Copper monohydride
- Formula: CuH
- Molecular weight: 64.554
- IUPAC Standard InChI: InChI=1S/Cu.H
- IUPAC Standard InChIKey: JJFLDSOAQUJVBF-UHFFFAOYSA-N
- CAS Registry Number: 13517-00-5
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.4440 ± 0.0060 | LPES | Calvi, Andrews, et al., 2007 |
De-protonation reactions
Cu- + =
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 346.8 ± 2.6 | kcal/mol | D-EA | Bilodeau, Scheer, et al., 1998 | gas phase |
| ΔrH° | 346.8 ± 2.6 | kcal/mol | D-EA | Leopold, Ho, et al., 1987 | gas phase |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Calvi, Andrews, et al., 2007
Calvi, R.M.D.; Andrews, D.H.; Lineberger, W.C.,
Negative ion photoelectron spectroscopy of copper hydrides,
Chem. Phys. Lett., 2007, 442, 1-3, 12-16, https://doi.org/10.1016/j.cplett.2007.05.060
. [all data]
Bilodeau, Scheer, et al., 1998
Bilodeau, R.C.; Scheer, M.; Haugen, H.K.,
Infrared Laser Photodetachment of Transition Metal Negative Ions: Studies on Cr-, Mo-, Cu-, and Ag-,
J. Phys. B: Atom. Mol. Opt. Phys., 1998, 31, 17, 3885-3891, https://doi.org/10.1088/0953-4075/31/17/013
. [all data]
Leopold, Ho, et al., 1987
Leopold, D.G.; Ho, J.; Lineberger, W.C.,
Photoelectron Spectroscopy of Mass-selected Metal Cluster Anions. I. Cun-, n=1-10,
J. Chem. Phys., 1987, 86, 4, 1715, https://doi.org/10.1063/1.452170
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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