Ethylene oxalate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-166.6 ± 0.29kcal/molCcbLebedev, Kulagina, et al., 1982see Lebedev, Kulagina, et al., 1981; ALS
Quantity Value Units Method Reference Comment
Δcsolid-346.20 ± 0.29kcal/molCcbLebedev, Kulagina, et al., 1982see Lebedev, Kulagina, et al., 1981; Corresponding Δfsolid = -166.6 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar37.86cal/mol*KN/ALebedev, Kulagina, et al., 1982, 2DH
solid,1 bar35.78cal/mol*KN/ALebedev, Kulagina, et al., 1982, 3DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
33.91298.15Lebedev, Kulagina, et al., 1982, 2T = 8 to 330 K.; DH
33.91298.15Lebedev, Kulagina, et al., 1982, 3T = 8 to 330 K.; DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Ttriple415.KN/ALebedev, Kulagina, et al., 1982, 4Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.2027415.Lebedev, Kulagina, et al., 1982, 2DH
3.20415.Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
7.717415.Lebedev, Kulagina, et al., 1982, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Kulagina, et al., 1982
Lebedev, B.V.; Kulagina, T.G.; Kiparisova, E.G., Thermodynamics of dl-lactide, ethylene oxalate, and 2,5-dioxopiperazine in the range 0-330 K., Russ. J. Phys. Chem. (Engl. Transl.), 1982, 56, 1641-1643. [all data]

Lebedev, Kulagina, et al., 1981
Lebedev, B.V.; Kulagina, T.G.; Kiparisova, E.G., Thermodynamics of 2,5-piperazinedione in the range 0-330 K, J. Gen. Chem. USSR, 1981, 51, 174-177. [all data]

Lebedev, Kulagina, et al., 1982, 2
Lebedev, B.V.; Kulagina, T.G.; Lyudvig, Ye.B.; Ovchinnikova, T.N., Calorimetric study of ethylene oxalate, polyethylene oxalate and parameters of the polymerization of ethylene oxalate in the range 8-450 K, Vysokomol. Soedin., 1982, A24, 1490-1495. [all data]

Lebedev, Kulagina, et al., 1982, 3
Lebedev, B.V.; Kulagina, T.G.; Kiparisova, Y.G., Thermodynamics of dl-lactide, ethylene oxalate, and 2,5-dioxopiperazine in the range 0-330 K, Zhur. Fiz. Khim., 1982, 56, 2665-2669. [all data]

Lebedev, Kulagina, et al., 1982, 4
Lebedev, B.V.; Kulagina, T.G.; Lyudvig, Ye.B.; Ovchinnikova, T.N., Calorimetric study of ethylene oxalate,polyethylene oxalate and parameters of the polymerization of ethylene oxalate in the range 8-450 K, Vysokomol. Soedin, Ser. A, 1982, 24, 1490. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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