AsCl radical

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to AsCl+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.29997EIAEPabst, Bennett, et al., 1976From AsCl3; G2MP2 calculations agree with this value

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through January, 1976

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 75As35Cl
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
B 40826 [520] H         B ← X V 40865 H
↳Basco and Yee, 1967
X 0 443 H 2         

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pabst, Bennett, et al., 1976
Pabst, R.E.; Bennett, S.L.; Franklin, J.L.; Margrave, J.L., Negative ion electron impact studies of arsenic trihalides: AsF3, AsCl3, and AsBr3, J. Chem. Phys., 1976, 64, 1550. [all data]

Basco and Yee, 1967
Basco, N.; Yee, K.K., Spectrum of the AsCl free-radical, Chem. Commun., 1967, 1255. [all data]

Notes

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