Al3O3 radical anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.780 ± 0.010LPESAkin and Jarrold, 2003bent rectangle" isomer. However, see 100KOY/BRA for evidence of no isomers and fast fragmentation.
2.102 ± 0.010LPESAkin and Jarrold, 2003Kite" isomer
2.12 ± 0.10LPESMeloni, Ferguson, et al., 2003 
2.800 ± 0.026LPESWu, Li, et al., 1998Vert. detachment energy: 2.96±0.02 eV. Isomer with EA=2.07 eV. See Akin and Jarrold, 2003 for structure

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Akin and Jarrold, 2003
Akin, F.A.; Jarrold, C.C., Separating contributions from multiple structural isomers in anion photoelectron spectra: Al3O3- beam hole burning, J. Chem. Phys., 2003, 118, 4, 1773-1778, https://doi.org/10.1063/1.1529176 . [all data]

Meloni, Ferguson, et al., 2003
Meloni, G.; Ferguson, M.J.; Neumark, D.M., Negative ion photodetachment spectroscopy of the Al3O2, Al3O3, Al4Ox, Al5Ox, (x=3-5), Al6O5, and Al7O5 clusters, Phys. Chem. Chem. Phys., 2003, 5, 19, 4073-4079, https://doi.org/10.1039/b308119b . [all data]

Wu, Li, et al., 1998
Wu, H.; Li, X.; Wang, X.-B.; Ding, C.-F.; Wang, L.-S., Al3Oy (y=0-5) Clusters: Sequential Oxidation, Metal-to-oxide Transformation, and Photoisomerization., J. Chem. Phys., 1998, 109, 2, 449, https://doi.org/10.1063/1.476583 . [all data]


Notes

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