H2OS


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

HOS- + Hydrogen cation = H2OS

By formula: HOS- + H+ = H2OS

Quantity Value Units Method Reference Comment
Δr1481. ± 15.kJ/molG+TSOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH
Quantity Value Units Method Reference Comment
Δr1452. ± 13.kJ/molIMRBOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to H2OS+ (ion structure unspecified)

De-protonation reactions

HOS- + Hydrogen cation = H2OS

By formula: HOS- + H+ = H2OS

Quantity Value Units Method Reference Comment
Δr1481. ± 15.kJ/molG+TSOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH
Quantity Value Units Method Reference Comment
Δr1452. ± 13.kJ/molIMRBOhair, Depuy, et al., 1993gas phase; between MeNO2, tBuSH

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ohair, Depuy, et al., 1993
Ohair, R.A.J.; Depuy, C.H.; Bierbaum, V.M., Gas-Phase Chemistry and Thermochemistry of the Hydroxysulfide Anion, HOS-, J. Phys. Chem., 1993, 97, 30, 7955, https://doi.org/10.1021/j100132a026 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References