Ferrocene-d10
- Formula: C10D10Fe
- Molecular weight: 196.093
- CAS Registry Number: 12082-87-0
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| S°solid,1 bar | 55.731 | cal/mol*K | N/A | Sorai and Shiomi, 1984 |
Constant pressure heat capacity of solid
| Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 53.045 | 298.15 | Sorai and Shiomi, 1984 | T = 13 to 300 K. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Enthalpy of phase transition
| ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 0.210 | 164.1 | crystaline, III | crystaline, II | Sorai and Shiomi, 1984 | Lambda transition. Secondary Cp maximum at 172 K. |
| 1.011 | 251. | crystaline, II | crystaline, I | Sorai and Shiomi, 1984 | |
| 0.210 | 164.1 | crystaline, III | crystaline, II | Shiomi and Sorai, 1983 | Lambda type transition in the metastable state. |
| 1.011 | 251. | crystaline, II | crystaline, I | Shiomi and Sorai, 1983 | Phase transition between stable LT and stable HT phases. |
Entropy of phase transition
| ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 1.26 | 164.1 | crystaline, III | crystaline, II | Sorai and Shiomi, 1984 | Lambda |
| 4.022 | 251. | crystaline, II | crystaline, I | Sorai and Shiomi, 1984 | |
| 1.26 | 164.1 | crystaline, III | crystaline, II | Shiomi and Sorai, 1983 | Lambda |
| 4.022 | 251. | crystaline, II | crystaline, I | Shiomi and Sorai, 1983 | Phase |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sorai and Shiomi, 1984
Sorai, M.; Shiomi, Y.,
Thermodynamic properties of ferrocene-d10 crystal: comparison with ferrocene-h10,
Mol. Cryst. Liq. Cryst., 1984, 107, 271-292. [all data]
Shiomi and Sorai, 1983
Shiomi, Y.; Sorai, M.,
Heat capacity in the range 13 to 300 K and phase transitions of ferrocene-d10,
Chem. Phys. Lett., 1983, 95(2), 167-170. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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