1-Adamantanecarboxamide, N,N-dimethyl-,


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-286.1 ± 2.7kJ/molCcbAbboud, Jimenez, et al., 1995Author was aware that data differs from previously reported values; See 93ABB/JIM

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-383.6 ± 2.7kJ/molCcbAbboud, Jimenez, et al., 1995Author was aware that data differs from previously reported values; See 93ABB/JIM
Quantity Value Units Method Reference Comment
Δcsolid-7733.2 ± 2.1kJ/molCcbAbboud, Jimenez, et al., 1995Author was aware that data differs from previously reported values; See 93ABB/JIM

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub97.5 ± 0.3kJ/molVAbboud, Jimenez, et al., 1995Author was aware that data differs from previously reported values; See 93ABB/JIM; ALS
Δsub97.5 ± 0.3kJ/molMEAbboud, Jimenez, et al., 1995AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
96.9 ± 0.3313.MEAbboud, Jimenez, et al., 1993Based on data from 303. to 322. K. See also Abboud, Jimenez, et al., 1995.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)949.4kJ/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity917.6kJ/molN/AHunter and Lias, 1998 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abboud, Jimenez, et al., 1995
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C.; Podosenin, A.; Rogers, D.W.; Liebman, J.F., Interrelations of the energetics of amides and alkenes: enthalpies of formation of N,N-dimethyl dertivatives of pivalamide, 1-adamantylcarboxamide and benzamide, and of styrene and its a-, trans-β- and β,β-methylated derivates, J. Phys. Org. Chem., 1995, 8, 15-25. [all data]

Abboud, Jimenez, et al., 1993
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C., Standard enthalpies of formation of N, N-dimethyl-tert-butylcarboxamide and N, N-dimethyl-1-adamantylcarboxamide, Calorim. Anal. Therm., 1993, 24, 181. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

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