase genes that are differently expressed during the growth of rice,
Proc. Natl. Acad. Sci. U.S.A, 2001, 98, 15, 8909-8914, https://doi.org/10.1073/pnas.141239398
. [all data]
Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E.,
Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins,
Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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